公开(公告)号：JPH11310562A

公开(公告)日：1999-11-09

申请号：JP8261299

申请日：1999-03-25

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK JR ,  TOFT MARK A

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/28 ,  B01J23/887 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08

Abstract: PROBLEM TO BE SOLVED: To provide an improved process for ammoxidation from a paraffin into an unsaturated mononitrile and corresponding monoolefin. SOLUTION: This process is to synthesize acrylonitrile or methacrylonitrile by a catalytic reaction of a paraffin selected from between propane and isobutane in the vapor phase according to a catalytic contact of a catalyst with a reactional component in a reactional zone of oxygen molecules with ammonia. The feed composition has a molar ratio of the paraffin to the ammonia within the range of about 2.5-16 and a molar ratio of the paraffin to the oxygen within the range of about 1.0-10. The catalyst contains elements in a ratio represented by the empirical formula VSbm Aa Mob Dd Ox [A is one or more kinds of Ti, Sn, Fe, Cr and Ga; D is one or more kinds of Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Nb, Zr, W, Cu, The, Ta, Se, Bi, Ce, In, As, B and Mn; (m) is 0.8-4; (a) is 0.01-2; 0

公开(公告)号：BG103280A

公开(公告)日：2000-02-29

申请号：BG10328099

申请日：1999-03-25

Applicant: STANDARD OIL CO OHIO

Inventor： TOFT MARK A

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/28 ,  B01J23/887 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08 ,  B01J27/00

Abstract: The invention relates to the production of acrylonitrile or methacrylonitrile by catalytic reaction in paraffin steam phase selected between propane and isobutane with molecular oxygen and ammonia at catalytic contact between the reagents and the catalyst in the reaction zone. The burden composition has molar ratio of paraffin to ammonia from 2.5 to 16 and paraffin to oxygen molar ratio from 1 to 10. The elements and the proportions of the catalyst are determined by the empiric formula VSbmAaMobDdOx where A means one or more of the elements Ti, Sn, Fe, Cr and Ga; D isone or more of the elements Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Nb, Zr, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B and Mn; m has the value of 0.8 to 4; a is from 0.01 to 2; 0

公开(公告)号：CA1330985C

公开(公告)日：1994-07-26

申请号：CA580734

申请日：1988-10-20

Applicant: STANDARD OIL CO OHIO

Inventor： TOFT MARK A ,  BRAZDIL JAMES F JR ,  GLAESER LINDA C

IPC: B01J23/18 ,  B01J23/22 ,  C07C253/00 ,  C07C253/24 ,  C07C255/00

Abstract: Disclosed is a method of making a catalyst precursor by reacting the ion VO(O2)+ in aqueous solution with an antimony compound that contains Sb having a valence of 3. In one embodiment, the VO(O2)+ ion is made by reacting H2O2 with a vanadium compound. Also disclosed is making a catalyst by drying and calcining such precursor. When the drying is effected by spray drying a new microspheroidal catalyst is produced. The catalysts useful for ammoxidation of propane are more attrition resistant than catalysts of the same empirical formula made by prior art methods.

公开(公告)号：CA2056923A1

公开(公告)日：1992-06-22

申请号：CA2056923

申请日：1991-12-04

Applicant: STANDARD OIL CO OHIO

Inventor： LYNCH CHARLES S ,  GLAESER LINDA C ,  BRAZDIL JAMES F ,  TOFT MARK A

IPC: B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/28 ,  B01J23/34 ,  B01J23/843 ,  B01J23/847 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C253/24 ,  C07C255/08

Abstract: -13- CSL-P-3611 Disclosed is a process for making an activated antimony and vanadiumcontaining catalyst in oxide form having an atomic ratio of Sb:V in the range from 0.8-4, which comprises calcining such an oxidic vanadium and antimony-containing composition at a temperature of over 750.degree.C, and thereafter contacting said calcined catalyst with a hydroxy compound in liquid form selected from (1) cyclohexanol, (2) cyclopentanol, (3) a monohydroxy, acyclic hydrocarbon having 1-8 C atoms, and (4) a dihydroxy, acyclic hydrocarbon having 2-4 carbon atoms, and separating as a liquid said compound from said catalyst insofar as it is present beyond the amount wetting said catalyst, and thereafter drying said catalyst. Applns.AX7 Applns.AX8

公开(公告)号：CA2055739A1

公开(公告)日：1992-06-04

申请号：CA2055739

申请日：1991-11-18

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES F ,  GLAESER LINDA C ,  TOFT MARK A

IPC: B01J23/84 ,  B01J23/847 ,  B01J23/85 ,  B01J23/89 ,  B01J27/057 ,  B01J27/198 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/07 ,  C07C255/08

Abstract: CSL-P-3645 Disclosed is a process for making an a , .beta.-unsaturated mononitrile by the catalytic reaction of a paraffin containing 3-5 carbon atoms with molecular oxygen and ammonia by catalytic contact of the foregoing reactants in a reaction zone with a metal oxide catalyst containing the elements indicated by the empirical formula, Vv Aa DdSnm Sbn CUc0x (formula 1) in the relative atomic proportions indicated by the subscripts, where A is selected from Te and Bi D is one or more optional elements selected from Mo, W, Ti, Ge, Ce, La, Cr, Mn, Mg, Ca, Co, Ni, Fe, Nb, Ta, Ag, Zn, Cd, B, P, Na, K and Cs, and a is 0.001 to 30 d is zero to 30 c is 0.001 to 30 m is 0.1 to 60 n is 0.1 to 60 n/v is > 12 and v + a + c + d, and x is determined by the valence requirements of the elements present, and wherein the reactants fed to the reaction zone contain a mole ratio of said paraffin:NH3 in the range from 2 to 16 and a mole ratio of said paraffin:02 in the range from 1 to 10. Applns.AZ5