公开(公告)号：AU572363B2

公开(公告)日：1988-05-05

申请号：AU4995185

申请日：1985-11-15

Applicant: STANDARD OIL CO OHIO

Inventor： DESMOND MICHAEL JOSEPH ,  PESA FREDERICK ANTHONY

IPC: C01B33/20 ,  B01J29/04 ,  C01B35/10 ,  C01B39/06 ,  C07B61/00 ,  C07C1/20 ,  C07C5/27 ,  C07C15/073 ,  C07C15/08 ,  C01B33/28

Abstract: A method for preparing a molecular sieving metallosilicate is disclosed which comprises(A) providing a mixture comprising: water, an oxide of silicon source; a mineralizing agent and/or synthesis directing agent; and a heteropolymetallate of the formulawhereinA is an ion selected from the group consisting of hydrogen; one or more of the Group I-A to VI-A or Group I-B to VI-B metals; one or more of the rare earth metals; ammonium, alkyl ammonium, alkyl phosphonium or aikyl arsonium; or a mixture of two or more thereof;M isZn, Ga, Ge, Ti, Cr, Mn, Fe, Co, B, Ni, Rh, Zr or a mixture of two or more thereof;L is P, As, Si, Al, H or a mixture of two or more thereof;J is Mo, W, V, Nb or a mixture of two or more thereof;a is a number which when multiplied by the charge of A will result in balancing the charge on the complex within the brackets;I is a number ranging from zero to about 20;m is a number ranging from zero to about 20;z is a number ranging from about 1 to about 50;y is a number ranging from about 7 to about 150: d is a number ranging from about zero to about 150; and(B) maintaining said mixture at a temperature of about 80°C to about 300°C for an effective period of to form said molecular sieving metallosilicate.

公开(公告)号：MX155549A

公开(公告)日：1988-03-25

申请号：MX18264780

申请日：1980-06-05

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK ANTHONY ,  GRAHAM ANNE MARIE

IPC: C07D223/10 ,  B01J23/00 ,  B01J23/64 ,  B01J23/84 ,  B01J23/89 ,  C07B61/00 ,  C07D201/02 ,  C07D201/08 ,  C07D207/263 ,  C07D211/76

公开(公告)号：DE3278031D1

公开(公告)日：1988-03-03

申请号：DE3278031

申请日：1982-12-17

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK ANTHONY ,  GRAHAM ANNE MARIE

IPC: B01J23/89 ,  B01J27/24 ,  C07C1/04 ,  C07C9/00 ,  C07C29/157 ,  C07C29/158 ,  C07C31/04 ,  C07C31/08 ,  C07C51/10 ,  C07C27/20 ,  C07C29/15 ,  C07C29/14 ,  C07C29/136

Abstract: Catalysts comprising the mixed oxides of ruthenium, copper, at least onc alkali metal and at least one of rhodium, iridium, palladium, and platinum are disclosed which are useful in the upgrading of synthesis gas, particularly for obtaining alkanes and alcohols.

公开(公告)号：AU6512686A

公开(公告)日：1987-02-12

申请号：AU6512686

申请日：1986-11-13

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK ANTHONY ,  GRAHAM ANNE MARIE

IPC: B01J23/89 ,  B01J27/24 ,  C07C1/04 ,  C07C9/00 ,  C07C29/157 ,  C07C29/158 ,  C07C31/04 ,  C07C31/08 ,  C07C51/10 ,  C07C29/15

Abstract: Catalysts comprising the mixed oxides of ruthenium, copper, at least onc alkali metal and at least one of rhodium, iridium, palladium, and platinum are disclosed which are useful in the upgrading of synthesis gas, particularly for obtaining alkanes and alcohols.

公开(公告)号：DE3063922D1

公开(公告)日：1983-07-28

申请号：DE3063922

申请日：1980-12-15

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK ANTHONY ,  HAASE THOMAS ALAN

IPC: B01J31/20 ,  B01J31/22 ,  C07B61/00 ,  C07C45/00 ,  C07C45/49 ,  C07C45/50 ,  C07C67/00 ,  C07C253/00 ,  C07C255/17 ,  C09B47/04 ,  C07F15/06

Abstract: A novel catalyst composition useful in hydroformylation reactions comprises cobalt carbonyl and a porphyrin promoter ligand. Aldehydes may be manufactured in increased yield at less severe operating conditions by contacting an olefinically unsaturated compound, carbon monoxide and hydrogen in the presence of such catalyst. A representative porphyrin promoter ligand is meso-tetra-(4-carboxyphenyl) porphyrin. Where acrylonitrile is used as the olefinically unsaturated compound, the product is 3-cyanopropionaldehyde.

