公开(公告)号：EP0306729A1

公开(公告)日：1989-03-15

申请号：EP88113130.4

申请日：1988-08-12

Applicant: ATOCHEM NORTH AMERICA, INC.

Inventor： Myers, Terry Ned ,  MacLeay, Ronald Edward

IPC: C08F8/30 ,  C08F8/34

CPC classification number: C08F8/30 ,  C08F8/34

Abstract: Polymer bound antioxidants in which the antioxidant stabilizer groups are chemically bound to polymers or copolymers by an acylaminoimide or diacylhydrazide function are prepared by reacting hydrazido substituted anti­oxidants with some or all of the anhydride groups of anhydride containing polymers or copolymers to form a polymer with recurring units selected from the formulas
or both wherein the units occur, e.g., in the polymer backbone, x is 0 or 1, R¹ and R² are, e.g., hydrogen and G is, e.g.,
wherein
R³ is t-alkyl of 4-8 carbons,
R⁴ is, e.g., hydrogen and
X¹ is, e.g., -N(R)-C(=O)-(CH₂) b -
wherein
R is e.g., hydrogen and
b is 0, 1 or 2.
The concentration of the stabilizers bound to the polymer may be readily varied depending upon the particular end-­use of said polymer. Polymer with high concentrations of bound antioxidants can be used as masterbatches to stabilize other polymer systems.

Abstract translation: 通过使酰肼取代的抗氧化剂与含酸酐的聚合物或共聚物的一部分或全部酸酐基团反应形成具有重复单元的聚合物来制备聚合物结合的抗氧化剂，其中抗氧化剂稳定剂基团通过酰氨基酰亚胺或二酰基酰肼官能团化学键合到聚合物或共聚物上 选自式（CHEM）或其中单元出现的二者，例如在聚合物骨架中，x为0或1，R 1和R 2为例如氢，G为例如 其中R 3为4-8个碳的叔烷基，R 4为例如氢，X 1为例如-N（R）-C（= O） - （CH 2）b - 其中R为例如氢，b为0,1或2.结合聚合物的稳定剂的浓度可根据所述聚合物的特定最终用途容易地变化。 具有高浓度结合的抗氧化剂的聚合物可用作母料以稳定其它聚合物体系。

公开(公告)号：EP0293672A1

公开(公告)日：1988-12-07

申请号：EP88107950.3

申请日：1988-05-18

Applicant: ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.)

Inventor： Sandler, Stanley Robert

IPC: C07C309/05 ,  C07C303/08

CPC classification number: C07C309/00

Abstract: Alkanedisulfonic acids, particularly methanedisulfonic acid (methionic acid), can be prepared by reacting the corresponding alkanesulfonic acid with chlorosulfonic acid. The reaction is carried out by heating the reactants with agitation, preferably under substantially anhydrous conditions in the presence of oxygen and at substantially atmospheric pressure. Particularly good yields are obtained using an activated carbon co-catalyst.

Abstract translation: 烷烃二磺酸，特别是甲基二磺酸（甲酸）可以通过使相应的烷烃磺酸与氯磺酸反应来制备。 反应通过在搅拌下加热反应物进行，优选在基本无水的条件下，在氧的存在下和在大气压下进行。 使用活性炭助催化剂可获得特别好的收率。

公开(公告)号：EP0273097A1

公开(公告)日：1988-07-06

申请号：EP87108901.7

申请日：1987-06-22

Applicant: ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.)

Inventor： Wheaton, Gregory Alan

IPC: C25B3/10

CPC classification number: C25B3/10

Abstract: Dialkanesulfonyl peroxide (RSO₂-0-0-0₂SR) is prepared in a continuous process by electrolyzing the corresponding alkanesulfonic acid at an elevated temperature (to keep the peroxide product in solution ) in a continmuous-flow electrolysis cell, removing the solution from the electrolytic cell, cooling the solution to precipitate the peroxide product, and recycling the supernatant alkanesulfonic acid back to the cell.

Abstract translation: 通过在升高的温度下电解相应的链烷磺酸（将过氧化物产物保持在溶液中）在连续流动的电解槽中，从电解质中除去溶液，以连续方法制备过氧化二甲基磺酰基（RSO 2 -O-0-0 2 SR） 将溶液冷却以沉淀过氧化物产物，并将上清液中的链烷磺酸再循环回细胞。

公开(公告)号：EP0183999A1

公开(公告)日：1986-06-11

申请号：EP85114002.0

申请日：1985-11-04

Applicant: ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.)

