公开(公告)号：CA1151138A

公开(公告)日：1983-08-02

申请号：CA360211

申请日：1980-09-12

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK A ,  GRAHAM ANNE M

IPC: C07D207/263 ,  B01J23/00 ,  B01J23/89 ,  C07B61/00 ,  C07D201/08 ,  C07D207/26 ,  C07D207/267 ,  C07D207/38 ,  C07D207/00

Abstract: Five-membered nitrogen-containing saturated heterocyclic compounds, e.g. pyrrolidone, can be prepared by the catalytic hydrogenation/amination or a five-membered heterocyclic anhydride or the corresponding acid. This reaction proceeds with high yields and selectivities when it is conducted in the presence of oxide complex catalysts containing ruthenium.

公开(公告)号：CA1150228A

公开(公告)日：1983-07-19

申请号：CA399171

申请日：1982-03-23

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK A ,  HAASE THOMAS A

IPC: B01J31/20 ,  C07C47/00 ,  C07C67/00

Abstract: Oxygenated organic compounds, e.g. esters, aldehydes, and amides, are prepared by reacting an olefinically unsaturated compound with carbon monoxide and a compound containing a replaceable hydrogen atom in the presence of a catalyst comprising cobalt or ruthenium carbonyl and a promoter ligand. The promoter ligand is selected from the group consisting of heterocyclic nitrogen compounds and phosphorus or sulfur oxides. These reactions are carried out under relatively mild conditions of temperature and pressure.

公开(公告)号：CA1133508A

公开(公告)日：1982-10-12

申请号：CA361705

申请日：1980-10-07

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK A ,  HAASE THOMAS A

IPC: C07C53/128 ,  B01J31/00 ,  B01J31/18 ,  C07B61/00 ,  C07C51/00 ,  C07C51/14 ,  C07C53/124 ,  C07C67/00

Abstract: (5218) THE SELECTIVE HYDROCARBOXYLATION OF PROPYLENE TO ISOBUTYRIC ACID A process for the selective hydrocarboxylation of propylene to produce predominantly isobutyric acid in the liquid phase is provided. The reaction of propylene, carbon monoxide and water is effected at a temperature of about 75.degree.C to about 150.degree.C and at a pressure of about 250 psi to about 5000 psi in the presence of a carboxylic acid solvent and a catalyst comprising a soluble palladium salt, an organo-arsine and a hydrogen halide.

公开(公告)号：CA1249564A

公开(公告)日：1989-01-31

申请号：CA493803

申请日：1985-10-24

Applicant: STANDARD OIL CO OHIO

Inventor： DESMOND MICHAEL J ,  PESA FREDERICK A

IPC: C01B33/20 ,  B01J29/04 ,  C01B35/10 ,  C01B39/06 ,  C07B61/00 ,  C07C1/20 ,  C07C5/27 ,  C07C15/073 ,  C07C15/08 ,  C01B33/28

Abstract: A method for preparing a molecular sieving metallosilicate is disclosed which comprises (A) providing a mixture comprising: water; an oxide of silicon source; a mineralizing agent and/or synthesis directing agent; and a heteropolymetallate of the formula Aa LlMmJzOy ? dH2O wherein A is an ion selected from the group consisting of hydrogen; one or more of the Group I-A to VI-A or Group I-B to VI-B metals; one or more of the rare earth metals; ammonium, alkyl ammonium, alkyl phosphonium or alkyl arsonium; or a mixture of two or more thereof; M is Zn, Ga, Ge, Ti, Cr, Mn, Fe, Co, B, Ni, Rh, Zr or a mixture of two or more thereof; L is P, As, Si, Al, H or a mixture of two or more thereof; J is Mo, W, V, Nb or a mixture of two or more thereof; a is a number which when multiplied by the charge of A will result in balancing the charge on the complex within the brackets; l is a number ranging from zero to about 20; m is a number ranging from zero to about 20; z is a number ranging from about 1 to about 50; y is a number ranging from about 7 to about 150; d is a number ranging from about zero to about 150; and (B) maintaining said mixture at a temperature of about 80.degree.C to about 300.degree.C for an effective period of to form said molecular sieving metallosilicate.

公开(公告)号：CA1212836A

公开(公告)日：1986-10-21

申请号：CA418942

申请日：1983-01-05

Applicant: STANDARD OIL CO OHIO

Inventor： VELENYI LOUIS J ,  PESA FREDERICK A ,  PAPARIZOS CHRISTOS

IPC: C01B3/26

Abstract: PRODUCTION OF SYNTHESIS GAS Gas mixtures containing at least hydrogen and carbon monoxide are prepared by reforming hydrocarbons in the presence of a catalyst impregnated on a specially prepared porous catalyst support. In one embodiment of the present invention, methane is reformed in a one-step process to produce a product gas mixture containing about equal portions of carbon monoxide and hydrogen in the presence of a Group VIII metal impregnated on a specially prepared porous catalytic support.

公开(公告)号：CA1211098A

公开(公告)日：1986-09-09

申请号：CA447401

申请日：1984-02-14

Applicant: STANDARD OIL CO OHIO

Inventor： FOX JOSEPH R ,  CURATOLO BENEDICT S ,  PESA FREDERICK A

IPC: B01J23/04 ,  B01J23/30 ,  B01J23/36 ,  B01J23/58 ,  B01J23/78 ,  C07C2/76 ,  B01J23/00 ,  C01B3/26

Abstract: CONVERSION OF METHANE TO OLEFINS AND HYDROGEN A methane conversion process is provided for the production of olefins and hydrogen comprising contacting methane in the absence of oxygen and in the absence of water at a reaction temperature of at least 500.degree.C with a catalyst comprising the mixed oxides of a first metal selected from lithium, sodium, potassium, rubidium, cesium and mixtures thereof, a second metal selected from beryllium, magnesium, calcium, strontium, barium, and mixtures thereof, and optionally a promoter metal selected from copper, rhenium, tungsten, zirconium, rhodium, and mixtures thereof.

公开(公告)号：CA1144141A

公开(公告)日：1983-04-05

申请号：CA361706

申请日：1980-10-07

Applicant: STANDARD OIL CO OHIO

Inventor： PESA FREDERICK A ,  HAASE THOMAS A

IPC: B01J31/20 ,  B01J31/22 ,  C07B61/00 ,  C07C45/00 ,  C07C45/49 ,  C07C45/50 ,  C07C67/00 ,  C07C253/00 ,  C07C255/17 ,  C09B47/04

Abstract: This invention relates to the production of aldehyde by the addition of carbon monoxide and hydrogen to olefinically unsaturated compounds in the presence of a complex catalyst comprising cobalt carbonyl and a porphyrin promoter ligand. This process can be carried out under relatively mild conditions of temperature and pressure.