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公开(公告)号:JPS5133198A
公开(公告)日:1976-03-22
申请号:JP10574474
申请日:1974-09-13
Applicant: KAO CORP
Inventor: MITSUNABE YASUHIKO , KAWAKATSU YASUYUKI , TAKAHASHI SHUNSUI , YAMAGUCHI TAKASHI
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公开(公告)号:JPS6228043A
公开(公告)日:1987-02-06
申请号:JP16726485
申请日:1985-07-29
Applicant: KAO CORP
Inventor: TAKAHASHI SHUNSUI , SAWA MASUO , KIUCHI KAZUHIKO
Abstract: PURPOSE:To improve the productivity of a casting mold by constituting a binder of a resin component consisting of a specific resol type resin alone or mixture composed of said resin and furan resin, etc. and a resin component selected from a prescribed phenolic resin, etc. CONSTITUTION:The resol type resin is obtd. by bringing the un-substd. or substd. monovalent or divalnet phenol compd. alone or the mixture composed of >=2 kinds thereof and aldehyde having >=1.3 molar ratio thereto into condensation reaction. Such resol type resin alone or the mixture composed of said resin and furan resin or the co-condensation product thereof is used as one resin component. The other resin component is then selected from resol type, novolak type phenolic resins, etc. Both components are so mixed so as to satisfy formula [I] to constitute the binder in this case. The initial strength of the casting mold is improved and the productivity of the casting mold is improved by the above-mentioned method.
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公开(公告)号:JPS6221442A
公开(公告)日:1987-01-29
申请号:JP15956285
申请日:1985-07-19
Applicant: KAO CORP
Inventor: KIUCHI KAZUHIKO , TAKAHASHI SHUNSUI , KAWAKATSU YASUYUKI
IPC: B22C1/22
Abstract: PURPOSE:To extend the pot life of system sand and to decrease the stickers to a metallic mold by using a compd. contg. >=2 epoxy groups in a molecule as a binder for a casting mold. CONSTITUTION:The compd. contg. >=2 epoxy groups in a binder is used as an essential component. The compd. having the epoxy groups includes independent compds. such as phenol novolak type epoxy resin and resol novolak type epoxy resin expressed by formulas I, II or a mixture composed of >=2 kinds thereof or the compd. contg. said compds. The pot life of the system sand for the casting mold is extended and the stickers to the metallic mold is decreased if the binder of the compsn. essentially consisting of the above-mentioned compd. is used. In formula I, R is a hydrocarbon group of 1-12C, X is H or methyl group and in formula II, X is -CH2O- or -CH2OCO-.
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公开(公告)号:JPS61235034A
公开(公告)日:1986-10-20
申请号:JP7594285
申请日:1985-04-10
Applicant: KAO CORP
Inventor: SUGA TOSHIYUKI , TAKAHASHI SHUNSUI
Abstract: PURPOSE:To improve the curing speed, strength, etc. of a casting mold by forming a compd. having >=1 aldehyde groups in a molecule of a saccharide, etc. then subjecting the compd. to the reaction with an acid-setting resin, etc. CONSTITUTION:The saccharide such as glucose and starch are oxidized by using an oxidizing agent such as periodic acid or lead chromate to form the compd. contg. >=1 aldehyde groups having high reactivity in the molecule. Such compd. is mixed with or brought into reaction with the acid-setting resin at 2-50wt% ratio, by which the binder compsn. for a casting mold is obtd. The curing speed of the casting mold is increased by the incorporation of the aldehyde having high reactivity in the binder curing reaction in the stage of molding when such binder is used. The surface stability and strength are further improved.
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公开(公告)号:JPH0456025B2
公开(公告)日:1992-09-07
申请号:JP12129883
申请日:1983-07-04
Applicant: KAO CORP
Inventor: TAKAHASHI SHUNSUI , SAWA MASUO
IPC: C08L61/02 , C07C67/00 , C07C301/00 , C07C309/30 , C08L61/00 , C08L61/04 , C08L83/00 , C08L83/02
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公开(公告)号:JPS6352738A
公开(公告)日:1988-03-05
申请号:JP19687886
申请日:1986-08-22
Applicant: KAO CORP
Inventor: YOSHIDA AKIRA , TAKAHASHI SHUNSUI
IPC: B22C1/22
Abstract: PURPOSE:To obtain a binder compsn. for a casting mold which is improved in the compatibility of lignin with a furan resin and storage stability by compounding
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公开(公告)号:JPS62252635A
公开(公告)日:1987-11-04
申请号:JP9407886
申请日:1986-04-23
Applicant: KAO CORP
Inventor: NAKANE SHOJI , TAKAHASHI SHUNSUI
IPC: B22C1/22
Abstract: PURPOSE:To provide substantial strength to a casting mold and to improve the pot life thereof by using NaOH and KOH in combination as the alkali in an alkaline phenol-formaldehyde resin and selecting the molar ratio of NaOH and KOH in a specific range. CONSTITUTION:This binder compsn. is used for a process for producing the gas curable casting mold by using the aq. alkaline phenol-aldehyde resin soln. as a binder and curing the same by an org. ester. The alkali in the aq. alkaline phenol-aldehyde resin soln. consists of NaOh and KOH. The molar ratio between the total molar number of NaOH and KOH and phenol is specified to 0.5:1-1.2:1 and the molar ratio between NaOH and KOH is specified to 5:95-99.5:0.5. The pot life is improved by the above-mentioned binder compsn.
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公开(公告)号:JPS62252633A
公开(公告)日:1987-11-04
申请号:JP9407686
申请日:1986-04-23
Applicant: KAO CORP
Inventor: NAKANE SHOJI , TAKAHASHI SHUNSUI
IPC: B22C1/22
Abstract: PURPOSE:To improve initial strength by using an aq. alkaline phenol- formaldehyde soln. in which a phenol-formaldehyde resin having a specific range of weight average mol. wt. is used as a binder. CONSTITUTION:This binder compsn. is used for a molding method which uses the aq. alkaline phenol-formaldehyde soln. as the binder and cures the same by an org. ester. The compsn. consists of the aq. alkaline phenol-formaldehyde soln. in which the weight average mol. wt. of the phenol-formaldehyde is 2,100-8,000. The initial strength of a casting mold is improved without decreasing the final strength of the casting mold by using the above-mentioned binder compsn.
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