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公开(公告)号:AU612915B2
公开(公告)日:1991-07-18
申请号:AU4563089
申请日:1989-11-28
Applicant: MITSUI TOATSU CHEMICALS
Inventor: YAMAYA NORIMASA , YAMAGUCHI AKIHIRO , OHTA MASAHIRO
IPC: C08F212/34 , C08F12/00 , C08F20/10 , C08F22/36 , C08F222/40 , C08G73/12 , C08G73/00 , C08F299/02
Abstract: This invention provides thermosetting-resin-forming compositions which are formed of (a) a bismaleimide compound represented by the following formula: wherein R represents a divalent group of or X being a direct bond or a group selected from divalent hydrocarbon groups having 1-10 carbon atoms, hexa-fluorinated isopropylidene, carbonyl, thio, sulfinyl, sulfonyl and oxo, and (b) a specific diallylbisphenol compound. These compositions can provide thermosetting resins having high cracking resistance due to improved impact resistance and toughness and low water absorption.
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公开(公告)号:AU611801B2
公开(公告)日:1991-06-20
申请号:AU3489589
申请日:1989-05-17
Applicant: MITSUI TOATSU CHEMICALS
Inventor: YAMAYA NORIMASA , OHTA MASHIRO , YAMAGUCHI AKIHIRO
Abstract: The present invention relates to thermosetting resin compositions comprising a bismaleimide compound represented by the formula (I) and an aromatic amine resin represented by the general formula (II) and to processes for preparing the same. g
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公开(公告)号:AU579511B2
公开(公告)日:1988-11-24
申请号:AU7235687
申请日:1987-04-08
Applicant: MITSUI TOATSU CHEMICALS
Inventor: YAMAYA NORIMASA , KOGA NOBUHITO , BABA KENICHI
Abstract: New polyimide resin compsn. is composed of 100 pts. by wt. of a polyimide having repeat units represented by general formula (I) and 5 to 100 pts. by wt. of fibrous reinforcing material, where Y represents a direct bond, a divalent 1-10C hydrocarbyl gp., a hexafluoroisopropylidene gp., a carbonyl gp., or a oxido gp. R represents a tetravalent 2 or more C aliphatic gp., an alicyclic gp., a monocyclic aromatic gp., a fused polycyclic aromatic gp., or a non-fused cyclic aromatic gp. in which aromatic gps. are linked direct to each other or via a linking member. The polyimide can have an isopropylidene gp. for Y in general formula (1), it can have a direct bond for Y and (II) for R, it can have an isopropylidene gp. for Y and (III) for R, etc. The fibrous reinforcing material can be glass fibres, carbon fibres, potassium titanate fibres or aromatic polyamide fibres.
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公开(公告)号:AU7552387A
公开(公告)日:1988-01-21
申请号:AU7552387
申请日:1987-07-10
Applicant: MITSUI TOATSU CHEMICALS
Inventor: YAMAYA NORIMASA
Abstract: 1. A thermosetting resin composition which comprises a bismaleimide derivative having the formula (I): and a diamine derivative having the formula (II): wherein R is a divalent radical represented by or where X is selected from a bond, a divalent hydrocarbon radical having 2 carbon atoms, hexafluorinated isopropylidene radical, carbonyl radical, thio radical and sulfinyl radical. A thermosetting resin prepolymer may be obtained by conducting heat-treatment of the thermosetting resin composition at a temperature of 70 to 220 DEG C in the presence or absence of a solvent.
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公开(公告)号:CA2028312C
公开(公告)日:1996-03-12
申请号:CA2028312
申请日:1990-10-23
Applicant: MITSUI TOATSU CHEMICALS
Inventor: YAMAYA NORIMASA , TAMAI SHOJI , OHTA MASAHIRO , YAMAGUCHI AKIHIRO
IPC: C08G73/12
Abstract: Disclosed is a composition for forming a thermosetting resin having excellent impact resistance and toughness. The composition comprises a bismaleimide compound represented by formula (I): (I) wherein R is a hydrogen atom or methyl, and an amine compound represented by formula (II): (II) wherein X is a radical selected from the group of divalent hydrocarbons having from 1 to 10 carbon atoms, hexafluorinated isopropylidene, carbonyl, thio, sulfinyl, sulfonyl, oxo, and O-, or by formula (III)): (III) wherein n is an integer of 0 to 50. Also disclosed is a process for preparing the composition.
