公开(公告)号：DE3266523D1

公开(公告)日：1985-10-31

申请号：DE3266523

申请日：1982-06-15

Applicant: TORAY INDUSTRIES

Inventor： CHIBA KAZUMASA ,  KATO NOBUO ,  KOBAYASHI KAZUHIKO

IPC: C08G69/26 ,  C08L77/00

Abstract: A copolyamide comprised of undecamethylenehexahydroterephthalamide units and hexamethylenehexahydroterephthalamide units having a trans isomer ratio of hexahydroterephthalic acid residues of 57 to 83 percent is provided. The copolyamide is suitable for injection and extrusion molding. The copolyamide is prepared by a process comprising heating an equimolar salt of undecamethylenediamine and hexahydroterephthalic acid and an equimolar salt of hexamethylenediamine and hexahydroterephthalic acid at a maximum temperature of about 280 to 360 DEG C. to stably melt-polymerize the copolyamide. A copolyamide molding composition comprised of the copolyamide and an inorganic reinforcing agent can be formed into various molded articles having excellent properties.

公开(公告)号：DE2967026D1

公开(公告)日：1984-07-05

申请号：DE2967026

申请日：1979-11-30

Applicant: TORAY INDUSTRIES

Inventor： CHIBA KAZUMASA ,  EGAWA KEIICHI ,  MURAKI TOSHIO

IPC: G03F7/037 ,  G03C1/68 ,  G03F7/02 ,  G03F7/10 ,  H01L21/302 ,  C08G73/00 ,  C08L79/00

Abstract: A photosensitive resin composition comprising a polyamide containing 10 to 70% by weight of a polyoxyethylene segment or poly(oxyethylene/oxypropylene) copolymer segment having a number average molecular weight of from 150 to 1,500 in its molecular chain, and a photopolymerizable unsaturated compound. This composition exhibits excellent flexibility and water- and alcohol-developability, and results in a printing plate exhibiting excellent transparency, toughness and printing durability.

公开(公告)号：DE68919151T2

公开(公告)日：1995-03-09

申请号：DE68919151

申请日：1989-08-03

Applicant: TORAY INDUSTRIES

Inventor： OGAWA TAKUYA TORAY ATSUTA-RYO ,  IWAMOTO MASATOSHI DAI ASAI BLD ,  CHIBA KAZUMASA ,  YANO KAZUHISA -GO -

IPC: C08L33/24 ,  C08L51/04 ,  C08L33/04 ,  C08L25/12

Abstract: Disclosed is a resin composition comprising (A) from 1 - 98 wt. parts of a graft copolymer obtained by graft-polymerizing (a) 5 - 80 wt.% of a rubbery polymer and (b) 95 - 20 wt.% of a monomer mixture consisting of 40 - 90 wt.% of an aromatic vinyl compound, 60 - 10 wt.% of a vinyl cyanide compound and 0 - 50 wt.% of another ethylenically unsaturated compound copolymerizable therewith, (B) 1 - 40 wt.% parts of a modified copolymer selected from (B1) a modified vinyl copolymer obtained by polymerizing (a) 40 - 90 wt.% of an aromatic vinyl compound, (b) 60 - 10 wt.% of a vinyl cyanide compound, (c) 0.01 - 10 wt.% of a monomer having an epoxy, carboxyl or amino group, and (d) 0 - 40 wt.% of another ethylenically unsaturated compound, and (B2) a modified olefinic copolymer obtained by copolymerizing (e) 50 - 95 wt.% of ethylene or propylene, (f) 0.1 - 20 wt.% of a monomer having an epoxy, carboxyl or amino group, and (g) 0 - 40 wt.% of another ethylenically unsaturated compound, (C) 1 - 60 wt. parts of an imidized acrylic resin, and (D) from 0 - 90 wt. parts of a vinyl copolymer obtained by polymerizing (a) 40 - 90 wt.% of an aromatic vinyl compound, (b) 60 - 10 wt.% of a vinyl cyanide compound and (c) 0 - 40 wt.% of another ethylenically unsaturated compound, wherein the content of the rubbery polymer (a) in the graft copolymer (A) is 5 to 40 wt.% based on the resin composition. This resin composition gives a shaped article having a delustered and pleasing appearance and a good impact resistance.

