公开(公告)号：WO2006101778A1

公开(公告)日：2006-09-28

申请号：PCT/US2006/008656

申请日：2006-03-10

Applicant: GENERAL ELECTRIC COMPANY ,  RUBINSZTAJN, Slawomir ,  CELLA, James, Anthony ,  MALENFANT, Patrick, Roland, Lucien

Inventor： RUBINSZTAJN, Slawomir ,  CELLA, James, Anthony ,  MALENFANT, Patrick, Roland, Lucien

IPC: C08G77/08 ,  C08G77/10 ,  C08G77/12

CPC classification number: C08G77/12 ,  C08G77/08 ,  C08G77/10 ,  C08K5/56

Abstract: Disclosed is a crosslinked polysiloxane network comprising both residual Si-H linkages and a Lewis acid catalyst, wherein the network is derived from a linear hydridosiloxane, a branched hydridosiloxane, a cyclic hydridosiloxane or a mixture of a linear hydridosiloxane or branched hydridosiloxane and a cyclic hydridosiloxane. Disclosed also is a method to produce the crosslinked polysiloxane network, alternatively accompanied by a silane with aliphatic, aromatic, or cycloaliphatic substituents by reacting in the presence of an effective amount of a Lewis acid catalyst a linear hydridosiloxane, a branched hydridosiloxane, a cyclic hydridosiloxane or a mixture of a linear hydridosiloxane or branched hydridosiloxane and a cyclic hydridosiloxane.

Abstract translation: 公开了一种包含残留Si-H键和路易斯酸催化剂的交联聚硅氧烷网络，其中网络衍生自线性氢硅氧烷，支链氢硅氧烷，环状氢化硅氧烷或直链羟基硅氧烷或支链氢硅氧烷和环状硅氢化合物的混合物 。 还公开了一种制备交联聚硅氧烷网络的方法，或者伴随着具有脂族，芳族或脂环族取代基的硅烷，在有效量的路易斯酸催化剂的存在下，通过线性羟基硅氧烷，支链氢硅氧烷，环状氢化硅氧烷 或直链羟基硅氧烷或支链氢硅氧烷和环状氢化硅氧烷的混合物。

公开(公告)号：WO2006076247A3

公开(公告)日：2006-08-31

申请号：PCT/US2006000572

申请日：2006-01-09

Applicant: GEN ELECTRIC ,  LITZ KYLE ERIK ,  CELLA JAMES ANTHONY ,  YE QING

Inventor： LITZ KYLE ERIK ,  CELLA JAMES ANTHONY ,  YE QING

IPC: C07D487/22 ,  C09K11/07

CPC classification number: C07D487/22

Abstract: The invention discloses compounds of structure I wherein M is a divalent, bivalent or tetravalent metal ion; "a" is 0, 1, 2, or a non-zero fraction having a value between 0 and 1; Y is independently at each occurrence a charge balancing counterion; R 1 and R 2 are independently at each occurrence a halogen, a C 1 -C 20 aliphatic radical, a C 3 -C 20 cycioaliphatic radical, a C 2 -C 20 aromatic radical, or R 1 and R 2 may together form a divalent aliphatic radical, a divalent cycioaliphatic radical, or a divalent aromatic radical; R 3 is independently at each occurrence an organic radical having structure II wherein Ar 1 is a C 2 -C 50 aromatic radical; L 1 is a C 1 -C 20 aliphatic radical, a C 3 -C 20 cycioaliphatic radical, or a C 2 -C 20 aromatic radical; F is independently at each occurrence a structural unit derived from an olefin monomer selected from the group consisting of polycyclic olefin monomers and heterocyclic olefin monomers; "n" is independently at each occurrence an integer from 1 to about 200; Q is independently at each occurrence a hydrogen, a halogen, a C 1 -C 20 aliphatic radical, a C 3 -C 20 cycioaliphatic radical, or a C 2 -C 20 aromatic radical; and "m" is independently at each occurrence an integer from 1 to about 10.

