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11.发明申请
公开(公告)号：WO1996039451A1
公开(公告)日：1996-12-12
申请号：PCT/US1996006280
申请日：1996-05-03
Applicant: THE DOW CHEMICAL COMPANY
Inventor： THE DOW CHEMICAL COMPANY , SOTO, Jorge , MARCHAND, Gary, R. , STEVENS, James, C. , CRAWFORD, Lenore, H.
IPC: C08F290/04
CPC classification number: C08F290/04
Abstract: This invention relates to segmented, multicomponent interpolymers comprising: A) at least one olefin polymer segment comprising a substantially linear ethylene homopolymer or a substantially linear or branched copolymer of ethylene and at least one comonomer selected from the group consisting of C3-20 alpha -olefins, and B) at least one monovinylidene aromatic polymer segment, said olefin polymer segment and monovinylidene aromatic polymer segment being joined by means of the copolymerization of the terminal vinyl functionality of a macromonomer comprising the monovinylidene aromatic polymer segment with ethylene or a mixture of ethylene and said at least one comonomer under Ziegler-Natta polymerization conditions.
Abstract translation: 本发明涉及分段的多组分互聚物，其包含：A）至少一种烯烃聚合物链段，其包含基本上线性的乙烯均聚物或乙烯和至少一种共聚单体的基本上线性或支化的共聚物，所述共聚单体选自C3-20α-烯烃 和B）至少一个单亚乙烯基芳族聚合物链段，所述烯烃聚合物链段和单亚乙烯基芳族聚合物链段通过包含单亚乙烯基芳族聚合物链段的大分子单体的末端乙烯基官能团与乙烯或乙烯和 在齐格勒 - 纳塔聚合条件下表示至少一种共聚单体。
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公开(公告)号：WO1996004290A1
公开(公告)日：1996-02-15
申请号：PCT/US1995008813
申请日：1995-07-14
Applicant: THE DOW CHEMICAL COMPANY
Inventor： THE DOW CHEMICAL COMPANY , TIMMERS, Francis, J. , DEVORE, David, D. , STEVENS, James, C. , ROSEN, Robert, K. , PATTON, Jasson, T. , NEITHAMER, David, R.
IPC: C07F17/00
CPC classification number: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F10/00 , Y10S526/901 , Y10S526/943
Abstract: Biscyclopentadienyl, Group 4 transition metal complexes are formed by contacting a biscyclopentadienyl Group 4 metal halide, hydrocarbyl, hydrocarbyloxy or amide complex with a conjugated diene. Uniquely, the ansa-rac diastereomer is selectively isolated and may be reconverted to the halide form if desired. When combined with standard activating cocatalysts or activated with an activating technique, the complexes form catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.
Abstract translation: 通过使双环戊二烯基第4族金属卤化物，烃基，烃氧基或酰胺络合物与共轭二烯接触来形成双环戊二烯基，第4族过渡金属络合物。 独特的是，所述外消旋非对映异构体是选择性分离的，并且如果需要可以再转化为卤化物形式。 当与标准活化助催化剂结合或用活化技术活化时，络合物形成用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂。
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公开(公告)号：WO1995000683A1
公开(公告)日：1995-01-05
申请号：PCT/US1994004660
申请日：1994-04-28
Applicant: THE DOW CHEMICAL COMPANY
Inventor： THE DOW CHEMICAL COMPANY , DEVORE, David, D. , MUSSELL, Robert, D. , STEVENS, James, C. , TIMMERS, Francis, J.
IPC: C25B03/00
CPC classification number: C07F17/00 , B01J37/348 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F2420/02 , Y10S526/943
Abstract: Group 4 metal complexes useful as addition polymerization catalysts are prepared by electrolysis of cyclopentadienyl metal complexes under inert electrolysis conditions.
Abstract translation: 可用作加成聚合催化剂的第4族金属络合物通过在惰性电解条件下电解环戊二烯基金属络合物来制备。
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14.发明公开
公开(公告)号：EP0977787A1
公开(公告)日：2000-02-09
申请号：EP98918908.9
申请日：1998-05-01
Applicant: THE DOW CHEMICAL COMPANY
Inventor： KALE, Lawrence, T. , VANDERLENDE, Daniel, D. , NICKIAS, Peter, N. , PATTON, Jasson, T. , STEVENS, James, C. , PARIKH, Deepak, R. , MANGOLD, Debra, J.
IPC: C08F210/16 , C08F4/645
CPC classification number: C08F210/18 , C08F4/65912 , C08F10/00 , C08F210/16 , C08F4/65908 , C08F4/6592 , C08F210/14 , C08F2500/08 , C08F2500/12 , C08F2500/03 , C08F2500/19 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/20
Abstract: The subject invention is directed to an olefin polymer produced by polymerizing at least one α-olefin in the presence of a Group 4 metal complex comprising an indenyl group substituted in the 2 or 3 position with at least one group selected from hydrocarbyl, perfluoro-substituted hydrocarbyl, silyl, germyl and mixtures thereof, said indenyl group further being covalently bonded to the metal by means of a divalent ligand group, wherein the divalent ligand comprises nitrogen or phosphorus having an aliphatic or alicyclic hydrocarby group covalently bonded thereto via a primary or secondary carbon. Preferred olefin polymers of the invention will be characterized as having a high molecular weight, narrow molecular weight distribution, high vinyl content, and a bimodal DSC melting curve or a deconvoluted ATREF or GPC curve which shows at least two distinct narrow peaks. The olefin polymer will have utiliity in a variety of applications, including but not limited to films, fibers, foams, molded parts, and as components of formulations such as adhesives, sealants, coatings, caulks, and asphalt.
