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公开(公告)号：EP0518548A2
公开(公告)日：1992-12-16
申请号：EP92305076.9
申请日：1992-06-03
Applicant: THE STANDARD OIL COMPANY
Inventor： Blum, Patricia Rae , Pepera, Marc Anthony
IPC: C07C53/08 , C07C51/215 , B01J27/195
CPC classification number: C07C51/215 , B01J23/002 , B01J23/22 , B01J27/198 , B01J2523/00 , C07C53/08 , B01J2523/51 , B01J2523/55 , B01J2523/74
Abstract: Disclosed is a process for making acetic acid which comprises oxidizing ethane with molecular oxygen in a reaction zone at a pressure of at least 100 psig while the reactants are in contact with a solid catalyst having the elements and relative atomic proportions indicated by the empirical formula:
VP a M b O x
where M is one or more optional element selected from
Co, Cu, Re, Fe, Ni, Nb, Cr, W, U, Ta, Ti, Zr, Zn, Hf, Mn, Pt, Pd, Sn, Sb, Bi, Ce, As, Ag, and Au,
wherein
a is 0.5 to 3,
b is 0 to 1, and
x is a number determined by the valence requirements of the other elements in the catalyst,
and
wherein said catalyst contains crystalline vanadyl pyrophosphate.Abstract translation: 公开了一种制备乙酸的方法，其包括在反应区中在至少100psig的压力下用分子氧氧化乙烷，同时反应物与具有以下经验式所示的元素和相对原子比例的固体催化剂接触： VPaMbOx其中M是选自Co，Cu，Re，Fe，Ni，Nb，Cr，W，U，Ta，Ti，Zr，Zn，Hf，Mn，Pt，Pd，Sn，Sb，Bi ，Ce，As，Ag和Au，其中a为0.5至3，b为0至1，x为由催化剂中其它元素的化合价要求确定的数，并且其中所述催化剂含有焦磷酸结晶氧钒。
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12.发明公开Synthesis of molecular sieving metallosilicates using silica-transition metal oxide sols 失效使用二氧化硅转移金属氧化物溶胶分子筛金属化合物的合成
公开(公告)号：EP0183391A3
公开(公告)日：1988-06-15
申请号：EP85307762
申请日：1985-10-28
Applicant: THE STANDARD OIL COMPANY
Inventor： Pepera, Marc Anthony , Callahan, James Louis , Desmond, Michael Joseph
CPC classification number: C01B33/2884 , B01J29/04 , C01B33/2876
Abstract: A method for preparing a molecular sieving metallosilicate which comprises:
(A) providing an aqueous dispersion of colloidal particles comprising contiguous mixtures of silica and the oxide of a transition metal selected from the group consisting of Sc, Ti, V, Cr, Mn, Fe, Co. Ni, Zn, Zr, Y or a mixture of two or more of said metals; (B) mixing an effective amount of a mineralizing agent and/or synthesis directing agent with said dispersion to form a gel; and (C) maintaining said gel at a temperature of 80°C to 300°C for an effective period of time to provide said metallosilicate.-
13.发明公开Synthesis of molecular sieving metallosilicates using silica-transition metal oxide sols 失效的金属硅酸盐用硅胶Übergangsmetalloxidsolen分子筛类型合成。
公开(公告)号：EP0183391A2
公开(公告)日：1986-06-04
申请号：EP85307762.6
申请日：1985-10-28
Applicant: THE STANDARD OIL COMPANY
Inventor： Pepera, Marc Anthony , Callahan, James Louis , Desmond, Michael Joseph
CPC classification number: C01B33/2884 , B01J29/04 , C01B33/2876
Abstract: A method for preparing a molecular sieving metallosilicate which comprises:
(A) providing an aqueous dispersion of colloidal particles comprising contiguous mixtures of silica and the oxide of a transition metal selected from the group consisting of Sc, Ti, V, Cr, Mn, Fe, Co. Ni, Zn, Zr, Y or a mixture of two or more of said metals;
(B) mixing an effective amount of a mineralizing agent and/or synthesis directing agent with said dispersion to form a gel; and
(C) maintaining said gel at a temperature of 80°C to 300°C for an effective period of time to provide said metallosilicate.-
14.发明授权Process for the preparation of fluid bed vinyl acetate catalyst support 失效一种制备催化剂的载体用于在流化床制备乙酸乙烯酯的过程
公开(公告)号：EP0949000B1
公开(公告)日：2007-06-13
申请号：EP99112752.3
申请日：1995-02-17
Applicant: THE STANDARD OIL COMPANY
Inventor： Blum, Patricia Rae , Cirjak, Larry Michael , Lemanski, Michael Francis , Paparizos, Christos , Pepera, Marc Anthony , Suresh, Devasirvatham Dhanarah
IPC: B01J37/00 , C07C67/055 , B01J21/08
CPC classification number: B01J37/0045 , B01J21/08 , B01J23/44 , B01J23/52 , B01J23/56 , B01J23/58 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J35/1042 , C07C67/055 , C07C69/01 , C07C69/15
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15.发明授权
公开(公告)号：EP0672453B1
公开(公告)日：2005-11-02
申请号：EP95301022.0
申请日：1995-02-17
Applicant: THE STANDARD OIL COMPANY
Inventor： Blum, Patricia Rae , Cirjak, Larry Michael , Lemanski, Michael Francis , Paparizos, Christos , Pepera, Marc Anthony , Suresh, Devasirvatham Dhanarah
CPC classification number: B01J23/63 , B01J21/08 , B01J23/44 , B01J23/52 , B01J23/56 , B01J23/58 , B01J35/08 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0045 , C07C67/055 , C07C69/01 , C07C69/15
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Patent Agency Ranking16.发明授权Process for the preparation of antimonate catalysts for (AMM) oxidation of alkanes and alkenes 失效一种用于生产锑酸盐催化剂的烷烃和烯烃的（氨）氧化过程
公开(公告)号：EP0867221B1
公开(公告)日：2003-11-12
申请号：EP98301629.6
申请日：1998-03-05
Applicant: The Standard Oil Company
Inventor： Cirjak, Larry Michael , Pepera, Marc Anthony
IPC: B01J23/22 , B01J23/18 , B01J23/84 , B01J23/847 , B01J23/843
CPC classification number: B01J23/22 , B01J23/18 , B01J23/8472
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17.发明公开
公开(公告)号：EP0949000A1
公开(公告)日：1999-10-13
申请号：EP99112752.3
申请日：1995-02-17
Applicant: THE STANDARD OIL COMPANY
Inventor： Blum, Patricia Rae , Cirjak, Larry Michael , Lemanski, Michael Francis , Paparizos, Christos , Pepera, Marc Anthony , Suresh, Devasirvatham Dhanarah
IPC: B01J37/00 , C07C67/055
CPC classification number: B01J37/0045 , B01J21/08 , B01J23/44 , B01J23/52 , B01J23/56 , B01J23/58 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J35/1042 , C07C67/055 , C07C69/01 , C07C69/15
Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns.
