POLYETHYLENE FILM WITH HIGH TENSILE STRENGTH AND HIGH TENSILE ENERGY TO BREAK
    241.
    发明申请
    POLYETHYLENE FILM WITH HIGH TENSILE STRENGTH AND HIGH TENSILE ENERGY TO BREAK 有权
    聚乙烯薄膜,具有高拉伸强度和高拉伸强度

    公开(公告)号:US20100144224A1

    公开(公告)日:2010-06-10

    申请号:US12452526

    申请日:2008-07-02

    Abstract: The present invention pertains to a UHMWPE film having a tensile strength of at least 2.0 GPa, a tensile energy to break of at least 30 J/g, an Mw of at least 500 000 gram/mole, and a Mw/Mn ratio of at most 6. The film may be manufactured via a process which comprises subjecting a starting UHMWPE with a weight average molecular weight of at least 500 000 gram/mole, an elastic shear modulus determined directly after melting at 160° C. of at most 0.9 MPa, and a Mw/Mn ratio of at most 6 to a compacting step and a stretching step under such conditions that at no point during the processing of the polymer its temperature is raised to a value above its melting point. The film may be used as starting material in any applications where high tensile strength and high energy to break are important. Suitable applications include ballistic applications, ropes, cables, nets, fabrics, and protective applications.

    Abstract translation: 本发明涉及一种抗拉强度为至少2.0GPa,拉伸断裂能至少为30J / g,Mw至少为500000克/摩尔,Mw / Mn比为 该膜可以通过以下方法制造,该方法包括使重均分子量为至少500000克/摩尔的起始UHMWPE,在160℃下熔融后直接测定的弹性剪切模量为至多0.9MPa ,并且在这样的条件下,在聚合物加工过程中任何时候,其温度升高到高于其熔点的值的条件下,Mw / Mn比至多为6的压实步骤和拉伸步骤。 在高抗拉强度和高能量破裂重要性的任何应用中,该膜可用作起始材料。 合适的应用包括弹道应用,绳索,电缆,网,织物和保护性应用。

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