Abstract translation: 本发明公开了结构I的化合物，其中M是二价，二价或四价金属离子; “a”为0,1,2或具有介于0和1之间的值的非零分数; Y在每次出现时都是独立的电荷平衡抗衡离子; R 1和R 2在每次出现时独立地为卤素，C 1 -C 20 - 脂族基团， C 3 -C 20脂环族基团，C 2 -C 20芳族基团或R SUP > 1和R 2可以一起形成二价脂族基团，二价环脂族基团或二价芳族基团; R 3在每次出现时独立地为具有结构II的有机基团，其中Ar 1为C 2 -C 50 芳香族; L 1是C 1 -C 20脂族基团，C 3 -C 20脂族基团，C 1 -C 20脂族基团， / SUB>环脂族基团或C 2 -C 20芳族基团; F在每次出现时独立地是衍生自选自多环烯烃单体和杂环烯烃单体的烯烃单体的结构单元; “n”在每次出现时独立地为1至约200的整数; Q在每次出现时独立地为氢，卤素，C 1 -C 20脂肪族基，C 3 -C 3 - 20个环脂族基团或C 2 -C 20芳族基团; 和“m”在每次出现时独立地为1至约10的整数。

公开(公告)号：WO2005005515A1

公开(公告)日：2005-01-20

申请号：PCT/US2004/018519

申请日：2004-06-10

Applicant: GENERAL ELECTRIC COMPANY ,  HERRMANN, Eugene, David ,  CELLA, James, Anthony ,  REITZ, John, Bradford ,  KERBOUA, Racid ,  DRIS, Irene

Inventor： HERRMANN, Eugene, David ,  CELLA, James, Anthony ,  REITZ, John, Bradford ,  KERBOUA, Racid ,  DRIS, Irene

IPC: C08G73/10

CPC classification number: G11B5/73 ,  C08G73/1053 ,  Y10S360/902 ,  Y10T428/21 ,  Y10T428/31504 ,  Y10T428/31681 ,  Y10T428/31721

Abstract: In one aspect the present invention provides a storage medium for data, the storage medium comprising: a) a substrate, a physical portion of which comprises at least one polyimide, and b) at least one data layer on the substrate. The substrate comprising a polyimide exhibits low axial displacement and beneficial damping characteristics.

Abstract translation: 一方面，本发明提供了一种用于数据的存储介质，所述存储介质包括：a）衬底，其物理部分包括至少一个聚酰亚胺，以及b）所述衬底上的至少一个数据层。 包含聚酰亚胺的基材表现出低轴向位移和有利的阻尼特性。

公开(公告)号：WO2010065178A1

公开(公告)日：2010-06-10

申请号：PCT/US2009/057948

申请日：2009-09-23

Applicant: GENERAL ELECTRIC COMPANY ,  CHICHAK, Kelly, Scott ,  LEWIS, Larry, Neil ,  CELLA, James, Anthony ,  SHIANG, Joseph, John

Inventor： CHICHAK, Kelly, Scott ,  LEWIS, Larry, Neil ,  CELLA, James, Anthony ,  SHIANG, Joseph, John

IPC: C09K11/06 ,  H05B33/14 ,  C08G61/12 ,  H01L51/00

CPC classification number: C09K11/06 ,  C08G61/02 ,  C08G61/122 ,  C08G2261/122 ,  C08G2261/148 ,  C08G2261/1526 ,  C08G2261/3142 ,  C08G2261/3245 ,  C08G2261/5242 ,  C08G2261/78 ,  C09K2211/1416 ,  C09K2211/1425 ,  C09K2211/1433 ,  C09K2211/1466 ,  C09K2211/1475 ,  H01L51/0039 ,  H05B33/14

Abstract: The present invention relates to process comprising reacting a polyfluorenes comprising at least one structural group of formula I with an iridium (III) compound of formula II wherein, R1 and R2 are independently alkyl, substituted alkyl, aryl, substituted aryl or a combination thereof; R5 is H or CHO; R3 and R4 are independently hydrogen, alkyl, substituted alkyl, aryl, substituted aryl or a combination thereof; R11 and R12 taken together form a substituted or unsubstituted monocyclic or bicyclic heteroaromatic ring; R13 is independently at each occurrence halo, nitro, hydroxy, amino, alkyl, aryl, arylalkyl, alkoxy, substituted alkoxy, substituted alkyl, substituted aryl, or substituted arylalkyl; Ar is aryl, heteroaryl, substituted aryl, substituted heteroaryl, or a combination thereof; X is selected from a direct bond, alky, substituted alkyl, and combinations thereof; Y is CHO or NH2; Z is CHO or NH2 where Z does not equal Y; and p is O, 1 or 2. The invention also relates to the polyfluorenes, which are products of the reaction, and the use of the polyfluorenes in optoelectronic devices.