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公开(公告)号:DE68915407T2
公开(公告)日:1994-12-01
申请号:DE68915407
申请日:1989-11-27
Applicant: MITSUI TOATSU CHEMICALS
Inventor: YAMAYA NORIMASA , OHTA MASAHIRO , YAMAGUCHI AKIHIRO
IPC: C08F212/34 , C08F12/00 , C08F20/10 , C08F22/36 , C08F222/40 , C08G73/12
Abstract: This invention provides thermosetting-resin-forming compositions which are formed of (a) a bismaleimide compound represented by the following formula: wherein R represents a divalent group of or X being a direct bond or a group selected from divalent hydrocarbon groups having 1-10 carbon atoms, hexa-fluorinated isopropylidene, carbonyl, thio, sulfinyl, sulfonyl and oxo, and (b) a specific diallylbisphenol compound. These compositions can provide thermosetting resins having high cracking resistance due to improved impact resistance and toughness and low water absorption.
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公开(公告)号:DE3883134T2
公开(公告)日:1994-04-14
申请号:DE3883134
申请日:1988-10-06
Applicant: MITSUI TOATSU CHEMICALS
Inventor: YAMAGUCHI KEIZABURO , TANABE YOSHIMITSU , URAKAMI TATSUHIRO , YAMAGUCHI AKIHIRO , YAMAYA NORIMASA , OHTA MASAHIRO
IPC: C07C211/50 , C08G73/10 , C08G73/12 , C08L79/04 , C08G73/02
Abstract: Disclosed herein is an aromatic amine resin formed of a mixture of aromatic amine compounds represented by the following general formula (a): wherein A means a phenylene, alkyl-substituted phenylene, diphenylene, diphenyl ether or naphthylenyl group, R denotes a halogen atom or a hydroxyl, C1-4 alkoxy or C1-5 alkyl group, l stands for 1 or 2, m is an integer of 0-3, when m is 2 or 3, R s may be the same or different and two of R s may join together into a 5- to 6-membered alicyclic moiety which may optionally contain one or more side chains, and n stands for an integer of 0-300.
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公开(公告)号:DE68906459T2
公开(公告)日:1994-01-05
申请号:DE68906459
申请日:1989-05-16
Applicant: MITSUI TOATSU CHEMICALS
Inventor: YAMAYA NORIMASA , OHTA MASAHIRO , YAMAGUCHI AKIHIRO
IPC: C08K5/3415 , C08K5/375 , C08K5/41 , C08K5/00 , C08L79/08
Abstract: The present invention relates to a thermosetting resin composition comprising about 100 parts by weight of a polyimide and from 5 to about 100 parts by weight of a bismaleimide having a similar structure and processes for preparing the same.
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公开(公告)号:DE68908009D1
公开(公告)日:1993-09-09
申请号:DE68908009
申请日:1989-05-17
Applicant: MITSUI TOATSU CHEMICALS
Inventor: YAMAYA NORIMASA , OHTA MASAHIRO , YAMAGUCHI AKIHIRO
IPC: C08G73/12
Abstract: The present invention relates to thermosetting resin compositions comprising a bismaleimide compound represented by the formula (I) and an aromatic amine resin represented by the general formula (II) and to processes for preparing the same. g
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公开(公告)号:DE3784842D1
公开(公告)日:1993-04-22
申请号:DE3784842
申请日:1987-04-08
Applicant: MITSUI TOATSU CHEMICALS
Inventor: YAMAYA NORIMASA , KOGA NOBUHITO , BABA KENICHI
Abstract: New polyimide resin compsn. is composed of 100 pts. by wt. of a polyimide having repeat units represented by general formula (I) and 5 to 100 pts. by wt. of fibrous reinforcing material, where Y represents a direct bond, a divalent 1-10C hydrocarbyl gp., a hexafluoroisopropylidene gp., a carbonyl gp., or a oxido gp. R represents a tetravalent 2 or more C aliphatic gp., an alicyclic gp., a monocyclic aromatic gp., a fused polycyclic aromatic gp., or a non-fused cyclic aromatic gp. in which aromatic gps. are linked direct to each other or via a linking member. The polyimide can have an isopropylidene gp. for Y in general formula (1), it can have a direct bond for Y and (II) for R, it can have an isopropylidene gp. for Y and (III) for R, etc. The fibrous reinforcing material can be glass fibres, carbon fibres, potassium titanate fibres or aromatic polyamide fibres.
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