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公开(公告)号：EP0656075A1
公开(公告)日：1995-06-07
申请号：EP94919987.0
申请日：1994-04-28
Applicant: THE DOW CHEMICAL COMPANY
Inventor： DEVORE, David, D. , MUSSELL, Robert, D. , STEVENS, James, C. , TIMMERS, Francis, J.
CPC classification number: C07F17/00 , B01J37/348 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F2420/02 , Y10S526/943
Abstract: Group 4 metal complexes useful as addition polymerization catalysts are prepared by electrolysis of cyclopentadienyl metal complexes under inert electrolysis conditions.
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Patent Agency Ranking
公开(公告)号：EP0689562B1
公开(公告)日：2000-04-26
申请号：EP94910840.1
申请日：1994-03-04
Applicant: THE DOW CHEMICAL COMPANY
Inventor： PARK, Chung, P. , STEVENS, James, C. , KNIGHT, George, W.
CPC classification number: C08J9/14 , C08J2323/16 , Y10S526/943
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公开(公告)号：EP0923616A1
公开(公告)日：1999-06-23
申请号：EP96929916.0
申请日：1996-09-04
Applicant: THE DOW CHEMICAL COMPANY
Inventor： STEVENS, James, C. , TIMMERS, Francis, J. , GUEST, Martin, J. , GATHERS, John, J. , CHUM, Pak-Wing, S. , CHEUNG, Yunwa, W. , PARK, Chung, P. , CLINGERMAN, George, P. , SIKKEMA, Kevin, D.
CPC classification number: C08F210/02 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08F212/08 , C08L23/0838 , C08L25/06 , C08L25/08 , C08L25/12 , C08L2203/14 , C08L2666/04 , C08F2500/03 , C08F210/06 , C08F2500/20 , C08F2500/26 , C08F210/14 , C08F2500/12 , C08F2500/07 , C08F212/02 , C08F218/00 , C08F220/00
Abstract: Blends of polymeric materials comprising (A) from about 1 to about 99 weight percent of at least one interpolymer containing (1) from about 1 to about 65 mole percent of (a) at least one vinylidene aromatic monomer, or (b) at least one hindered aliphatic vinylidene monomer, or (c) a combination of at least one vinylidene aromatic monomer and at least one hindered aliphatic vinylidene monomer, and (2) from about 35 to about 99 mole percent of at least one aliphatic α-olefin having from 2 to about 20 carbon atoms; and (B) from about 1 to about 99 weight percent of at least one homopolymer or interpolymer of one or more vinylidene aromatic monomers and/or one or more hindered aliphatic vinylidene monomers. These blends have been observed to possess improved properties when compared to the individual polymers comprising the blend and to provide materials with enhanced processability and temperature ranges of performance.
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18.发明公开
公开(公告)号：EP0914353A1
公开(公告)日：1999-05-12
申请号：EP97935016.0
申请日：1997-07-18
Applicant: THE DOW CHEMICAL COMPANY
Inventor： ROSEN, Robert, K. , STEVENS, James, C.
CPC classification number: B01J31/1805 , B01J31/14 , B01J31/2295 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F210/14
Abstract: Catalyst compositions that are highly tolerant of catalyst poisons comprising a catalytic derivative of a Group 4 metal complex and a Group 13 metal compound according to the formula R12Me(NR22), wherein R?1 and R2¿ independently each occurrence is a hydrocarbyl, silyl, halocarbyl, halohydrocarbyl, hydrocarbyl-substituted silyl, halocarbyl-substituted silyl, or halohydrocarbyl-substituted silyl group, said R?1 and R2¿ having from 1 to 30 carbon, silicon, or mixtures of carbon and silicon atoms, and Me is a Group 13 metal, the molar ratio of complex to Group 13 compound being from 1:0.1 to 1:100.
Abstract translation: 对催化剂毒物高度耐受的催化剂组合物，其包含第4族金属络合物的催化衍生物和式R12Me（NR22）的第13族金属化合物，其中R 1和R 2各自独立地为烃基，甲硅烷基， 卤代烃基，卤代烃基，烃基取代的甲硅烷基，卤代烃基取代的甲硅烷基或卤代烃基取代的甲硅烷基，所述R 1和R 2具有1至30个碳，硅或碳和硅原子的混合物，Me是基团 13金属，配合物与第13族化合物的摩尔比为1:0.1至1:100。
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公开(公告)号：EP0876407A1
公开(公告)日：1998-11-11
申请号：EP96945608.0
申请日：1996-12-18
Applicant: THE DOW CHEMICAL COMPANY
Inventor： ROSEN, Robert, K. , STEVENS, James, C. , TRACY, John, C.
CPC classification number: C08F10/00 , B01J31/143 , B01J31/146 , B01J31/1608 , B01J31/2295 , B01J2531/46 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F210/16 , Y10S526/943
Abstract: Catalyst compositions that are highly tolerant of catalyst poisons comprising a cationic or zwitterionic Group 4 metal complex of the constrained geometry type and an organoaluminum hydrocarbyloxide compound according to the formula R12Al(OR2), wherein R?1 and R2¿ independently each occurence are C¿1-30? hydrocarbyl, the molar ratio of complex to organoaluminum hydrocarbyloxide compound being from 1:0.1 to 1:100.
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20.发明授权
公开(公告)号：EP0640090B1
公开(公告)日：1998-09-02
申请号：EP93912135.6
申请日：1993-04-07
Applicant: THE DOW CHEMICAL COMPANY
Inventor： NEITHAMER, David, R. , STEVENS, James, C.
CPC classification number: C07F17/00 , C07F7/28 , C08F4/65908 , C08F4/6592 , C08F10/00 , Y10S526/943
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