公开(公告)号：DE68919151D1

公开(公告)日：1994-12-08

申请号：DE68919151

申请日：1989-08-03

Applicant: TORAY INDUSTRIES

Inventor： OGAWA TAKUYA TORAY ATSUTA-RYO ,  IWAMOTO MASATOSHI DAI ASAI BLD ,  CHIBA KAZUMASA ,  YANO KAZUHISA -GO -

IPC: C08L33/24 ,  C08L51/04 ,  C08L33/04 ,  C08L25/12

Abstract: Disclosed is a resin composition comprising (A) from 1 - 98 wt. parts of a graft copolymer obtained by graft-polymerizing (a) 5 - 80 wt.% of a rubbery polymer and (b) 95 - 20 wt.% of a monomer mixture consisting of 40 - 90 wt.% of an aromatic vinyl compound, 60 - 10 wt.% of a vinyl cyanide compound and 0 - 50 wt.% of another ethylenically unsaturated compound copolymerizable therewith, (B) 1 - 40 wt.% parts of a modified copolymer selected from (B1) a modified vinyl copolymer obtained by polymerizing (a) 40 - 90 wt.% of an aromatic vinyl compound, (b) 60 - 10 wt.% of a vinyl cyanide compound, (c) 0.01 - 10 wt.% of a monomer having an epoxy, carboxyl or amino group, and (d) 0 - 40 wt.% of another ethylenically unsaturated compound, and (B2) a modified olefinic copolymer obtained by copolymerizing (e) 50 - 95 wt.% of ethylene or propylene, (f) 0.1 - 20 wt.% of a monomer having an epoxy, carboxyl or amino group, and (g) 0 - 40 wt.% of another ethylenically unsaturated compound, (C) 1 - 60 wt. parts of an imidized acrylic resin, and (D) from 0 - 90 wt. parts of a vinyl copolymer obtained by polymerizing (a) 40 - 90 wt.% of an aromatic vinyl compound, (b) 60 - 10 wt.% of a vinyl cyanide compound and (c) 0 - 40 wt.% of another ethylenically unsaturated compound, wherein the content of the rubbery polymer (a) in the graft copolymer (A) is 5 to 40 wt.% based on the resin composition. This resin composition gives a shaped article having a delustered and pleasing appearance and a good impact resistance.

公开(公告)号：DE3780415D1

公开(公告)日：1992-08-20

申请号：DE3780415

申请日：1987-05-18

Applicant: TORAY INDUSTRIES

Inventor： CHIBA KAZUMASA ,  KISHIMOTO AKIHIKO

IPC: C08L71/02 ,  C08L53/02 ,  C08L71/12 ,  C08L77/00

公开(公告)号：DE3382369D1

公开(公告)日：1991-09-12

申请号：DE3382369

申请日：1983-12-29

Applicant: TORAY INDUSTRIES

Inventor： CHIBA KAZUMASA ,  KOBAYASHI KAZUHIKO ,  SUSUKI TOSAKU

IPC: C08G69/18 ,  C08G69/40 ,  C08G69/42

Abstract: A block copolyamide having effectively improved impact strength is obtained by polymerizing a mixture comprising substantially from about 50 to about 95 parts by weight of lactam and from about 50 to about 5 parts by weight of polyol in the presence of a catalyst for an anionic polymerization and an activator represented by the following formula (I);wherein A denotes a bifunctional organic residue having at least one kind of heteroatom selected from the group consisting of N, 0, S, F, Cl, Br and I, Y and Y' denote an acyl group selected from the group consisting ofand n and n' denote an integer of 3 to 11 or by polymerizing, in the presence of a catalyst for anionic polymerization, a mixture comprising substantially from about 50 to about 95 parts by weight of lactam and from about 5 to about 50 parts by weight of prepolymer obtained by a reaction of polyol and an activator represented by the above formula (I), wherein A denotes a bifunctional aromatic residue having at least one halogen atom attached to the aromatic ring.

