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公开(公告)号:JPS6049055A
公开(公告)日:1985-03-18
申请号:JP15507483
申请日:1983-08-26
Applicant: TORAY INDUSTRIES
Inventor: YONETANI KIICHI , KIDA SANJI , KOTANI NORIYOSHI , INOUE SHIYUNEI
IPC: C08L67/02 , B29C45/00 , B29C45/26 , C08J5/00 , C08K5/00 , C08K5/09 , C08K5/10 , C08L7/00 , C08L21/00 , C08L67/00 , C08L69/00
Abstract: PURPOSE:To provide the titled molded article having excellent grained surface and high mechanical properties, by mixing polybutylene terephthalate with polyethylene terephthalate and/or polycarbonate and optionally a montanic acid compound. CONSTITUTION:The objective polyester resin molded article having grained surface pattern is produced from a resin composition obtained by compounding 100pts.wt. of polybutylene terephthalate with (A) 1-100pts.wt. of polyethylene terephthalate and/or 1-100pts.wt. of polycarbonate, and if necessary (B) 0.05- 5pts.wt. of montanic acid, its salt, its ester or its ester salt. The molded article can be manufactured by molding the above specific polyester resin composition with a mold for injection molding and having grained cavity.
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公开(公告)号:JPS5817150A
公开(公告)日:1983-02-01
申请号:JP11512081
申请日:1981-07-24
Applicant: TORAY INDUSTRIES
Inventor: HIRAI AKIRA , KOTANI NORIYOSHI , AOYAMA TOSHIKAZU
IPC: C08L69/00 , C08G59/00 , C08G59/18 , C08G59/32 , C08G59/40 , C08G59/42 , C08K3/00 , C08K3/16 , C08K3/20 , C08L23/00 , C08L23/08 , C08L33/00 , C08L33/02 , C08L63/00 , C08L67/00 , C08L67/02 , C08L101/00
Abstract: PURPOSE:To obtain a flame-retardant polyester composition having a balanced impact resistance and balanced heat resistance and electrical properties, by adding to a thermoplastic polyester a halogenated bisphenol type copolymerized polycarbonate and an ethylenic copolymer. CONSTITUTION:100pts.wt. thermoplastic polyester are blended with 5-40pts.wt. halogenated bisphenol type copolymerized polycarbonate of formulaI[wherein X represents Br or C; R represents alkylene, carbonyl], ether, thioether or sulfone; p is 1-5; m and n are defined by formula II (wherein Mm is the weight of a cyclic unit represented by formula III and, Mn is that of a cyclic unit represented by formula IV), provided that 3
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公开(公告)号:JPS57192454A
公开(公告)日:1982-11-26
申请号:JP7664681
申请日:1981-05-22
Applicant: TORAY INDUSTRIES
Inventor: AOYAMA TOSHIKAZU , KOTANI NORIYOSHI , AKATSU TATSUO
Abstract: PURPOSE:To improve shape stability and impact resistance, by blending an ethylene copolymer having a specified copolymer composition and glass bead pretreated with epoxysilane, with a thermoplastic polyester. CONSTITUTION:1-30pts.wt. ethylene/glycidyl methacylate copolymer contg. 3-9wt% copolymerized glycidyl methacrylate and 7-150pts.wt. glass bead pretreated with epoxysilane, are blended with 100pts.wt. thermoplastic polyester such as polyethylene terephthalate or polyethylene naphthalate to produce the desired polyester compsn. for molding. The pretreatment of glass bead is conducted in such a manner that a soln. of epoxysilane is mixed with glass bead with stirring, and the mixture is left to stand in order to precipitate glass bead which is then separated and dried.