Inventor： Dahl, Gerd H. ,  Simkin, Joseph

IPC: A01N25/28 ,  B01J13/02

CPC classification number: A01N25/28 ,  Y10S514/963

Abstract: A sprayable insecticidal composition of low fish toxicity of a mixture in water of microcapsules comprised of a pyrethroid (synthetic pyrethrin) contained within an encapsulating wall of a cross-linked polymeric material, and methods of preparation and method of use of the composition on a wide variety of crops and aquatic sites infested with a broad spectrum of undesirable insects.

公开(公告)号：EP0788471B1

公开(公告)日：2000-09-20

申请号：EP96926737.6

申请日：1996-07-18

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： SILVERMAN, Gary, Stephen ,  MERCANDO, Paul

IPC: C07C45/50 ,  B01J31/40

CPC classification number: C07C45/50 ,  Y02P20/584 ,  C07C47/02

Abstract: Active Rhodium catalyst and impurities are separated from a hydroformylation process stream containing both active and inactive organo-rhodium catalyst by binding active catalyst and impurities to an acidic ion exchange resin containing an acidic group. The purified hydroformylation stream can be returned to the hydroformylation reactor. All or a portion of inactive rhodium can be reactivated before recycling purified hydroformylation process stream to the reactor. During regeneration of the resin, a neutral solvent is used first to remove impurities which are discarded, then an acidic solvent is used to remove active organic rhodium catalyst from the resin. Such active catalyst can be rehydrided and returned to the hydroformylation reactor. An ion exchange resin having at least one acid group disposed on a silica backbone and an active organo-rhodium complex from a hydroformylation process stream bound to the resin can be produced.

公开(公告)号：EP0974571A3

公开(公告)日：2000-04-12

申请号：EP99305781.9

申请日：1999-07-21

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Elsheikh, Maher Yousef ,  Fellenger, Paul David

IPC: C07C17/25

CPC classification number: C07C17/25 ,  C07C21/18

Abstract: Disclosed is a process for the preparation of cis/trans 1,1,1,3-tetrafluoro-2-propene (1234 ze) which comprises (a) contacting 1,1,1,3,3-pentafluoropropane (245fa) with an alkaline solution, preferably an aqueous or alcoholic solution of a base such as KOH, NaOH, Ca(OH) 2 or Mg(OH) 2 , or with a chromium-based catalyst, such as fluorided Cr 2 O 3 or fluorided Cr/Ni/Alf 3 , and (b) recovering cis/trans 1,1,1,3-tetrafluoro-2-propene from the reaction mixture.

Abstract translation: 本发明公开了制备顺式/反式1,1,1,3-四氟-2-丙烯（1234ze）的方法，该方法包括（a）使1,1,1,3,3-五氟丙烷（245fa）与 碱性溶液，优选碱如KOH，NaOH，Ca（OH）2或Mg（OH）2的水溶液或醇溶液，或与铬基催化剂如氟化Cr2O3或氟化Cr / Ni / 和（b）从反应混合物中回收顺式/反式1,1,1,3-四氟-2-丙烯。

公开(公告)号：EP0983972A2

公开(公告)日：2000-03-08

申请号：EP99306694.3

申请日：1999-08-23

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： McKown, Clem Steffler ,  Roger, Christophe ,  Russo, David Alan ,  Stricker, Jeffrey Lee

IPC: C03C17/34 ,  C03C17/245

CPC classification number: C03C17/2453 ,  C03C17/3417 ,  C03C2217/211 ,  C03C2217/24 ,  C03C2217/241 ,  C03C2217/244 ,  C03C2218/152 ,  Y10T428/24975

Abstract: A solar-control glass that has acceptable visible light transmission, absorbs near infrared wavelength light (NIR) and reflects midrange infrared light (low emissivity mid IR) along with a preselected color within the visible light spectrum for reflected light is provided. Also provided is a method of producing the improved, coated, solar-controlled glass. The improved glass has a solar energy (NIR) absorbing layer comprising tin oxide having a dopant such as antimony and a low emissivity control layer (low emissivity) capable of reflecting midrange infrared light and comprising tin oxide having fluorine and/or phosphorus dopant. A separate iridescence color suppressing layer as described in the prior art is generally not needed to achieve a neutral (colorless) appearance for the coated glass, however an iridescence suppressing layer or other layers may be combined with the two layer assemblage provided by the present invention. Ifdesired, multiple solar control and/or multiple low emissivity layers can be utilized. The NIR layer and the low emissivity layer can be separate portions ofa single tin oxide film since both layers are composed of doped tin oxide. A method of producing the coated solar control glass is also provided.