公开(公告)号：DE2454929A1

公开(公告)日：1975-05-22

申请号：DE2454929

申请日：1974-11-20

Applicant: TORAY INDUSTRIES

Inventor： AYA TOSHIHIKO ,  CHIBA KAZUMASA ,  IZUMI ZENJI

IPC: C08F8/12 ,  C08F8/32

Abstract: A novel, easily regeneratable, high-performance chelating resin and process for preparing the same. More in particular, a crosslinked polymer consisting mainly of an aromatic vinyl monomer having a polyalkylene polyamine functional group containing an iminodipropionic acid group or an iminodi- alpha -methylpropionic acid group, and process for preparing the same.

公开(公告)号：EP0269748A4

公开(公告)日：1988-07-25

申请号：EP87903410

申请日：1987-05-18

Applicant: TORAY INDUSTRIES

Inventor： CHIBA KAZUMASA ,  KISHIMOTO AKIHIKO

IPC: C08L71/02 ,  C08L53/02 ,  C08L71/12 ,  C08L77/00

CPC classification number: C08L77/00 ,  C08L71/12 ,  C08L71/123 ,  C08L2666/02 ,  C08L2666/22

Abstract: The polyphase structure is prepared by kneeding: (A) 30 to 60 wt % of aliphatic polyamide; (B) 35 to 55 wt % of polyphenylene ether; and (c) 5 to 20 wt % of A-B-A' type diene block copolymer (wherein A and A' each represents the same or different polymerized vinylaromatic hydrocarbon block, and B represents polymerized conjugated diene block), with (A)+(B)+(C) of 100 wt %, and the aliphatic polyamide (A) forming a matrix phase, the polyphenylene ether (B) forming a primary dispersed phase in the matrix phase, and the diene block copolymer (C) forming a secondary dispersed phase in the primary dispersed phase. This polyphase structure gives moldings excellent in impact resistance, rigidity, and heat resistance, and can be used as automobile parts, mechanical parts, and electric and electronic components.

公开(公告)号：EP0020782A4

公开(公告)日：1982-04-22

申请号：EP79901613

申请日：1980-06-17

Applicant: TORAY INDUSTRIES

Inventor： CHIBA KAZUMASA ,  EGAWA KEIICHI ,  MURAKI TOSHIO

IPC: G03F7/037 ,  G03C1/68 ,  C08G73/00 ,  C08L79/00 ,  G03F7/02 ,  G03F7/10 ,  H01L21/302

CPC classification number: G03F7/037

公开(公告)号：JPH09100321A

公开(公告)日：1997-04-15

申请号：JP25900195

申请日：1995-10-05

Applicant: TORAY INDUSTRIES

Inventor： HONMA MASATO ,  TAMURA SHINICHI ,  CHIBA KAZUMASA

IPC: C08F8/32 ,  C08F8/48 ,  C08F220/10 ,  C08F222/12

Abstract: PROBLEM TO BE SOLVED: To obtain excellent heat resistance by reacting a copolymer of a (meth)acrylic ester monomer and an addition-polymerizable monomer with NH3 or a primary amine in the presence of a nitrogenous heterocyclic compound. SOLUTION: A mixture of a (meth)acrylic ester monomer (a) such as methylmethacrylate and other addition-polymerizable monomer(s) such as styrene in a given proportion is heated together with a polymerization initiator and a chain transfer agent to react the monomers. The resultant copolymer is mixed with 0.1-10 pts.wt. nitrogenous heterocyclic compound such as 2-pyridone per 100 pts.wt. the copolymer and with about 0.1-10mol of an imidating agent comprising NH3 or a primary amine such as p-toluidine per mol of the two kinds of acrylic ester structural units. The mixture is reacted at 100-350 deg.C to obtain an imidated copolymer made up of 1-98% addition-polymerized structural units (b) derived from the monomer (a), 1-98wt.% imidated structural units derived from the units (b), and 0-98% other addition-polymerized structural units.