公开(公告)号：PT66875B

公开(公告)日：1979-01-23

申请号：PT6687577

申请日：1977-08-01

Applicant: STANDARD OIL CO OHIO

Inventor： HARDMAN HARLEY FOCH ,  GRASSELLI ROBERT KARL ,  CALLAHAN JAMES LOUIS

IPC: C07C57/05 ,  B01J23/00 ,  B01J23/88 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/00 ,  C07C45/00 ,  C07C45/27 ,  C07C45/32 ,  C07C45/33 ,  C07C45/34 ,  C07C45/37 ,  C07C47/22 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08

Abstract: The present invention relates to a process for the conversion of tertiary-butyl-containing compounds to methacrylic derivatives, and more particularly to a process for the conversion of tertiary-butyl-containing compounds selected from the group consisting of alkyl tertiary-butyl ethers, tertiary-butyl alcohol, isobutylene dimer (2,2,4-trimethylpentene) and isobutylene trimer, to methacrolein, methacrylic acid or methacrylonitrile.

公开(公告)号：DE2732952A1

公开(公告)日：1978-02-09

申请号：DE2732952

申请日：1977-07-21

Applicant: STANDARD OIL CO OHIO

Inventor： HARDMAN HARLEY FOCH ,  GRASSELLI ROBERT KARL ,  CALLAHAN JAMES LOUI

IPC: C07C57/05 ,  B01J23/00 ,  B01J23/88 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/00 ,  C07C45/00 ,  C07C45/27 ,  C07C45/32 ,  C07C45/33 ,  C07C45/34 ,  C07C45/37 ,  C07C47/22 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C47/20 ,  C07C45/04 ,  C07C121/32 ,  C07C120/14

Abstract: The present invention relates to a process for the conversion of tertiary-butyl-containing compounds to methacrylic derivatives, and more particularly to a process for the conversion of tertiary-butyl-containing compounds selected from the group consisting of alkyl tertiary-butyl ethers, tertiary-butyl alcohol, isobutylene dimer (2,2,4-trimethylpentene) and isobutylene trimer, to methacrolein, methacrylic acid or methacrylonitrile.

公开(公告)号：NO772723A

公开(公告)日：1978-02-03

申请号：NO772723

申请日：1977-08-01

Applicant: STANDARD OIL CO OHIO

Inventor： HARDMAN HARLEY FOCH ,  GRASSELLI ROBERT KARL ,  CALLAHAN JAMES LOUIS

IPC: C07C57/05 ,  B01J23/00 ,  B01J23/88 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/00 ,  C07C45/00 ,  C07C45/27 ,  C07C45/32 ,  C07C45/33 ,  C07C45/34 ,  C07C45/37 ,  C07C47/22 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C

CPC classification number: B01J23/8876 ,  B01J2523/00 ,  C07C45/27 ,  C07C45/32 ,  C07C45/33 ,  C07C45/34 ,  C07C45/37 ,  C07C51/235 ,  C07C51/252 ,  C07C253/24 ,  Y02P20/52 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/41 ,  B01J2523/15 ,  B01J2523/53 ,  C07C255/08

公开(公告)号：DE2530959A1

公开(公告)日：1976-02-05

申请号：DE2530959

申请日：1975-07-11

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  SURESH DEV DHANARAJ ,  HARDMAN HARLEY FOCH

IPC: B01J23/00 ,  B01J23/88 ,  B01J23/881 ,  B01J23/887 ,  B01J23/89 ,  B01J27/057 ,  B01J27/186 ,  B01J27/192 ,  C07B31/00 ,  C07B33/00 ,  C07B35/04 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/12 ,  C07C27/00 ,  C07C27/14 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C253/26 ,  C07C255/08 ,  B01J37/00 ,  B01J23/10

公开(公告)号：DE2424934A1

公开(公告)日：1975-01-02

申请号：DE2424934

申请日：1974-05-22

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  MILLER ARTHUR FRANCIS ,  SURESH DEV DHANARAJ ,  HARDMAN HARLEY FOCH

IPC: B01J21/00 ,  B01J23/00 ,  B01J23/88 ,  B01J23/881 ,  B01J23/89 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C121/32

