公开(公告)号：WO2010144297A3

公开(公告)日：2011-03-03

申请号：PCT/US2010037170

申请日：2010-06-03

Applicant: HONEYWELL INT INC ,  CHIU YUON ,  COTTRELL STEPHEN A ,  HORWATH RICHARD DURICK ,  KOPKALLI HALUK

Inventor： CHIU YUON ,  COTTRELL STEPHEN A ,  HORWATH RICHARD DURICK ,  KOPKALLI HALUK

IPC: B01J8/06 ,  B01J8/04 ,  B01J19/32

CPC classification number: F28D7/1638 ,  B01J8/067 ,  B01J2208/00221 ,  B01J2208/0023 ,  F28F9/0202 ,  F28F9/0265 ,  F28F2009/226 ,  F28F2210/08

Abstract: A multi-stage, multi-tube, shell-and-tube reactor which contains reaction zones and interstage temperature control (cooling/heating) zones in series. The reactor has at least two types of zones which both contribute to removing or supplying heat to the system depending on the system's need. The reactor will have a group of reaction zones which contain tubes packed with catalyst to progress the reaction and remove or supply heat simultaneously. There are also a number of interstage temperature control (cooling/heating) zones which are designed to supply or remove heat to or from the system. The positioning, number, and design of the zones will depend on the amount of temperature control desired and exothermic or endothermic nature of the processes to be conducted in the reactor.

Abstract translation: 包含反应区和级间温度控制（冷却/加热）区的多级，多管，管壳式反应器。 反应器具有至少两种类型的区域，这两个区域有助于根据系统的需要去除或供应热量。 反应器将具有一组反应区，其中包含装有催化剂的管，以进行反应并同时除去或提供热量。 还有一些级间温度控制（冷却/加热）区域，其设计用于向系统或从系统提供或移除热量。 区域的定位，数量和设计将取决于在反应器中进行的方法所需的温度控制量和放热或吸热性质。

公开(公告)号：WO2005063660A3

公开(公告)日：2005-11-17

申请号：PCT/US2004043195

申请日：2004-12-21

Applicant: HONEYWELL INT INC ,  COTTRELL STEPHEN A ,  WILSON ROBERT E

Inventor： COTTRELL STEPHEN A ,  WILSON ROBERT E

IPC: C07C17/38 ,  C07C17/383 ,  C07C17/389 ,  C07C19/12

CPC classification number: C07C17/383 ,  B01D3/34 ,  C07C17/38 ,  C07C17/389 ,  C07C19/08 ,  C07C19/10

Abstract: A method for the purification of pharmaceutical grade 1, 1, 1,2-tetrafluoroethane (HFC-134a) and polymer grade chlorodifluoromethane (HCFC-22) by contacting a mixture comprising 1, 1, 1,2-tetrafluoroethane or chlorodifluoromethane and methyl chloride with a zeolite such as a molecular sieve, and recovering from said contacted mixture substantially purified 1, 1, 1,2-tetrafluoroethane or chlorodifluoromethane.

Abstract translation: 通过使包含1,1,1,2-四氟乙烷或氯二氟甲烷和氯甲烷的混合物接触来纯化药物级别1,1,1-四氟乙烷（HFC-134a）和聚合物级氯二氟甲烷（HCFC-22）的方法 与沸石如分子筛反应，并从所述接触的混合物中回收基本上纯化的1,1,1-四氟乙烷或氯二氟甲烷。

公开(公告)号：WO2004106271A2

公开(公告)日：2004-12-09

申请号：PCT/US2004016231

申请日：2004-05-21

Applicant: HONEYWELL INT INC ,  TUNG HSUEH SUNG ,  COTTRELL STEPHEN A ,  MARKS CHAD L

Inventor： TUNG HSUEH SUNG ,  COTTRELL STEPHEN A ,  MARKS CHAD L

IPC: C07C17/20 ,  C07C17/21 ,  C07C17/00

CPC classification number: C07C17/21 ,  C07C17/206 ,  C07C19/08

Abstract: A manufacturing process for making hydrofluorocarbons (HFCs), by reacting a hydrochlorocarbon and HF in a liquid phase catalytic reactor using a large mole ratio of HF to hydrochlorocarbon to minimize formation of high boiling byproducts and improve HF consumption and hydrofluorocarbon yields.

Abstract translation: 通过使用大量摩尔比的HF与氢氯化碳在液相催化反应器中使氢氟烃和HF反应制备氢氟烃（HFCs）的制造方法，以最小化高沸点副产物的形成并提高HF消耗量和氢氟碳化合物产率。

公开(公告)号：EP3294697A1

公开(公告)日：2018-03-21

申请号：EP16793142

申请日：2016-04-25

Applicant: HONEYWELL INT INC

Inventor： WANG HAIYOU ,  TUNG HSUEH SUNG ,  COTTRELL STEPHEN A

IPC: C07C17/25 ,  C07C17/42 ,  C07C19/10

CPC classification number: C07C17/25 ,  C07C21/18

Abstract: Disclosed is a process for the production of 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) which includes reacting a propane feedstock comprising tetrachlorofluoropropanes, trichlorodifluoropropanes, dichlorotrifluoropropanes, or a mixture thereof, in the presence of a solid catalyst. The process generally comprises the following four steps: (i) providing a propane feedstock comprising trichlorodifluoropropanes and dichlorotrifluoropropanes, (ii) reacting the feedstock in a vapor phase reactor in the presence of HF and in the presence of a solid catalyst under conditions effective to form a product stream comprising HCFO-1233zd and unconverted starting materials, (iii) recovering or removing HCl and HF, and (iv) isolating HCFO-1233zd(E), HCFO-1233zd(Z), or both.