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公开(公告)号:JPH03269052A
公开(公告)日:1991-11-29
申请号:JP6678890
申请日:1990-03-19
Applicant: NIPPON PIGMENT , TORAY INDUSTRIES
Inventor: MUKAI EIZO , HANEDA KAZUO , YONETANI KIICHI , KOTANI NORIYOSHI
Abstract: PURPOSE:To provide a polybutylene terephthalate resin colored composition not staining molds and having excellent color transfer resistance and thermal stability by compounding polybutylene terephthalate resin with a specific blue coloring agent as an essential coloring component. CONSTITUTION:A colored composition comprises (A) polybutylene terephthalate having a relative viscosity (0.5% ortho-chlorophenol solution, 25 deg.C) of 1.3-2, especially 1.35-1.7, (B) at least one green coloring agent of CI. pigment blue 15:3, CI. pigment blue 15:1 and CI. solvent blue 132 in an amount of 0.001-5 pts.wt., more preferably 0.01-2 pts.wt., per 100 pts.wt. of the component A, if necessary, any other coloring agent and (C) a dispersing agent (preferably N,N'-ethylenebisstearic acid amide) in an amount of 0.1-2 pts.wt., preferably 0.1-1.5 pts.wt., per 1 pt.wt. of the component B.
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公开(公告)号:JPH03269050A
公开(公告)日:1991-11-29
申请号:JP6678690
申请日:1990-03-19
Applicant: NIPPON PIGMENT , TORAY INDUSTRIES
Inventor: MUKAI EIZO , HANEDA KAZUO , YONETANI KIICHI , KOTANI NORIYOSHI
Abstract: PURPOSE:To provide a polybutylene terepthalate resin colored composition not staining molds and having color transfer resistance and thermal stability by compounding polybutylene terephthate resin with a specific organic red pigment as an essential coloring component. CONSTITUTION:A composition comprises (A) polybutylene terephthate resin having a relative viscosity (0.5% ortho-chlorophenol solution, 25 deg.C) of preferably 1.3-2, especially 1.35-1.7, (B) at least one of CI. pigment red 247, CI. pigment red 151, CI. pigment violet 19, CI. pigment red 122 and CI. pigment red 202 in an amount of preferably 0.0001-5 pts., more preferably 0.01-2 pts.wt., per 100 pts.wt. of the component A, if necessary, an inorganic pigment, and (C) a dispersing agent (preferably N,N'-ethylenebis-stearic acid amide) in an amount of 0.1-2 pts.wt. per 1 pt.wt. of the component B.
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公开(公告)号:JPH03269049A
公开(公告)日:1991-11-29
申请号:JP6678590
申请日:1990-03-19
Applicant: NIPPON PIGMENT , TORAY INDUSTRIES
Inventor: MUKAI EIZO , HANEDA KAZUO , YONETANI KIICHI , KOTANI NORIYOSHI
Abstract: PURPOSE:To provide a polybutylene terephthalate resin colored composition not staining molds and having excellent color transfer resistance and thermal stability by compounding polybutylene terephthalate resin with a specific organic yellow pigment as an essential coloring component. CONSTITUTION:A colored resin composition comprises (A) polybutylene terephthalate resin having a relative viscosity (0.5% orthochlorophenol solution, 25 deg.C) of preferably 1.3-2, especially 1.35-1.7, (B) at least one of CI. pigment yellow 183, CI. pigment yellow 190 and CI. pigment yellow 150 in an amount of preferably 0.001-5 pts.wt., more preferably 0.01-2 pts.wt., based on 100 pts.wt. of the component A, if necessary, an inorganic pigment and (C) a dispersing agent (preferably N,N'-ethylenebisstearic acid amide) in an amount of 0.1-2 pts.wt., preferably 0.4-1.5 pts.wt., per 1 pt.wt. of the component B.