Abstract translation: 一种用于在流化床乙酸乙烯酯的制备方法，（VAM）催化剂，包含浸渍载体，其包含基本上惰性的微球颗粒的混合物与溶液包含钯和M，worin M包括钡，金，镧一个无卤化物金属盐 ，铌，铈，锌，铅，钙，锶，锑或它们的混合物，还原金属盐以形成钯和M的支撑表面上的沉积物和与至少一种无卤化物的碱金属盐浸渍载体。 用于微球形载体颗粒的至少50％具有低于100微米的粒度，优选低于60微米。
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18.发明公开Process for the preparation of antimonate catalysts for (AMM) oxidation of alkanes and alkenes 失效一种用于生产锑酸盐催化剂的烷烃和烯烃的（氨）氧化过程
公开(公告)号：EP0867221A3
公开(公告)日：1999-06-23
申请号：EP98301629.6
申请日：1998-03-05
Applicant: THE STANDARD OIL COMPANY
Inventor： Cirjak, Larry Michael , Pepera, Marc Anthony
CPC classification number: B01J23/22 , B01J23/18 , B01J23/8472
Abstract: A method of preparing a V a Sb b M m N n O x catalyst useful in the ammoxidation of a C 2 -C 5 hydrocarbon to its corresponding α, β unsaturated nitrile comprising heating an aqueous mixture comprising V 2 O 5 and Sb 2 O 3 at a temperature above about 100° to 250°C, preferably 110° to 175°C, most preferably 120° to 160°C, under autogenous pressure with agitation to form a catalyst precursor, drying the catalyst precursor and calcining the catalyst precursor to form the finished catalyst.
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19.发明公开Process for the preparation of antimonate catalysts for (AMM) oxidation of alkanes and alkenes 失效氧化on阿尔卡宁和阿尔肯宁（阿尔卑斯山）
公开(公告)号：EP0867221A2
公开(公告)日：1998-09-30
申请号：EP98301629.6
申请日：1998-03-05
Applicant: THE STANDARD OIL COMPANY
Inventor： Cirjak, Larry Michael , Pepera, Marc Anthony
CPC classification number: B01J23/22 , B01J23/18 , B01J23/8472
Abstract: A method of preparing a V a Sb b M m N n O x catalyst useful in the ammoxidation of a C 2 -C 5 hydrocarbon to its corresponding α, β unsaturated nitrile comprising heating an aqueous mixture comprising V 2 O 5 and Sb 2 O 3 at a temperature above about 100° to 250°C, preferably 110° to 175°C, most preferably 120° to 160°C, under autogenous pressure with agitation to form a catalyst precursor, drying the catalyst precursor and calcining the catalyst precursor to form the finished catalyst.
Abstract translation: 一种制备可用于将C2-C5烃氨氧化成其相应的α，β不饱和腈的VaSbbMmNnOx催化剂的方法，包括在高于约100℃至250℃，优选110℃至大约110℃的温度加热包含V 2 O 5和Sb 2 O 3的含水混合物， 175℃，最优选120℃至160℃，在自生压力下搅拌以形成催化剂前体，干燥催化剂前体并煅烧催化剂前体以形成最终催化剂。
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公开(公告)号：EP0518548A3
公开(公告)日：1993-03-31
申请号：EP92305076.9
申请日：1992-06-03
Applicant: THE STANDARD OIL COMPANY
Inventor： Blum, Patricia Rae , Pepera, Marc Anthony
IPC: C07C53/08 , C07C51/215 , B01J27/195
CPC classification number: C07C51/215 , B01J23/002 , B01J23/22 , B01J27/198 , B01J2523/00 , C07C53/08 , B01J2523/51 , B01J2523/55 , B01J2523/74
Abstract: Disclosed is a process for making acetic acid which comprises oxidizing ethane with molecular oxygen in a reaction zone at a pressure of at least 100 psig while the reactants are in contact with a solid catalyst having the elements and relative atomic proportions indicated by the empirical formula:
VP a M b O x
where M is one or more optional element selected from
Co, Cu, Re, Fe, Ni, Nb, Cr, W, U, Ta, Ti, Zr, Zn, Hf, Mn, Pt, Pd, Sn, Sb, Bi, Ce, As, Ag, and Au,
wherein
a is 0.5 to 3,
b is 0 to 1, and
x is a number determined by the valence requirements of the other elements in the catalyst,
and
wherein said catalyst contains crystalline vanadyl pyrophosphate.
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