公开(公告)号：US4535174A

公开(公告)日：1985-08-13

申请号：US667931

申请日：1984-11-02

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08F4/00 ,  C07F7/18 ,  C08F4/16 ,  C08F4/42 ,  C08F4/72 ,  C08F293/00 ,  C07F7/08

CPC classification number: C07F7/1828

Abstract: Free-radical initiators are provided in the form of silylethers of arylpinacols. An aryl ketone is reacted with a monohalo- or dihalosilane having at least one olefinically unsaturated organic radical attached to silicon in the presence of an active metal reducing agent, such as magnesium.

Abstract translation: 自由基引发剂以芳基辛醇的水飞蓟宾的形式提供。 在活性金属还原剂如镁的存在下，将芳基酮与具有至少一个与烯属不饱和有机基团连接的单卤代或二卤硅烷反应。

公开(公告)号：US4529490A

公开(公告)日：1985-07-16

申请号：US497357

申请日：1983-05-23

Applicant: James V. Crivello ,  Julia L. Lee

Inventor： James V. Crivello ,  Julia L. Lee

IPC: C07C45/00 ,  C07C45/63 ,  C07C46/00 ,  C07C49/697 ,  C07C49/813 ,  C07C50/24 ,  C07C67/00 ,  C07F9/68 ,  C08F2/50 ,  C08G59/00 ,  C08G59/68 ,  C08G85/00 ,  C08K5/07 ,  C08L101/00 ,  G03F7/029

CPC classification number: C08G59/68 ,  C07F9/68 ,  C08G85/00 ,  G03F7/029

Abstract: Aryliodonium salts resulting from the condensation of aryliodosotosylates and aryl ketones are provided which are used as photoinitiators to effect deep section UV cures. Deep section photopolymerizable organic materials are also provided which can be used as encapsulating agents to encapsulate a wide variety of electronic components.

Abstract translation: 提供由芳基碘代甲酸酯和芳基酮缩合产生的芳基碘盐，其用作光引发剂以实现深部分UV固化。 还提供了深层可光聚合的有机材料，其可以用作封装剂以封装各种各样的电子部件。

公开(公告)号：US4407759A

公开(公告)日：1983-10-04

申请号：US329485

申请日：1981-12-10

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08G59/68 ,  C07F9/66 ,  C07F9/02 ,  C07F9/90

CPC classification number: C08G59/68 ,  C07C381/12

Abstract: Onium salts of Group VIa elements having an MF.sub.6.sup.- anion, where M is selected from P, As and Sb, have been found to be photo active under ultraviolet light. These onium salts can be employed as cationic photoinitiators when used with a variety of organic resins and cyclic organic compounds.

Abstract translation: 已经发现，在紫外光下，具有选自P，As和Sb中的M选自具有MF6-阴离子的VIa族元素的鎓盐是光活性的。 当与各种有机树脂和环状有机化合物一起使用时，这些鎓盐可用作阳离子光引发剂。

公开(公告)号：US4399071A

公开(公告)日：1983-08-16

申请号：US357433

申请日：1982-03-12

Applicant: James V. Crivello ,  Julia L. Lee

Inventor： James V. Crivello ,  Julia L. Lee

IPC: C07C17/093 ,  C07C25/18 ,  C07C41/22 ,  C07C43/225 ,  C07C43/29 ,  C07C49/675 ,  C07F9/68 ,  C07F9/00 ,  C07F9/92

CPC classification number: C07C49/675 ,  C07C17/093 ,  C07C25/18 ,  C07C41/22 ,  C07D307/91

Abstract: A method is provided for making certain diaryliodonium salts which are useful as photoinitiators for a variety of cationic polymerizable organic materials. Reaction is effected between an aromatic iodo compound and an arylorganic aromatic compound in the presence of a peroxy organic acid and an organic sulfonic acid.

Abstract translation: 提供了制备某些可用作多种阳离子可聚合有机材料的光引发剂的二芳基碘鎓盐的方法。 在过氧有机酸和有机磺酸的存在下，在芳族碘化合物和芳基有机芳族化合物之间进行反应。

公开(公告)号：US4388450A

公开(公告)日：1983-06-14

申请号：US243302

申请日：1981-03-13

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C07C43/14 ,  C07C41/00 ,  C07C43/18 ,  C07C43/20 ,  C07C43/215 ,  C07C43/257 ,  C07C45/00 ,  C07C49/175 ,  C07C49/86 ,  C07C67/00 ,  C07C69/76 ,  C07C69/767 ,  C07C69/92 ,  C07C313/00 ,  C07C317/22 ,  C07C317/44 ,  C07C317/46 ,  C07C321/30 ,  C07C323/20 ,  C07C323/62 ,  C08F4/00 ,  C08F4/40 ,  C08F4/44 ,  C08F16/00 ,  C08F16/32 ,  C08G8/36 ,  C09D5/25 ,  C09K3/10 ,  C08L61/12 ,  C08L29/10 ,  C08L61/08

CPC classification number: C08F16/32 ,  C08G8/36

Abstract: Aromatic polyvinylethers and active hydrogen compound reaction products thereof have been found to provide fast heat curable molding compositions when used with various heat activated curing catalysts, for example, diaryliodonium salts in combination with aromatic polyvinylether soluble copper compounds, or dialkylhydroxyarylsulfonium salts in combination with certain organic oxidants.

