公开(公告)号：MXPA03000783A

公开(公告)日：2003-09-10

申请号：MXPA03000783

申请日：2001-05-15

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES F JR

IPC: C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

公开(公告)号：ZA200106072B

公开(公告)日：2002-10-24

申请号：ZA200106072

申请日：2001-07-24

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES F JR

IPC: B01J23/22 ,  B01J23/847 ,  B01J23/85 ,  B01J23/88 ,  B01J23/887 ,  C07B61/00 ,  C07C253/24 ,  C07C255/08 ,  C07C ,  B01J

Abstract: A process of manufacturing acrylonitrile or methacrylonitrile by the catalytic reaction in the vapor phase of a paraffin selected from propane and isobutane with molecular oxygen and ammonia by catalytic contact of the reactants in a reaction zone with a catalyst, the feed composition having a mole ratio of the paraffin to ammonia in the range of from about 2.5 to 16 and a mole ratio of paraffin to oxygen in the range of from about 1.0 to 10, wherein said catalyst has the elements in the proportions indicated by the empirical formula: VSbmAaDbQqRrOx where A is one or more of Ti, Sn, Fe, Cr and Ga; D is one or more of Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Zr, Cu, Ta, Bi, Ce, In, B and Mn; Q is one or more of Mo, W, and Nb; R is one or more of As, Te, and Se; m equals 0.8 to 4; a equals 0.01 to 2; d is 0 to 2; 0

公开(公告)号：CA2416712A1

公开(公告)日：2002-02-14

申请号：CA2416712

申请日：2001-05-15

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES F JR ,  PADOLEWSKI JOSEPH P

IPC: C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

Abstract: The invention is a method for the reduction of ammonia breakthrough during t he manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propane and isobutane; ammonia and an oxygen- containing gas into a lower portion of a fluid-bed reactor containing an ammoxidation catalyst to react in the presence of said catalyst to produce acrylonitrile. The method comprises introducing into the reactor at least on e C2 to C5 olefin which will react with at least a portion of the unreacted ammonia and oxygen present in the reactor to substantially reduce the amount of ammonia present in the reactor effluent exiting the reactor.

公开(公告)号：BR0008070A

公开(公告)日：2002-02-05

申请号：BR0008070

申请日：2000-01-18

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES F JR

IPC: B01J23/85 ,  B01J23/22 ,  B01J23/847 ,  B01J23/88 ,  B01J23/887 ,  C07B61/00 ,  C07C253/24 ,  C07C255/08 ,  B01J23/28

Abstract: A process of manufacturing acrylonitrile or methacrylonitrile by the catalytic reaction in the vapor phase of a paraffin selected from propane and isobutane with molecular oxygen and ammonia by catalytic contact of the reactants in a reaction zone with a catalyst, the feed composition having a mole ratio of the paraffin to ammonia in the range of from about 2.5 to 16 and a mole ratio of paraffin to oxygen in the range of from about 1.0 to 10, wherein said catalyst has the elements in the proportions indicated by the empirical formula: VSbmAaDbQqRrOx where A is one or more of Ti, Sn, Fe, Cr and Ga; D is one or more of Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Zr, Cu, Ta, Bi, Ce, In, B and Mn; Q is one or more of Mo, W, and Nb; R is one or more of As, Te, and Se; m equals 0.8 to 4; a equals 0.01 to 2; d is 0 to 2; 0

公开(公告)号：CA2416712C

公开(公告)日：2009-12-01

申请号：CA2416712

申请日：2001-05-15

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES F JR ,  PADOLEWSKI JOSEPH P

IPC: C07C253/24 ,  C07B61/00 ,  C07C253/26 ,  C07C253/32 ,  C07C255/08

Abstract: The invention is a method for the reduction of ammonia breakthrough during t he manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propane and isobutane; ammonia and an oxygen- containing gas into a lower portion of a fluid-bed reactor containing an ammoxidation catalyst to react in the presence of said catalyst to produce acrylonitrile. The method comprises introducing into the reactor at least on e C2 to C5 olefin which will react with at least a portion of the unreacted ammonia and oxygen present in the reactor to substantially reduce the amount of ammonia present in the reactor effluent exiting the reactor.

