PROCESS FOR THE PREPARATION OF LACTAMS THROUGH OXIME ISOMERIZATION

    公开(公告)号:GB2014572B

    公开(公告)日:1982-07-14

    申请号:GB7905164

    申请日:1979-02-14

    Applicant: ATO CHIMIE

    Abstract: The invention relates to a process for the preparation of lactames according to the so-called "Beckmann rearrangement" which consists in isomerizing oximes in a sulfuric solution, the weight ratio percentage of sulfuric acid to the combined amount of sulfuric acid and water being raised to a value above that of the sulfuric solution feed.

    PROCESS FOR PRODUCING DODECALACTAM
    266.
    发明专利

    公开(公告)号:SU938741A3

    公开(公告)日:1982-06-23

    申请号:SU2729503

    申请日:1979-02-16

    Applicant: ATO CHIMIE

    Abstract: The invention relates to a process for the preparation of lactames according to the so-called "Beckmann rearrangement" which consists in isomerizing oximes in a sulfuric solution, the weight ratio percentage of sulfuric acid to the combined amount of sulfuric acid and water being raised to a value above that of the sulfuric solution feed.

    269.
    发明专利
    未知

    公开(公告)号:DE2203945C3

    公开(公告)日:1980-11-20

    申请号:DE2203945

    申请日:1972-01-28

    Abstract: Object of the invention is a process for the purification of epsilon -caprolactam prepared either by Beckmann rearrangement or by rearrangement of cyclohexanoxime in the gaseous phase or by depolymerisation of polyamide waste comprising treating the solid, finely-divided crude lactam with an organic solvent for a period of up to 60 hours at a temperature from 0 DEG to 50 DEG C. According to the purification process many impurities could be removed without a substantial decrease in the yield of the purified caprolactam.

    270.
    发明专利
    未知

    公开(公告)号:DE2203945B2

    公开(公告)日:1980-03-27

    申请号:DE2203945

    申请日:1972-01-28

    Abstract: Object of the invention is a process for the purification of epsilon -caprolactam prepared either by Beckmann rearrangement or by rearrangement of cyclohexanoxime in the gaseous phase or by depolymerisation of polyamide waste comprising treating the solid, finely-divided crude lactam with an organic solvent for a period of up to 60 hours at a temperature from 0 DEG to 50 DEG C. According to the purification process many impurities could be removed without a substantial decrease in the yield of the purified caprolactam.

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