Abstract translation: 本发明涉及使包含至少一种式I结构基团的聚芴与式II的铱（III）化合物反应的方法，其中R 1和R 2独立地为烷基，取代的烷基，芳基，取代的芳基或其组合; R5是H或CHO; R3和R4独立地是氢，烷基，取代的烷基，芳基，取代的芳基或它们的组合; R11和R12一起形成取代或未取代的单环或双环杂芳环; R13各自独立地为卤素，硝基，羟基，氨基，烷基，芳基，芳基烷基，烷氧基，取代的烷氧基，取代的烷基，取代的芳基或取代的芳基烷基; Ar是芳基，杂芳基，取代的芳基，取代的杂芳基或其组合; X选自直接键，烷基，取代的烷基及其组合; Y为CHO或NH2; Z是CHO或NH2，其中Z不等于Y; 并且p是O，1或2.本发明还涉及作为反应产物的聚芴，以及聚芴在光电器件中的应用。

公开(公告)号：WO2009079039A1

公开(公告)日：2009-06-25

申请号：PCT/US2008/073627

申请日：2008-08-20

Applicant: GENERAL ELECTRIC COMPANY ,  CHICHAK, Kelly, Scott ,  CELLA, James, Anthony ,  SHIANG, Joseph, John ,  LEWIS, Larry, Neil

Inventor： CHICHAK, Kelly, Scott ,  CELLA, James, Anthony ,  SHIANG, Joseph, John ,  LEWIS, Larry, Neil

IPC: C09K11/06 ,  H05B33/14 ,  C07F15/00 ,  H01L51/00

CPC classification number: C09K11/06 ,  C07F15/004 ,  C09K2211/1416 ,  C09K2211/1425 ,  C09K2211/1433 ,  C09K2211/1466 ,  C09K2211/185 ,  H01L51/0035 ,  H01L51/0039 ,  H01L51/5012 ,  H05B33/14

Abstract: Polymers including at least one structural unit derived from a compound of Formula (I) or including at least one pendant group of Formula (II) may be used in optoelectronic devices, wherein R 1 , R 3 , R 4 and R 6 are independently hydrogen, alkyl, alkoxy, oxaalkyl, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted oxaalkyl, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; R 1a is hydrogen or alkyl; R 2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO 2 ; R 2a is alkylene; R 5 is independently at each occurrence hydrogen, alkyl, alkylaryl, aryl, arylalkyl, alkoxy, carboxy, substituted alkyl; substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted alkoxy, X is halo, triflate, -B(OR 1a ) 2 , or Formula (III) located at the 2, 5- or 2, 7- positions; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2-phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3-methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.

Abstract translation: 包括衍生自式（I）化合物或至少包含式（II）的至少一个侧基的至少一个结构单元的聚合物可以用于光电子器件中，其中R 1，R 3，R 4和R 6独立地为氢，烷基，烷氧基 烷基芳基，芳基，芳基烷基，杂芳基，取代的烷基; 取代的烷氧基，取代的氧杂烷基，取代的烷基芳基，取代的芳基，取代的芳基烷基或取代的杂芳基; R1a是氢或烷基; R2是亚烷基，取代的亚烷基，氧杂亚烷基，CO或CO 2; R2a是亚烷基; R5各自独立地为氢，烷基，烷基芳基，芳基，芳基烷基，烷氧基，羧基，取代的烷基; 取代的烷基芳基，取代的芳基，取代的芳烷基或取代的烷氧基，X是卤素，三氟甲磺酸酯，-B（OR1a）2或位于2,5-或2,7-位的式（III） 苯基吡啶，苯并噻吩并吡啶，二苯并喹嗪，芴基吡啶，酮咯吡咯，2-（1-萘基）苯并恶唑）），2-苯基苯并恶唑，2-苯基苯并噻唑，香豆素，噻吩基吡啶，苯基吡啶，苯并噻吩基吡啶，3-甲氧基 - 2-苯基吡啶，噻吩基吡啶，苯亚胺，乙烯基吡啶，吡啶基萘，吡啶基吡咯，吡啶基咪唑，苯基吲哚，其衍生物或其组合。