公开(公告)号：MY119391A

公开(公告)日：2005-05-31

申请号：MYPI9703372

申请日：1997-07-24

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES F JR ,  PADOLEWSKI JOSEPH P ,  CAVALCANTI FERNANDO A P

IPC: B01J23/16 ,  B01J23/843 ,  B01J23/847 ,  B01J37/02 ,  C07C253/24

Abstract: A METHOD OF MAKING A CATALYST HAVING THE FOLLOWING EMPIRICAL FORMULA: VSBMAADDOX WHERE A = SN, TI OR MIXTURES THEREOF, D = AT LEAST ONE ELEMENT SELECTED FROM LI, MG, NA, CA, SR, BA, CO, FE, CR, GA, NI, ZN, GE, NB, MO, W, CU, TI, TA, SE, BI, CE, IN, AS, B, AL, AND MN, AND WHEREIN M = 0.5 TO 10 A = 0 TO 10 D = 0 TO 10 X = NUMBER OF OXYGEN ATOMS NECESSARY TO SATISFY THE VALENCY REQUIREMENTS OF THE OTHER ELEMENTS, COMPRISING REACTING A MONOPEROXOVANADIUM ION, VO(O2)+, WHILE IN AQUEOUS SOLUTION WITH A FIRST PORTION OF AN SB COMPOUND WHICH CONTAINS SB, HAVING A VALENCE OF 3+, THEREBY REDUCING THE AVERAGE VALENCE OF THE V TO LESS THAN 5+ AND OXIDIZING SB TO A VALENCE STATE OF 5+, REMOVING THE WATER FROM THE SOLUTION TO FORM A DRIED CATALYST PRECURSOR, AND CALCINING THE RESULTING DRIED PRECURSOR AT A TEMPERATURE IN THE RANGE OF 650° TO 950°C TO FORM THE CATALYST, WHEREIN THE MPROVEMENT COMPRISES ADDING AT LEAST A SECOND PORTION OF AN SB COMPOUND AFTER THE FIRST PORTION OF SB COMPOUND HAS BEEN ADDED AND HAS AT LEAST PARTIALLY REACTED WITH THE MONOPEROXOVANADIUM ION.

公开(公告)号：ES2208271T3

公开(公告)日：2004-06-16

申请号：ES00903329

申请日：2000-01-18

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES F JR

IPC: B01J23/22 ,  B01J23/847 ,  B01J23/88 ,  B01J23/85 ,  B01J23/887 ,  C07B61/00 ,  C07C253/24 ,  C07C255/08 ,  B01J23/28

Abstract: A process of manufacturing acrylonitrile or methacrylonitrile by the catalytic reaction in the vapor phase of a paraffin selected from propane and isobutane with molecular oxygen and ammonia by catalytic contact of the reactants in a reaction zone with a catalyst, the feed composition having a mole ratio of the paraffin to ammonia in the range of from about 2.5 to 16 and a mole ratio of paraffin to oxygen in the range of from about 1.0 to 10, wherein said catalyst has the elements in the proportions indicated by the empirical formula: VSbmAaDbQqRrOx where A is one or more of Ti, Sn, Fe, Cr and Ga; D is one or more of Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Zr, Cu, Ta, Bi, Ce, In, B and Mn; Q is one or more of Mo, W, and Nb; R is one or more of As, Te, and Se; m equals 0.8 to 4; a equals 0.01 to 2; d is 0 to 2; 0

公开(公告)号：CA1330985C

公开(公告)日：1994-07-26

申请号：CA580734

申请日：1988-10-20

Applicant: STANDARD OIL CO OHIO

Inventor： TOFT MARK A ,  BRAZDIL JAMES F JR ,  GLAESER LINDA C

IPC: B01J23/18 ,  B01J23/22 ,  C07C253/00 ,  C07C253/24 ,  C07C255/00

Abstract: Disclosed is a method of making a catalyst precursor by reacting the ion VO(O2)+ in aqueous solution with an antimony compound that contains Sb having a valence of 3. In one embodiment, the VO(O2)+ ion is made by reacting H2O2 with a vanadium compound. Also disclosed is making a catalyst by drying and calcining such precursor. When the drying is effected by spray drying a new microspheroidal catalyst is produced. The catalysts useful for ammoxidation of propane are more attrition resistant than catalysts of the same empirical formula made by prior art methods.