公开(公告)号：AU554328B2

公开(公告)日：1986-08-14

申请号：AU1689383

申请日：1983-07-15

Applicant: STANDARD OIL CO OHIO

Inventor： VELENYI LOUIS JOSEPH ,  HARDMAN HARLEY FOCH ,  PESA FRED ANTHONY

IPC: B01J23/00 ,  C01C3/02

Abstract: A process for producing HCN by contacting CO and NH3 with a catalyst comprising a porous catalyst support, a Group VIII metal which is at least one of Fe, Ni, Co and Ru, and carbon, wherein the metal is disposed on the pore surfaces of the support and the carbon is randomly bonded to the metal.

公开(公告)号：DE3267173D1

公开(公告)日：1985-12-05

申请号：DE3267173

申请日：1982-08-09

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  BURRINGTON JAMES DAVID ,  PESA FREDERICK ANTHONY ,  HARDMAN HARLEY FOCH

IPC: B01J31/00 ,  B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  C07C67/00 ,  C07C253/00 ,  C07C255/04 ,  C07C255/09 ,  C07D307/60 ,  C07C120/00 ,  C07C121/26 ,  C07C121/30 ,  B01J31/06

Abstract: A process for dimerizing acrylonitrile to produce adiponitrile and/or 1,4-dicyanobutenes comprises contacting acrylonitrile with a catalyst at a temperature of 20 to 250 DEG C in the presence of hydrogen, said catalyst comprising a polymer support having a ruthenium complex bonded thereto, said polymer support comprising an organic polymer backbone having trivalent pendant atoms selected from P, As, Sb, Bi and N covalently bonded thereto and randomly distributed in said polymer, said ruthenium complex being capable of catalyzing the dimerization of acrylonitrile to adiponitrile and/or 1,4-dicyanobutenes and comprising Ru and at least two homogeneous ligands having at least four ligating bonds bonding to said Ru, the Ru in each ruthenium complex datively bonding to a pendant atom in said polymer support, the Ru/pendant atom ratio in said catalyst being at least 0.001, said complex having on the average no more than one homogeneous phosphine ligand per atom of ruthenium. … Preferred ruthenium complexes are those which are substantially free of homogeneous phosphine ligands. The organic polymer support can be a terpolymer of 2-20% divinyl benzene, 0.4 to 6% para-diphenylphosphenostyrene and the balance styrene.

公开(公告)号：DE3061920D1

公开(公告)日：1983-03-17

申请号：DE3061920

申请日：1980-10-16

Applicant: STANDARD OIL CO OHIO

Inventor： HARDMAN HARLEY FOCH ,  SCHWERKO ALBERT PETER

IPC: C07C45/80 ,  C07C45/81 ,  C07C47/22 ,  C07C51/48 ,  C07C57/04 ,  C07C121/32

公开(公告)号：CH616861A5

公开(公告)日：1980-04-30

申请号：CH952175

申请日：1975-07-21

Applicant: STANDARD OIL CO

Inventor： GRASSELLI ROBERT KARL ,  SURESH DEV DHANARAJ ,  HARDMAN HARLEY FOCH

IPC: B01J23/00 ,  B01J23/88 ,  B01J23/881 ,  B01J23/887 ,  B01J23/89 ,  B01J27/057 ,  B01J27/186 ,  B01J27/192 ,  C07B31/00 ,  C07B33/00 ,  C07B35/04 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/12 ,  C07C27/00 ,  C07C27/14 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C253/26 ,  C07C255/08 ,  B01J23/76

公开(公告)号：ATA544975A

公开(公告)日：1979-06-15

申请号：AT544975

申请日：1975-07-15

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  SURESH DEV DHANARAJ ,  HARDMAN HARLEY FOCH

IPC: B01J23/00 ,  B01J23/88 ,  B01J23/881 ,  B01J23/887 ,  B01J23/89 ,  B01J27/057 ,  B01J27/186 ,  B01J27/192 ,  C07B31/00 ,  C07B33/00 ,  C07B35/04 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/12 ,  C07C27/00 ,  C07C27/14 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C253/26 ,  C07C255/08