公开(公告)号：WO2007111763A3

公开(公告)日：2007-10-04

申请号：PCT/US2007/000629

申请日：2007-01-10

Applicant: GENERAL ELECTRIC COMPANY ,  LIU, Jie ,  CELLA, James, Anthony ,  LEWIS, Larry, Neil ,  DUGGAL, Anil, Raj ,  SPIVACK, James, Lawrence ,  YE, Qing

Inventor： LIU, Jie ,  CELLA, James, Anthony ,  LEWIS, Larry, Neil ,  DUGGAL, Anil, Raj ,  SPIVACK, James, Lawrence ,  YE, Qing

IPC: H01L51/54 ,  H01L51/46

Abstract: Described herein is an organic opto-electronic device comprising a cathode comprising at least one zero-valent metal; an anode; an opto-electronically active organic material; wherein said cathode is in contact with at least one organic ammonium salt. In certain embodiments, the organic ammonium salt has structure (I), wherein R 1 -R 4 are independently at each occurrence a C 1 -C 20 aliphatic radical, a C 3 -C 20 cycloaliphatic radical, or a C 3 -C 2O aromatic radical and wherein X - is selected from the group consisting of monovalent inorganic anions, monovalent organic anions, polyvalent inorganic anions, polyvalent organic anions, and mixtures thereof.

公开(公告)号：WO2007111763A2

公开(公告)日：2007-10-04

申请号：PCT/US2007000629

申请日：2007-01-10

Applicant: GEN ELECTRIC ,  LIU JIE ,  CELLA JAMES ANTHONY ,  LEWIS LARRY NEIL ,  DUGGAL ANIL RAJ ,  SPIVACK JAMES LAWRENCE ,  YE QING

Inventor： LIU JIE ,  CELLA JAMES ANTHONY ,  LEWIS LARRY NEIL ,  DUGGAL ANIL RAJ ,  SPIVACK JAMES LAWRENCE ,  YE QING

IPC: H01L51/54

CPC classification number: H01L51/5012 ,  C09K11/06 ,  H01L51/4206 ,  H01L51/5032 ,  H01L51/5092 ,  H01L2251/564 ,  H05B33/14 ,  H05B33/20 ,  Y02E10/549

Abstract: Described herein is an organic opto-electronic device comprising a cathode comprising at least one zero-valent metal; an anode; an opto-electronically active organic material; wherein said cathode is in contact with at least one organic ammonium salt. In certain embodiments, the organic ammonium salt has structure (I), wherein R 1 -R 4 are independently at each occurrence a C 1 -C 20 aliphatic radical, a C 3- C 20 cycloaliphatic radical, or a C 3 -C 2O aromatic radical is disclosed and wherein X - is selected from the group consisting of monovalent inorganic anions, monovalent organic anions, polyvalent inorganic anions, polyvalent organic anions, and mixtures thereof.

Abstract translation: 本文描述的是一种有机光电子器件，其包括：包含至少一种零价金属的阴极; 阳极; 光电活性有机材料; 其中所述阴极与至少一种有机铵盐接触。 在某些实施方案中，有机铵盐具有结构（I），其中R 1 -R 4 - 在每次出现时独立地为C 1〜 C 20脂肪族基团，C 3 -C 20脂环族基团或C 3 -C 3亚烷基 > OO 2芳族基团，其中X为 - 选自一价无机阴离子，一价有机阴离子，多价无机阴离子，多价有机阴离子及其混合物。

公开(公告)号：WO2006026421A3

公开(公告)日：2007-02-01

申请号：PCT/US2005030390

申请日：2005-08-25

Applicant: GEN ELECTRIC ,  CELLA JAMES ANTHONY ,  COLOMBO DANIEL GERARD ,  KAPUSTA CHRISTOPHER JAMES

Inventor： CELLA JAMES ANTHONY ,  COLOMBO DANIEL GERARD ,  KAPUSTA CHRISTOPHER JAMES

IPC: C08J3/24 ,  C08J5/18 ,  C08L69/00 ,  G02F1/361

CPC classification number: C08J5/18 ,  C08G64/045 ,  C08J2369/00 ,  C08K5/0025 ,  G02F1/3615

Abstract: Crosslinkable polymeric materials are disclosed useful for the temporal stabilization of a poling- induced noncentrosymmetric host lattice containing guest nonlinear optical chromophores . The materials are also suitable as, crosslinkable coatings in the absence of chromophores. Also disclosed is a method of srosslinking such polymeric material comprising reacting i)a crosslinkable polymeric material comprising olefin groups and ii) a crosslinking agent comprising electron deficient olefin groups, at a temperature at which crosslinking occurs.