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公开(公告)号:JPH0386757A
公开(公告)日:1991-04-11
申请号:JP22161789
申请日:1989-08-30
Applicant: TORAY INDUSTRIES
Inventor: NAKASE MICHIYUKI , OSANAWA NOBUO , KOTANI NORIYOSHI
Abstract: PURPOSE:To produce a molding resin compsn. excellent in the low-temp. impact strength, heat resistance, etc., by melt mixing an aliph. polyamide, a polyphenylene ether, a specific diene block copolymer, and an alpha,beta-unsatd. carboxylic acid in a specific way. CONSTITUTION:A polyphenylene ether is melt mixed with an alpha,beta-unsatd. carboxylic acid (e.g. maleic anhydride) and then with 5-95wt.% aliph. polyamide (e.g. nylon 6) and a diene block copolymer selected from the group consisting of an A-B-A' type block copolymer elastomer (wherein A and A' are each an arom. hydrocarbon polymer block; and B is a conjugated diene polymer block) and a hydrogenated A-B-A' type block copolymer elastomer (wherein the internal polymer block B is hydrogenated). The resulting mixture is further melt mixed with the rest, 95-5wt.% of the polyamide, thus producing a molding resin compsn.
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公开(公告)号:JPS58171438A
公开(公告)日:1983-10-08
申请号:JP5375782
申请日:1982-04-02
Applicant: TORAY INDUSTRIES
Inventor: HIRAI AKIRA , KOTANI NORIYOSHI , OKAMOTO TAKEHIKO
Abstract: PURPOSE:The titled composition for providing a molded article having improved impact resistance, rigidity at high temperature and surface gloss, obtained by blending a thermoplastic polyester with a glycidyl group-containing copolymer and/or an ethylenic copolymer and potassium titanate whisker. CONSTITUTION:100pts.wt. thermoplastic polyester (preferably polybutylene terephthalate or polyethylene terephthalate) is blended with (A) 0.1-40pts.wt. ethylenic copolymer consisting of an alpha-olefin and a glycidyl ester (the amount of the copolymerization of glycidyl ester of an alpha,beta-unsaturated acid is preferably 3- 9wt%) of an alpha,beta-unsaturated acid and/or ethylenic copolymer consisting of ethylene and >=3C alpha-olefin and (B) 1-70pts.wt., preferably 5-20pts.wt. potassium titanate whisker, white needle-like crystal having 10-20mum average fiber length and 0.2-0.5mum fiber diameter, consisting of single crystal fiber of potassium titanate.
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公开(公告)号:JPS5817149A
公开(公告)日:1983-02-01
申请号:JP11511981
申请日:1981-07-24
Applicant: TORAY INDUSTRIES
Inventor: HIRAI AKIRA , KOTANI NORIYOSHI , AOYAMA TOSHIKAZU
Abstract: PURPOSE:To obtain a flame-retardant polyester composition having a balanced extrusion stability and balanced heat resistance and electrical properties, by adding to a thermoplastic polyester a halogenated bisphenol type copolymerized polycarbonate and a phosphite compound. CONSTITUTION:100pts.wt. thermoplastic polyester are blended with 5-40pts.wt. halogenated bisphenol type copolymerized polycarbonate of the formulaI[wherein X represents Br or C; R represents alkylene, carbonyl, etc.; p is 1-5; m and n are defined by formula II (wherein Mm is the weight of a cyclic unit represented by formula III and Mn is that of a cyclic unit represented by formula IV), provided that 3
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公开(公告)号:JPS5817147A
公开(公告)日:1983-02-01
申请号:JP11511781
申请日:1981-07-24
Applicant: TORAY INDUSTRIES
Inventor: HIRAI AKIRA , KOTANI NORIYOSHI , AOYAMA TOSHIKAZU
Abstract: PURPOSE:To obtain a flame-retardant polyester composition excellent in heat resistance and electrical and mechanical properties, by blending a thermoplastic polyester with a halogenated bisphenol type copolymerized polycarbonate, antimony trioxide, and asbestos fibers. CONSTITUTION:100pts.wt. thermoplastic polyester are blended with 5-40pts.wt. halogenated bisphenol type copolymerized polycarbonate of the formulaI[wherein X represents Br or Cl; R represents alkylene, carbonyl, ether, thioether or sulfone; p is 1-5; m and n are defined by formula II (wherein Mm is the weight of a cyclic unit represented by formula III and Mn is that of a cyclic unit represented by formula IV), provided that 3
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