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公开(公告)号:CA1196472A
公开(公告)日:1985-11-12
申请号:CA431393
申请日:1983-06-29
Applicant: STANDARD OIL CO OHIO
Inventor: VELENYI LOUIS J , HARDMAN HARLEY F , PESA FREDERICK A
Abstract: (5477) PROCESS FOR THE PRODUCTION OF HYDROGEN CYANIDE FROM CARBON MONOXIDE AND AMMONIA A process for producing HCN by contacting CO and NH3 with a catalyst comprising a porous catalyst support, a Group VIII metal which is at least one of Fe, Ni, Co and Ru, and carbon, wherein the metal is disposed on the pore surfaces of the support and the carbon is randomly bonded to the metal. 4819A
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公开(公告)号:CA1141770A
公开(公告)日:1983-02-22
申请号:CA366808
申请日:1980-12-15
Applicant: STANDARD OIL CO OHIO
Inventor: VELENYI LOUIS J , PAPARIZOS CHRISTOS , DOLHYJ SERGE R
Abstract: Hydroperoxides are catalytically decomposed using a novel metal complex of the formula: wherein M is a positively charged metal or metal compound; Z is S, O, P, S-P, or S-S; L is C, P, or N; and A is selected from the group consisting of halogens; hydrogen: N-R wherein R is selected from the group consisting of H, C1-30 alkyls and 4 to 8 membered aryls optionally substituted with one or more Cl1-20 alkyls and C1-20 alkoxys; and hydrocarbon groups containing up to 30 carbon atoms optionally substituted with halogen atoms, C1-12hydroxy groups, C1-12 acid groups, C1-2 aldehyde groups, C1-12 ketone groups, and C1-10 nitrile groups; and wherein n is 1 or 2; and b is 1, 2 or 3. These catalysts are especially effective in decomposing either cumene hydroperoxide or cyclohexylbenzene hydroperoxide to phenol.
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公开(公告)号:CA1128752A
公开(公告)日:1982-08-03
申请号:CA335519
申请日:1979-09-12
Applicant: STANDARD OIL CO OHIO
Inventor: DOLHYJ SERGE R , VELENYI LOUIS J , GUTTMANN ANDREW T
Abstract: A Motor fuel is provided which comprises a blend of (1) a mixture of hydrocarbons boiling within the gasoline range, and (2) an aryl ether boiling with the gasoline range, the aryl ether having the structure: R1 - (R2)n - O - R3 wherein R1 is selected from the group consisting of phenyl, substituted phenyl substituted with one methyl group, substituted phenyl substituted with two methyl groups and substituted phenyl substituted with one ethyl group; R2 is selected from the group consisting of substituted CH2 substituted with one or two methyl groups, ethane, and substituted ethane substituted with one or two methyl groups; R3 is selected from the group consisting of methyl and ethyl; and wherein n is 0 or l. These aryl ethers are especially useful in increasing the octane number of unleaded gasolines.
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公开(公告)号:CA1212836A
公开(公告)日:1986-10-21
申请号:CA418942
申请日:1983-01-05
Applicant: STANDARD OIL CO OHIO
Inventor: VELENYI LOUIS J , PESA FREDERICK A , PAPARIZOS CHRISTOS
IPC: C01B3/26
Abstract: PRODUCTION OF SYNTHESIS GAS Gas mixtures containing at least hydrogen and carbon monoxide are prepared by reforming hydrocarbons in the presence of a catalyst impregnated on a specially prepared porous catalyst support. In one embodiment of the present invention, methane is reformed in a one-step process to produce a product gas mixture containing about equal portions of carbon monoxide and hydrogen in the presence of a Group VIII metal impregnated on a specially prepared porous catalytic support.
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公开(公告)号:CA1160429A
公开(公告)日:1984-01-17
申请号:CA388417
申请日:1981-10-21
Applicant: STANDARD OIL CO OHIO
Inventor: SHAW WILFRID G , PAPARIZOS CHRISTOS , VELENYI LOUIS J
Abstract: 5230 The invention herein is directed toward a process for the conversion of oxides of nitrogen to nitrogen gas by employing a reactant carbon fiber or inter host carbon material at a temperature of about 550.degree. C. The reactant material can be utilized alone or on a support material; in reactors such as fixed bed, fluid bed and radial flow; and, if desired, can be regenerated during the conversion process.
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公开(公告)号:CA2093332A1
公开(公告)日:1992-04-10
申请号:CA2093332
申请日:1991-10-03
Applicant: STANDARD OIL CO OHIO
Inventor: MAZANEC TERRY J , VELENYI LOUIS J
Abstract: 2093332 9205862 PCTABS00011 Oxygen is separated from an oxygen-containing gas by introducing the gas into a first zone (1) of a gas separation apparatus, the apparatus comprising first (1) and second (2) zones separated by a mixed metal oxide membrane (8), the membrane (8) having a first surface (7) open to the first zone (1), a second surface (10) open to the second zone (2), and an empirical formula of Bi Ax My Mz' On, where A is at least one of Mg, Ca, Sr, Ba, Y, Th, U, and the lanthanide elements; M is at least one of Sc, Ti, Cr, Mn, Fe, Ni, Cu and Zn; and M' is at least one of Co, Rh, Pd, Pt or Ru. The oxygen separated from the oxygen-containing gas can be recovered from the second surface (10) of the membrane (8) either as molecular oxygen, or it can be reacted with an oxygen-consuming substance, such as a hydrocarbon gas, which can be introduced into the second zone (2) of the separation apparatus and brought in contact with the second surface (10) of the membrane (8).
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公开(公告)号:CA1180318A
公开(公告)日:1985-01-02
申请号:CA392623
申请日:1981-12-18
Applicant: STANDARD OIL CO OHIO
Inventor: VELENYI LOUIS J , HARDMAN HARLEY F
Abstract: A catalyst comprising a fluid-bed particle support having a specific surface area and pore volume impregnated with a Group VIII metal.
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公开(公告)号:CA1152109A
公开(公告)日:1983-08-16
申请号:CA366876
申请日:1980-12-16
Applicant: STANDARD OIL CO OHIO
Inventor: SUNDEEN MARCIA H , VELENYI LOUIS J , DOLHYJ SERGE R
IPC: B01J31/00 , C07C67/00 , C07C407/00 , C07C409/02 , C07C409/08 , C07C409/10 , C07C409/14 , C07C179/035
Abstract: MANUFACTURE OF HYDROPEROXIDES Hydroperoxides, such as cyclohexylbenzene hydroperoxide, are manufactured by the oxidation of aryl compounds, such as cyclohexylbenzene, in the presence of a catalyst selected from the group consisting of C6 - C18 primary amines and polyvinylpyrrolidone.
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