公开(公告)号：EP2970741A4

公开(公告)日：2016-11-02

申请号：EP14778275

申请日：2014-03-05

Applicant: HONEYWELL INT INC

Inventor： MERKEL DANIEL C ,  POKROVSKI KONSTANTIN A ,  TUNG HSUEH SUNG ,  WANG HAIYOU ,  COTTRELL STEPHEN A ,  PHAM HANG T

IPC: C09K5/04 ,  C07C19/08 ,  C11D7/08 ,  C11D7/50 ,  C23G5/028

CPC classification number: C07C19/10 ,  C09K5/044 ,  C11D7/08 ,  C11D7/5036 ,  C23G5/02809

Abstract: Provided are azeotropic or azeotrope-like mixtures of 1,3,3-trichloro-1,1-difluoro-propane (HCFC-242fa) and hydrogen fluoride. Such compositions are useful as a feed stock or intermediate in the production of HFC-245fa and HCFO-1233zd.

公开(公告)号：EP2709970A4

公开(公告)日：2014-10-29

申请号：EP12786229

申请日：2012-05-17

Applicant: HONEYWELL INT INC

Inventor： COTTRELL STEPHEN A ,  TUNG HSUEH SUNG ,  POKROVSKI KONSTANTIN A

IPC: C07C17/25 ,  C07C17/383 ,  C07C21/18

CPC classification number: C07C17/383 ,  C07C17/206 ,  C07C17/25 ,  C07C17/38 ,  C07C21/18 ,  Y02P20/125

公开(公告)号：EP3294698A1

公开(公告)日：2018-03-21

申请号：EP16793144

申请日：2016-04-25

Applicant: HONEYWELL INT INC

Inventor： COTTRELL STEPHEN A ,  CERRI GUSTAVO ,  CHIU YUON ,  MCCLAINE JENNIFER W

IPC: C07C17/42 ,  C07C17/25 ,  C07C19/10

CPC classification number: C07C17/21 ,  C07C17/208 ,  Y02P20/125 ,  C07C19/08

Abstract: A process is described wherein otherwise unusable by-products from a process for the manufacture of trans HCFO-1233zd(E) are converted to a valuable product by introducing them into a process for the production of HFC-245fa. The process includes the catalytic hydrofluorination of a reaction mixture comprising the HCFO-1233zd production by-products.

公开(公告)号：EP2951140A4

公开(公告)日：2016-09-28

申请号：EP14746002

申请日：2014-02-03

Applicant: HONEYWELL INT INC

Inventor： TUNG HSUEH SUNG ,  WANG HAIYOU ,  MERKEL DANIEL C ,  COTTRELL STEPHEN A ,  POKROVSKI KONSTANTIN A ,  SHANKLAND IAN

IPC: C07C17/25 ,  C07C17/35 ,  C07C21/18

CPC classification number: C07C17/204 ,  C07C17/206 ,  C07C17/21 ,  C07C17/25 ,  C07C21/18

Abstract: Disclosed is a process in which the fluorination of an organic reactant comprising 1,1,1,3,3-pentachloropropane (240fa) with anhydrous HF is conducted in the presence of an effective amount of a phase-transfer catalyst which facilitates the reaction between these incompatible reaction components to produce 1-chloro-3,3,3-trifluoro-propene (1233zd). Other organic reactant materials include 1,1,3,3-tetrachloropropene (HCO-1230za), 1,3,3,3-tetrachloropropene (HCO-1230zd), and various mixtures with or without 240fa.

公开(公告)号：EP2665696A4

公开(公告)日：2015-12-23

申请号：EP12737145

申请日：2012-01-13

Applicant: HONEYWELL INT INC

Inventor： COTTRELL STEPHEN A ,  CHIU YUON ,  TUNG HSUEH SUNG ,  UHRICH KEVIN D ,  SCHEIDLE PETER ,  KOPKALLI HALUK

IPC: C07C17/25 ,  B01J23/18 ,  C07C17/087 ,  C07C17/21 ,  C07C17/38 ,  C07C21/18

CPC classification number: C07C17/21 ,  C07C17/087 ,  C07C17/206 ,  C07C17/25 ,  C07C17/38 ,  C07C17/383 ,  C07C19/10 ,  C07C21/18

Abstract: wherein the HC1 generated during these steps is scrubbed with water to form an acid solution and the organic components are scrubbed with a caustic solution and then dried before further processing.

公开(公告)号：EP2760784A4

公开(公告)日：2015-07-08

申请号：EP12836006

申请日：2012-09-20

Applicant: HONEYWELL INT INC

Inventor： CHIU YUON ,  HORWATH RICHARD DURICK ,  COTTRELL STEPHEN A

IPC: C01B7/19

CPC classification number: C01B7/195

Abstract: Disclosed are methods used to remove HF from a fluorocarbon containing stream, thereby forming a final aqueous HF solution having both a high HF concentration and low dissolved organic content.