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公开(公告)号：JPS5441843A
公开(公告)日：1979-04-03
申请号：JP10727977
申请日：1977-09-08
Applicant: TORAY INDUSTRIES
Inventor： KONDOU TSUNEYUKI , KURODA AKIO , MATSUHISA SEIKICHI
Abstract: PURPOSE:The selective adsorption of cyclohexene in benzene is conducted by using an adsorbent of Y-type aluminosilicate zeolite thereby isolating cyclohexene of high purity in simple operation and high economy. CONSTITUTION:A mixture of cyclohexene along with benzene and cyclohexane is brought into contact with a Y-type aluminosilicate zeolite of the formula Mn/2O Al2O3.xSiO2.yH2O (M is metal, n is valency of the metal, x is 3-6, y is the content of crystal water) which is previously subjected to dewatering treatment at 200-600 deg.C, at 0-50 deg.C to remove benzene by adsorption. Then the resulting mixture of cyclohexene and cyclohexane is treated with another Y- type aluminosilicate zeolite to remove cyclohexene by adsorption. The cyclohexene and benzene adsorbed on zeolites are liberated from zeolites by heating and recovered respectively.
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公开(公告)号：JPS5441844A
公开(公告)日：1979-04-03
申请号：JP10728077
申请日：1977-09-08
Applicant: TORAY INDUSTRIES
Inventor： KONDOU TSUNEYUKI , KURODA AKIO , MATSUHISA SEIKICHI
Abstract: PURPOSE:High-purity cyclohexene is isolated inexpensively by simple operations from benzene containing cyclohexene by selective adsorption on an adsorbent of X-type alminosilicate zeolite. CONSTITUTION:A mixture containing cycloexene, cyclohexane and benzene is brought into contact with an X-type aluminosilicate zeolite of the formula Mn/2O Al2O3.xSiO2yH2O (M is metal, n is valency of M, x is 2-3, y is the content of crystal water) which is previously dewatered by heating at 200-600 deg.C, at 0-50 deg.C to remove bezene by adsorption. Then the mixture of cyclohexane and cyclohexene is treated with another X-type aluminosilicate zeolite to remove cyclohexene by adsorption. The benzene and cyclohexene adsorbed on above zeolites are liberated by heating and recovered respectively.
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公开(公告)号：JPS5359649A
公开(公告)日：1978-05-29
申请号：JP13467276
申请日：1976-11-11
Applicant: TORAY INDUSTRIES
Inventor： YASUHARA YUTAKA , NISHINO MASAKI , MATSUHISA SEIKICHI
IPC: C07C69/75 , B01J23/00 , B01J23/50 , B01J23/72 , C07B61/00 , C07C17/00 , C07C17/02 , C07C23/10 , C07C27/00 , C07C29/00 , C07C35/08 , C07C67/00 , C07C69/02
Abstract: PURPOSE:To prepare cyclohexane derivatives, useful as raw materials for organic chemicals, with one-step process by simultaneous hydrogenative reduction and addition of an aromatic hydrocarbon with an organic acid, etc. in the presence of a strong acid and specific catalysts.
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公开(公告)号：JPS51138648A
公开(公告)日：1976-11-30
申请号：JP6300675
申请日：1975-05-28
Applicant: TORAY INDUSTRIES
Inventor： AIZAWA HIDEYUKI , KURODA AKIO , MITSUNAGA MASAHIRO , OONISHI KOUJI , MATSUHISA SEIKICHI
Abstract: PURPOSE:To prepare cyclohexene easily and in good yield by heating dicyclohexylether in the presence of acid catalysts.
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公开(公告)号：JPS5154535A
公开(公告)日：1976-05-13
申请号：JP12752374
申请日：1974-11-07
Applicant: TORAY INDUSTRIES
Inventor： YASUHARA YUTAKA , NISHINO KATSUTAKA , MATSUHISA SEIKICHI
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Patent Agency Ranking
公开(公告)号：JPS5929172B2
公开(公告)日：1984-07-18
申请号：JP4876080
申请日：1980-04-15
Applicant: Toray Industries
Inventor： YASUHARA YUTAKA , NISHINO MASAKI , MATSUHISA SEIKICHI
IPC: C07C69/03 , B01J23/00 , B01J23/40 , C07B61/00 , C07C27/00 , C07C29/00 , C07C29/19 , C07C35/08 , C07C67/00 , C07C67/04
CPC classification number: Y02P20/52
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公开(公告)号：JPS53144544A
公开(公告)日：1978-12-15
申请号：JP5874677
申请日：1977-05-23
Applicant: TORAY INDUSTRIES
Inventor： YASUHARA YUTAKA , NISHINO MASAKI , MATSUHISA SEIKICHI
IPC: C07C29/00 , B01J23/00 , B01J23/46 , B01J23/68 , B01J23/84 , C07B61/00 , C07C27/00 , C07C35/08 , C07C67/00
Abstract: PURPOSE:In the hydrogenation of an aromatic hydrocarbon in an aqueous strong oxy acid solution in the presence of a catalyst of noble metal of Group VIII in the peridic table, a specific alcohol is incorporated thereinto to produce title compound with economical advantage, which is useful as solvents and feedstocks for synthetic high-polymer matrials.
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公开(公告)号：JPS53144543A
公开(公告)日：1978-12-15
申请号：JP5874777
申请日：1977-05-23
Applicant: TORAY INDUSTRIES
Inventor： YASUHARA YUTAKA , NISHINO MASAKI , MATSUHISA SEIKICHI
IPC: C07C69/02 , B01J23/00 , B01J23/68 , B01J27/00 , B01J31/00 , C07B61/00 , C07C17/00 , C07C17/02 , C07C17/08 , C07C17/10 , C07C23/08 , C07C23/10 , C07C29/00 , C07C29/04 , C07C35/08 , C07C67/00 , C07C67/04
Abstract: PURPOSE:Hydrogenation of an aromatic hydrocarbon is conducted in the presence Hydrogenation of an aromatic hydrocarbon is conducted in the presence of a strong acid using a specific hydrogenation catalyst and simultaneously an addition reaction is carried out using a specific addition reaction agent to produce economically said compound useful as a starting material or solvent in organic synthetic chemistry in one stage.
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公开(公告)号：JPS5268146A
公开(公告)日：1977-06-06
申请号：JP14333375
申请日：1975-12-04
Applicant: TORAY INDUSTRIES
Inventor： YASUHARA YUTAKA , NISHINO KATSUTAKA , MATSUHISA SEIKICHI
IPC: C07C69/03 , B01J21/00 , B01J23/40 , C07B61/00 , C07C17/00 , C07C17/02 , C07C17/08 , C07C23/10 , C07C27/00 , C07C29/00 , C07C35/08 , C07C61/00 , C07C67/00
Abstract: PURPOSE:Cyclohexane derivatives are prepared with a one-stage process by the addition of water, an organic acid or hydrogen halide to an aromatic hydrocarbon at the hydrogenation thereof.
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公开(公告)号：JPS518243A
公开(公告)日：1976-01-23
申请号：JP7870374
申请日：1974-07-11
Applicant: TORAY INDUSTRIES
Inventor： AIZAWA HIDEYUKI , KURODA AKIO , MITSUNAGA MASAHIRO , OONISHI KOJI , MATSUHISA SEIKICHI
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