Abstract translation: 提供具有可接受的可见光透射，吸收近红外波长光（NIR）并且反射中频红外光（低辐射率IR）的太阳能控制玻璃以及用于反射光的可见光光谱内的预选颜色。 还提供了一种生产改进的涂覆的太阳能控制玻璃的方法。 改进的玻璃具有包含具有诸如锑的掺杂剂的氧化锡和能够反射中频红外光并且包含具有氟和/或磷掺杂剂的氧化锡的低发射率控制层（低发射率）的太阳能（NIR）吸收层。 通常不需要如现有技术中所述的单独的虹彩色抑制层来实现涂覆玻璃的中性（无色）外观，然而可以将虹彩抑制层或其它层与本发明提供的两层组合物组合 。 如果需要，可以使用多个太阳能控制和/或多个低发射率层。 NIR层和低发射率层可以是单一氧化锡膜的分离部分，因为两层都由掺杂的氧化锡组成。 还提供了一种生产涂覆的太阳能控制玻璃的方法。

公开(公告)号：EP0573639B1

公开(公告)日：1999-10-27

申请号：EP93901245.6

申请日：1992-12-21

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： RUSSO, David, A. ,  DIRKX, Ryan, R. ,  FLORCZAK, Glenn, P.

IPC: C03C17/245

CPC classification number: C23C16/40 ,  C03C17/2453 ,  C03C17/3417 ,  C03C2217/23 ,  C03C2217/91 ,  C03C2218/1525

Abstract: A composition for coating glass by chemical-vapor deposition comprises a mixture of a tin oxide precursor monobutyltin trichloride, a silicon dioxide precursor tetraethylorthosilicate, and an accelerant such as triethyl phosphite; the composition is gaseous below 200 °C, and permits coating glass having a temperature from 450 to 650 °C at deposition rates higher than 350 Å/sec. The layer of material deposited can be combined with other layers to produce an article with specific properties such as controlled emissivity, refractive index, abrasion resistance, or appearance.

公开(公告)号：EP0939747A1

公开(公告)日：1999-09-08

申请号：EP98944642.0

申请日：1998-09-01

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： PAPANU, Victor, Dennis ,  CARSON, Stephen, William ,  SCHWARTZ, Scott, Jay

IPC: C03C17

CPC classification number: C03C17/32 ,  C03C17/001 ,  C03C17/002 ,  C03C17/30 ,  Y10T428/1317 ,  Y10T428/1321 ,  Y10T428/219 ,  Y10T428/24926 ,  Y10T428/315 ,  Y10T428/31612 ,  Y10T428/31663

Abstract: A method is described for strengthening or restoring strength to a flat brittle oxide substrate (12) which includes the steps of coating the edges of the brittle oxide substrate (12) with a strengthening composition without coating a significant portion of the major flat surfaces of the substrate (12). The strengthened brittle oxide substrate (12), such as glass, and a window containing as a window pane the edge strengthened glass (12) are also provided.

公开(公告)号：EP0927706A2

公开(公告)日：1999-07-07

申请号：EP99106266.2

申请日：1992-12-21

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Russo, David A. ,  Dirkx, Ryan R. ,  Florczak, Glenn P.

IPC: C03C17/245 ,  C03C17/23

CPC classification number: C23C16/40 ,  C03C17/2453 ,  C03C17/3417 ,  C03C2217/23 ,  C03C2217/91 ,  C03C2218/1525

Abstract: A glass substrate having a coating comprising a film containing a metal oxide, an oxide of silicon and an oxide of phosphorus or boron. The metal oxide is preferably selected from the group of tin oxide, germanium oxide, titanium oxide, aluminium oxide, zirconium oxide, zinc oxide, indium oxide, cadmium oxide, tungsten oxide, vanadium oxide, chromium oxide, molybdenum oxide, iridium oxide, nickel oxide, and tantalum oxide.

Abstract translation: 一种具有包含含有金属氧化物，硅氧化物和磷或硼的氧化物的膜的涂层的玻璃基板。 金属氧化物优选选自氧化锡，氧化锗，氧化钛，氧化铝，氧化锆，氧化锌，氧化铟，氧化镉，氧化钨，氧化钒，氧化铬，氧化钼，氧化铱，镍 氧化物和氧化钽。