公开(公告)号：DE3585272D1

公开(公告)日：1992-03-05

申请号：DE3585272

申请日：1985-11-06

Applicant: STANDARD OIL CO OHIO

Inventor： DESMOND MICHAEL JOSEPH ,  CURRIE JANIE KAMMENOF ,  PESA FREDERICK ANTHONY

IPC: C01B39/04 ,  B01J29/18 ,  C01B39/06 ,  C01B39/26 ,  C01B33/34

公开(公告)号：IN158966B

公开(公告)日：1987-02-28

申请号：IN463DE1983

申请日：1983-07-06

Applicant: STANDARD OIL CO OHIO

Inventor： VELENYI LOUIS JOSEPH ,  HARDMAN HARLEY FOCH ,  PESA FREDERICK ANTHONY

IPC: B01J23/00 ,  C01C3/02

Abstract: A process for producing HCN by contacting CO and NH3 with a catalyst comprising a porous catalyst support, a Group VIII metal which is at least one of Fe, Ni, Co and Ru, and carbon, wherein the metal is disposed on the pore surfaces of the support and the carbon is randomly bonded to the metal.

公开(公告)号：AU557908B2

公开(公告)日：1987-01-15

申请号：AU9091982

申请日：1982-11-26

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK ANTHONY ,  GRAHAM ANNE MARIE

IPC: B01J23/89 ,  B01J27/24 ,  C07C1/04 ,  C07C9/00 ,  C07C29/157 ,  C07C29/158 ,  C07C31/04 ,  C07C31/08 ,  C07C51/10

Abstract: Catalysts comprising the mixed oxides of ruthenium, copper, at least onc alkali metal and at least one of rhodium, iridium, palladium, and platinum are disclosed which are useful in the upgrading of synthesis gas, particularly for obtaining alkanes and alcohols.

公开(公告)号：AU4995185A

公开(公告)日：1986-05-22

申请号：AU4995185

申请日：1985-11-15

Applicant: STANDARD OIL CO OHIO

Inventor： DESMOND MICHAEL JOSEPH ,  PESA FREDERICK ANTHONY

IPC: C01B33/20 ,  B01J29/04 ,  C01B35/10 ,  C01B39/06 ,  C07B61/00 ,  C07C1/20 ,  C07C5/27 ,  C07C15/073 ,  C07C15/08 ,  C01B33/28

Abstract: A method for preparing a molecular sieving metallosilicate is disclosed which comprises(A) providing a mixture comprising: water, an oxide of silicon source; a mineralizing agent and/or synthesis directing agent; and a heteropolymetallate of the formulawhereinA is an ion selected from the group consisting of hydrogen; one or more of the Group I-A to VI-A or Group I-B to VI-B metals; one or more of the rare earth metals; ammonium, alkyl ammonium, alkyl phosphonium or aikyl arsonium; or a mixture of two or more thereof;M isZn, Ga, Ge, Ti, Cr, Mn, Fe, Co, B, Ni, Rh, Zr or a mixture of two or more thereof;L is P, As, Si, Al, H or a mixture of two or more thereof;J is Mo, W, V, Nb or a mixture of two or more thereof;a is a number which when multiplied by the charge of A will result in balancing the charge on the complex within the brackets;I is a number ranging from zero to about 20;m is a number ranging from zero to about 20;z is a number ranging from about 1 to about 50;y is a number ranging from about 7 to about 150: d is a number ranging from about zero to about 150; and(B) maintaining said mixture at a temperature of about 80°C to about 300°C for an effective period of to form said molecular sieving metallosilicate.

公开(公告)号：DE3168182D1

公开(公告)日：1985-02-21

申请号：DE3168182

申请日：1981-10-07

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK ANTHONY ,  HAASE THOMAS ALAN

IPC: C07C53/124 ,  B01J27/00 ,  B01J31/00 ,  B01J31/28 ,  C07C51/00 ,  C07C51/14 ,  C07C67/00

Abstract: A process for the selective hydrocarboxylation of propylene to produce predominantly isobutyric acid in the liquid phase comprising reacting propylene, carbon monoxide and water at a temperature of from 75 DEG C to 150 DEG C and at a pressure of 250 psi (17.5 kg/cm ) to 5000 psi (350 kg/cm ) in the presence of a suitable solvent and a catalyst comprising palladium or a palladium compound, a phosphoamine promoter ligand compound and a hydrogen halide. In this way better yields of isobutyric acid are obtained.