Abstract translation: 公开了可交联聚合材料，其用于包含客体非线性光学发色团的极化诱导的非中心对称主体晶格的时间稳定性。 在不存在发色团的情况下，这些材料也适合作为可交联涂层。 还公开了一种交联这种聚合材料的方法，包括使i）包含烯烃基团的可交联聚合物材料和ii）在发生交联的温度下包含电子缺陷烯烃基团的交联剂。

公开(公告)号：WO2006020752A1

公开(公告)日：2006-02-23

申请号：PCT/US2005/028511

申请日：2005-08-10

Applicant: GENERAL ELECTRIC COMPANY ,  CELLA, James, Anthony ,  RUBINSZTAJN, Slawomir

Inventor： CELLA, James, Anthony ,  RUBINSZTAJN, Slawomir

IPC: C07F7/18

CPC classification number: C07G1/00 ,  B01J31/14 ,  C07F7/0874 ,  C07F7/126 ,  C08G77/06 ,  C08G77/08 ,  C08G77/48

Abstract: A new silicone condensation reaction, the condensation between an alkoxy silane or siloxane or a dihydric phenol and an organo-hydrosilane or siloxane and catalysts therefore is described and claimed.

Abstract translation: 因此，新的有机硅缩合反应，烷氧基硅烷或硅氧烷或二元酚与有机氢硅烷或硅氧烷和催化剂之间的缩合被描述和要求保护。

公开(公告)号：WO2007067407A2

公开(公告)日：2007-06-14

申请号：PCT/US2006/045852

申请日：2006-12-01

Applicant: GENERAL ELECTRIC COMPANY ,  LIU, Jie ,  CELLA, James, Anthony ,  YAN, Min ,  DUGGAL, Anil, Raj ,  HERZOG, Michael, Scott ,  ROGOJEVIC, Svetlana ,  PARTHASARATHY, Gautam

Inventor： LIU, Jie ,  CELLA, James, Anthony ,  YAN, Min ,  DUGGAL, Anil, Raj ,  HERZOG, Michael, Scott ,  ROGOJEVIC, Svetlana ,  PARTHASARATHY, Gautam

IPC: H01L51/52

CPC classification number: H01L51/5048 ,  H01B1/06 ,  H01L51/0059 ,  H01L51/5221 ,  H01L2251/5323 ,  H05B33/28 ,  Y10T428/31938

Abstract: Described herein is a transparent electrode comprising at least one optically transparent electrically conductive layer; and at least one optically transparent intermediate layer, wherein said optically transparent conductive layer is in contact with said optically intermediate layer, and wherein said optically transparent conductive layer and said optically transparent intermediate layer together transmit at least 50 percent of incident light having a wavelength in a range between about 200 and about 1200 nanometers, said optically transparent conductive layer having a bulk conductivity at least 100 Siemens per centimeter (S/cm), said optically transparent intermediate layer being comprised of a material having a bulk electrical conductivity at room temperature less than 10 -12 Siemens per centimeter and a band gap of 3.5 eV. Described herein are also methods for forming a transparent electrode, and transparent electronic devices comprising at least one transparent electrode.

Abstract translation: 这里描述的是包括至少一个光学透明导电层的透明电极; 和至少一个光学透明中间层，其中所述光学透明导电层与所述光学中间层接触，并且其中所述光学透明导电层和所述光学透明中间层一起透射至少50％的入射光， 在约200和约1200纳米之间的范围内，所述光学透明导电层具有至少100西门子每厘米（S / cm）的体积电导率，所述光学透明中间层由在室温下具有体电导率的材料组成 比每厘米10 -12西门子和3.5eV的带隙。 这里描述的还有用于形成透明电极的方法，以及包括至少一个透明电极的透明电子器件。