Method for producing nitro compound and catalyst therefor
    286.
    发明专利
    Method for producing nitro compound and catalyst therefor 审中-公开
    生产硝基化合物及其催化剂的方法

    公开(公告)号:JP2003277330A

    公开(公告)日:2003-10-02

    申请号:JP2003004198

    申请日:2003-01-10

    Inventor: HAGITANI KOJU

    CPC classification number: Y02P20/52

    Abstract: PROBLEM TO BE SOLVED: To provide a method for industrially advantageously producing a nitro compound by reacting a primary amine (with the proviso that the carbon atom to which an amino group is bound has no hydrogen atom) with hydrogen peroxide. SOLUTION: The method for producing the nitro compound comprises reacting the primary amine (with the proviso that the carbon atom to which the amino group is bound has no hydrogen atom) with the hydrogen peroxide in the presence of a metal oxide catalyst. The metal oxide catalyst is prepared by reacting at least one kind selected from the group consisting of tungsten metal, molybdenum metal, a tungsten compound composed of tungsten and a group IIIb element, a group IVb element, a group Vb element or a group VIb element except oxygen and a molybdenum compound composed of molybdenum and the group IIIb element, the group IVb element, the group Vb element or the group VIb element except oxygen with the hydrogen peroxide. COPYRIGHT: (C)2004,JPO

    Abstract translation: 待解决的问题:提供一种工业上有利地通过使伯胺(其中氨基被结合的碳原子不具有氢原子)与过氧化氢反应而产生硝基化合物的方法。 解决方案:硝基化合物的制备方法包括在金属氧化物催化剂的存在下使伯胺(前提条件是氨基被结合的碳原子不具有氢原子)与过氧化氢反应。 金属氧化物催化剂通过使选自钨金属,钼金属,钨组成的钨化合物和IIIb族元素,IVb族元素,Vb族元素或VIb族元素中的至少一种 除了氧和由钼组成的钼化合物和IIIb族元素,IVb族元素,Vb族元素或VIb族元素除了氧与过氧化氢之外。 版权所有(C)2004,JPO

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