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公开(公告)号:DE69531641T2
公开(公告)日:2004-07-01
申请号:DE69531641
申请日:1995-03-15
Applicant: TORAY INDUSTRIES
Inventor: SAWAOKA RYUJI , KOUCHI SHINJI , MURAKI TOSHIO
Abstract: A microcapsule-type curing agent comprises (A) a curing agent for a thermosetting resin and (B) a thermoplastic resin dissolvable in the thermosetting resin by heating. The microcapsule-type curing agent is formed as a particle-like material in which the component (A) is coated with a layer whose main constituent is the component (B) and the mean particle diameter of which is in the range of 0.1 to 20 mu m. By using the microcapsule-type curing agent, a thermosetting resin composition and a prepreg which are good in storage stability at a room temperature and excellent in thermal resistance of a cured product made therefrom can be obtained. Further, a fiber reinforced composite material obtained using this thermosetting resin composition is excellent in curing uniformity and thermal resistance.
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公开(公告)号:DE2967026D1
公开(公告)日:1984-07-05
申请号:DE2967026
申请日:1979-11-30
Applicant: TORAY INDUSTRIES
Inventor: CHIBA KAZUMASA , EGAWA KEIICHI , MURAKI TOSHIO
Abstract: A photosensitive resin composition comprising a polyamide containing 10 to 70% by weight of a polyoxyethylene segment or poly(oxyethylene/oxypropylene) copolymer segment having a number average molecular weight of from 150 to 1,500 in its molecular chain, and a photopolymerizable unsaturated compound. This composition exhibits excellent flexibility and water- and alcohol-developability, and results in a printing plate exhibiting excellent transparency, toughness and printing durability.
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公开(公告)号:DE69531641D1
公开(公告)日:2003-10-09
申请号:DE69531641
申请日:1995-03-15
Applicant: TORAY INDUSTRIES
Inventor: SAWAOKA RYUJI , KOUCHI SHINJI , MURAKI TOSHIO
Abstract: A microcapsule-type curing agent comprises (A) a curing agent for a thermosetting resin and (B) a thermoplastic resin dissolvable in the thermosetting resin by heating. The microcapsule-type curing agent is formed as a particle-like material in which the component (A) is coated with a layer whose main constituent is the component (B) and the mean particle diameter of which is in the range of 0.1 to 20 mu m. By using the microcapsule-type curing agent, a thermosetting resin composition and a prepreg which are good in storage stability at a room temperature and excellent in thermal resistance of a cured product made therefrom can be obtained. Further, a fiber reinforced composite material obtained using this thermosetting resin composition is excellent in curing uniformity and thermal resistance.
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公开(公告)号:DE68922979T2
公开(公告)日:1995-12-21
申请号:DE68922979
申请日:1989-11-23
Applicant: TORAY INDUSTRIES
Inventor: KIMOTO YUKITANE , MURATA KOHZOU , MURAKI TOSHIO
IPC: B29B11/16 , B29C45/00 , B29C45/02 , B29C70/06 , B29C70/14 , B29C70/46 , B29K101/12 , B29K105/06 , C08J5/24 , F02F7/00 , F16J10/00 , B60B5/00
Abstract: A thermoplastic composite plate material (4) having a quasi isotropy comprises a thermoplastic resin having a melt viscosity of 1,000-15,000 poise and strip pieces (1) each constructed of unidirectionally orientated reinforcing fibers and each having the ratio of the width to the length thereof within specific ranges. The strip pieces (1) are randomly distributed in the plane parallel to a surface of the composite plate material (4). Since the composite plate material (4) has good quasi-isotropic and high mechanical properties such as flexural strength, flexural modulus and impact strength, a composite product having good quasi-isotropic and high mechanical properties can be obtained by using the composite plate materials (4). Moreover, since the composite plate material (4) can be easily fitted into a mould, a composite product having a complicated shape can be easily moulded.
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公开(公告)号:DE3274456D1
公开(公告)日:1987-01-15
申请号:DE3274456
申请日:1982-06-10
Applicant: TORAY INDUSTRIES
Inventor: CHIBA KAZUMASA , KOBAYASHI KAZUHIKO , MURAKI TOSHIO
IPC: C08G69/44
Abstract: An aliphatic copolyesteramide having a high degree of polymerization is prepared by heating a mixture of (A) ester-forming components comprising (a) aliphatic diols with 2 to 6 carbon atoms and (b) aliphatic dicarboxylic acids with 9 to 12 carbon atoms and (B) amide-forming components chosen from (a) aliphatic omega -aminocarboxylic acids having 11 or 12 carbon atoms and (b) equimolar salts of aliphatic diamines with 6 to 12 carbon atoms and aliphatic dicarboxylic acids with 9 to 12 carbon atoms, at temperatures of 150 to 260 DEG C, under a substantially atmospheric pressure, in the presence of catalyst and in the substantial absence of water, and subsequently heating the resulting esterified product at temperatures of 200 to 300 DEG C under a reduced pressure. The obtained copolyesteramide can be formed into various moulded articles, in particular such as tubes, having excellent flexibility, toughness, shapability, chemical resistance, heat resistance, hydrolysis resistance and fatigue resistance.