公开(公告)号：US4216288A

公开(公告)日：1980-08-05

申请号：US940564

申请日：1978-09-08

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08G59/68 ,  C08G63/82 ,  C08K5/00 ,  G03F7/029 ,  G03C1/68 ,  C08F8/18 ,  C08F8/34

CPC classification number: G03F7/029 ,  C08G59/68 ,  C08G63/823 ,  C08K5/0025

Abstract: Heat curable cationically polymerizable organic materials, such as epoxy resins, are described based on the use of an aromatic onium salt initiator which can be used in combination with a reducing agent. The heat curable compositions can be used in a variety of applications, such as coating compounds, photoresists, etc.

Abstract translation: 基于使用可与还原剂组合使用的芳族鎓盐引发剂来描述热固化的可阳离子聚合的有机材料，例如环氧树脂。 可热固化组合物可用于各种应用中，例如涂料化合物，光致抗蚀剂等。

公开(公告)号：US4173551A

公开(公告)日：1979-11-06

申请号：US861128

申请日：1977-12-16

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08G59/68 ,  C08G63/82 ,  C08G85/00 ,  C08L61/00 ,  C08L61/06 ,  C08F4/00 ,  C08F4/06 ,  C08G8/10

CPC classification number: C08G85/00 ,  C08G59/68 ,  C08G63/823 ,  C08L61/00 ,  C08L61/06

Abstract: Aromatic onium salts, such as diaryliodonium salts, have been found to be effective thermal initiators for the polymerization of a variety of cationically polymerizable materials including epoxides, cyclic ethers, phenol formaldehyde resins, etc., when used in combination with various cocatalysts such as organic acids and copper salts.

Abstract translation: 已经发现，芳族鎓盐如二芳基碘鎓盐当与各种助催化剂如有机物结合使用时，可用于各种可阳离子聚合的材料的聚合的有效的热引发剂，包括环氧化物，环醚，苯酚甲醛树脂等。 酸和铜盐。

公开(公告)号：US4161405A

公开(公告)日：1979-07-17

申请号：US822150

申请日：1977-08-05

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08F2/00 ,  C08F2/46 ,  C08F2/50 ,  C08F4/00 ,  C08F4/06 ,  C08G65/00 ,  C08G85/00 ,  C09J4/00 ,  C09J201/00 ,  G03F7/029 ,  G03F7/038 ,  G03F7/26 ,  G03C5/00 ,  C08J3/28 ,  G03C1/94 ,  G03C5/04

CPC classification number: C08F2/50 ,  G03F7/029 ,  G03F7/0388 ,  Y10S430/115

Abstract: Cationic polymerization of a variety of organic materials such as vinyl monomers, prepolymers, cyclic ethers, cyclic esters, cyclic sulfides and organosilicon cyclics can be achieved by the use of certain radiation sensitive aromatic onium salts of Group VIa elements. In addition, polymerizable compositions are provided which can be used as coating compounds, molding resins, adhesives, etc.

Abstract translation: 各种有机材料如乙烯基单体，预聚物，环醚，环酯，环硫醚和有机硅环化合物的阳离子聚合可以通过使用VIa族元素的某些辐射敏感芳族鎓盐来实现。 此外，提供可用作涂料化合物，模塑树脂，粘合剂等的可聚合组合物

公开(公告)号：US4138255A

公开(公告)日：1979-02-06

申请号：US810036

申请日：1977-06-27

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08G59/68 ,  G03F7/029 ,  G03C5/00

CPC classification number: G03F7/029 ,  C08G59/68 ,  Y10S430/115

Abstract: Cationic polymerization of epoxy resin materials, such as epoxy monomers or prepolymers, can be achieved by use of certain radiation sensitive aromatic onium salts of Group VIa elements. Curable compositions are provided which can be used as sealants, coating compounds, encapsulants, etc.

Abstract translation: 环氧树脂材料如环氧单体或预聚物的阳离子聚合可以通过使用VIa族元素的某些辐射敏感芳族鎓盐来实现。 提供可用作密封剂，涂料化合物，密封剂等的可固化组合物

公开(公告)号：US3981897A

公开(公告)日：1976-09-21

申请号：US574007

申请日：1975-05-02

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08F2/00 ,  C07C17/00 ,  C07C17/35 ,  C07C25/02 ,  C07C25/18 ,  C07C67/00 ,  C07C201/00 ,  C07C205/12 ,  C07F9/90 ,  C08F2/50 ,  C08G59/00 ,  C08G59/68 ,  G03F7/029 ,  C07F9/66

CPC classification number: C07F9/902 ,  C08G59/68 ,  G03F7/029

Abstract: A method is provided for making certain diarylhalonium salts containing Group Va metal hexafluorides useful as photoinitiators, such as diphenyliodonium hexafluoroarsonate. An intermediate diarylhalonium bisulfate is prepared. Reaction is thereafter effected between the diarylhalonium bisulfate and the source of a counterion, such as AsF.sub.6 .sup.- , in the form of the corresponding acid or salt. The halonium salt photoinitiators can be used to make UV curable compositions.

Abstract translation: 提供了一种制备含有可用作光引发剂的第Va族金属六氟化铬的某些二芳基卤鎓盐的方法，例如六氟砷酸二苯基碘鎓。 制备中间体二芳基脲硫酸氢盐。 此后，以相应的酸或盐的形式在二硫酸氢二铵和抗衡离子源（如AsF 6 - ）之间进行反应。 卤盐光引发剂可用于制备紫外光固化组合物。