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公开(公告)号:AU1610795A
公开(公告)日:1995-10-19
申请号:AU1610795
申请日:1995-03-23
Applicant: TORAY INDUSTRIES
Inventor: MURAKI TOSHIO , TOKUNOU MASAZUMI , SAWAOKA RYUJI , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , TAZAKI TOKUO
Abstract: A prepreg precursor comprising a carbon fiber woven fabric having applied to the fabric from 0.5 to 10 wt% of a stabilizer material for rendering stable the structural form of the fabric. Prepregs can then be produced using the woven fabric. The undesired settlement, into the prepreg of matrix resin with which the fabric is impregnated in order to produce the prepreg and which is originally present on the surface of the woven fabric, is thus prevented. Hence, compared with a prepreg prepared using conventional woven fabric, a prepreg prepared by using the woven fabric of the invention can hold its tackiness for a long time and can be used to produce a fiber reinforced composite material excellent in smoothness without being devoid of the resin on the surface.
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公开(公告)号:DE68922979D1
公开(公告)日:1995-07-13
申请号:DE68922979
申请日:1989-11-23
Applicant: TORAY INDUSTRIES
Inventor: KIMOTO YUKITANE , MURATA KOHZOU , MURAKI TOSHIO
IPC: B29B11/16 , B29C45/00 , B29C45/02 , B29C70/06 , B29C70/14 , B29C70/46 , B29K101/12 , B29K105/06 , C08J5/24 , F02F7/00 , F16J10/00 , B60B5/00
Abstract: A thermoplastic composite plate material (4) having a quasi isotropy comprises a thermoplastic resin having a melt viscosity of 1,000-15,000 poise and strip pieces (1) each constructed of unidirectionally orientated reinforcing fibers and each having the ratio of the width to the length thereof within specific ranges. The strip pieces (1) are randomly distributed in the plane parallel to a surface of the composite plate material (4). Since the composite plate material (4) has good quasi-isotropic and high mechanical properties such as flexural strength, flexural modulus and impact strength, a composite product having good quasi-isotropic and high mechanical properties can be obtained by using the composite plate materials (4). Moreover, since the composite plate material (4) can be easily fitted into a mould, a composite product having a complicated shape can be easily moulded.
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公开(公告)号:CA2003561A1
公开(公告)日:1990-05-24
申请号:CA2003561
申请日:1989-11-22
Applicant: TORAY INDUSTRIES
Inventor: KIMOTO YUKITANE , MURATA KOHZOU , MURAKI TOSHIO
IPC: B29B11/16 , B29C45/00 , B29C45/02 , B29C70/06 , B29C70/14 , B29C70/46 , B29K101/12 , B29K105/06 , C08J5/24 , F02F7/00 , B29C67/14
Abstract: THERMOPLASTIC COMPOSITE PLATE MATERIAL AND PRODUCTS MOLDED FROM THE SAME A thermoplastic composite plate material having a quasi isotropy comprises a thermoplastic resin having a melt viscosity of 1,000-15,000 poise and strip pieces each constructed of unidirectionally orientated reinforcing fibers and each having the specific dimensions of the thickness, the width, the length and the ratio of the width and the length thereof. The strip pieces are randomly distributed in plane parallel to a surface of the composite plate material. Since the composite plate material has good quasi-isotropic and high mechanical properties such as flexural strength, flexural modulus and impact strength, the composite product having good quasi-isotropic and high mechanical properties can be obtained by using the composite plate materials. Moreover, since the composite plate material has a good fittability, a composite product having a complicated shape can be easily molded.
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公开(公告)号:DE2964673D1
公开(公告)日:1983-03-10
申请号:DE2964673
申请日:1979-10-25
Applicant: TORAY INDUSTRIES
Inventor: MURAKI TOSHIO
Abstract: A highly rigid poly-ε-caprolactam composition containing about 50 to 5000 ppm of barium and having a γ-type crystal ratio of about 0.3 to 0.7 is disclosed. The composition has improved rigidity without loss of other advantageous mechanical properties of poly-ε-caprolactam. By addition of an aluminium compound, e.g. aluminium stearate, the rigidity of the composition can be further improved. A bisamide compound, e.g. methylene-bis-stearylamide, may be added to provide excellent mold release without harming the mechanical properties of the composition.The composition is made by treating poly-ε-caprolactam with an aqueous solution containing Ba ions and heating the treated poly-ε-caprolactam to the molten state, or alternatively by melt-polymerizing ε-caprolactam in the presence of a suitable Ba compound e.g. barium-E-amino caprolate or Ba(OH) 2 . If aluminium is to be included, the barium-containing poly-ε-caprolactam can be melt-blended with an Al salt of an aliphatic carboxylic acid; alternatively e-caprolactam can be melt-polymerized in the presence of suitable barium and aluminium compounds.
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公开(公告)号:EP0020782A4
公开(公告)日:1982-04-22
申请号:EP79901613
申请日:1980-06-17
Applicant: TORAY INDUSTRIES
Inventor: CHIBA KAZUMASA , EGAWA KEIICHI , MURAKI TOSHIO
CPC classification number: G03F7/037
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