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公开(公告)号：KR101847391B1
公开(公告)日：2018-05-24
申请号：KR1020160052418
申请日：2016-04-28
Applicant: 국방과학연구소
Abstract: 본발명은고폭화약입자의건조장치및 그의건조방법에관한것이다. 본발명의고폭화약입자의건조장치는, 수분이함유된고폭화약입자의수분을제거하는수분제거부; 및상기수분제거부에서수분이제거된상기고폭화약입자를이산화탄소를이용하여건조시키는건조부;를포함하고, 상기수분제거부는, 내부에상기고폭화약입자가수용되는수용공간과유입부및 유출부를구비하는퍼넬; 및미리설정된크기의관통부를구비하여상기퍼넬의내부에구비되고, 상기고폭화약입자를세척하여수분을제거하는알코올및 상기고폭화약입자를세척하여상기알코올을제거하는헥산은통과시키고상기고폭화약입자를지지하는필터;를구비하고, 상기건조부는, 상기수분제거부에서수집된상기고폭화약입자가수용되는고압건조용기; 및상기고압건조용기의내부에이산화탄소를공급하여상기고압건조용기의내부의고폭화약입자의헥산을제거하는이산화탄소공급부;를구비하여구성된다. 이에의해, 고폭화약입자의건조시 응집발생을억제할수 있어고폭화약입자를뭉치지아니하게건조할수 있다.
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公开(公告)号：KR101714736B1
公开(公告)日：2017-03-09
申请号：KR1020150056602
申请日：2015-04-22
Applicant: 국방과학연구소
Abstract: 본발명은서브마이크론과마이크론크기의구형 RDX(Cyclotrimethylene trinitramine) 입자제조방법에관한것으로서, 더욱상세하게는, 유기용매(solvent)에 RDX를용해시켜 RDX 용액을제조하는단계; 상기 RDX 용액과반용매를혼합하여 RDX 입자를석출하는단계; 및석출된 RDX 입자를수득하는단계;를포함하며, 상기 RDX 용액과반용매를혼합하기전에상기 RDX 용액또는상기반용매에계면활성제를추가하여혼합하는것을특징으로한다. 본발명에의하면, 기존방법에비해높은생산성으로서브마이크론및 마이크론크기의구형 RDX 입자를제조할수 있으며, 이러한구형형상의 RDX 입자는충진밀도상승에따른기폭압력극대화, 매끈한표면으로인하여비교적둔감한 RDX 입자의제조가가능하며, 또한미세입자크기로인해빠른에너지방출속도를보이므로고폭화약및 고체복합추진제(solid composite propellant) 등민수용및 군용조성물로서널리이용될수 있다.
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公开(公告)号：KR101336754B1
公开(公告)日：2013-12-05
申请号：KR1020120126502
申请日：2012-11-09
Applicant: 국방과학연구소
Abstract: The present invention provides a test warhead for detecting a real time impact pressure comprises: a plurality of pressure detection modules (20, 30, 40) provided with pressure detection sensors (3-1, 3-2, 3-3) and manufactured by using a complex gunpowder composition made of granular raw gunpowder, a polymer bonding agent, a plasticizer, and a catalyst, and a complex gunpowder composition simulant using an inactive granular material for ensuring the safety in an impact test or a production; a pressure measurement device (60) for processing pressure information detected in the sensors; and a warhead shell (50) where the pressure detection modules, forming solid solutions with the simulant, are positioned at the pressure detection positions respectively. The present invention can measure precisely the impact pressure transmitted to a main firing charge simulant when the test warhead penetrates through a robust structure, specifically can develop the main firing charge, namely high explosive gunpowder, with the impact resistance and the performance optimized according to operation conditions of penetrated explosives. [Reference numerals] (AA) Start;(S10) Manufacture a main gunpowder (High explosive gunpowder);(S11) Prepare an inactive granular material (Raw gunpowder);(S12) Prepare a polymer bonding agent and a plasticizer;(S13) Stir;(S14) Complete a slurry simulant;(S20) Manufacture a warhead module;(S21) Combine a frame for each shape with a sensor and a wire;(S22) Complete a first to a third warhead frame;(S30) Inject the slurry simulant into the warhead frame and cure the slurry simulant;(S40) Manufacture a pressure detection module and process a shape;(S50) Complete a first to a third detection module
Abstract translation: 本发明提供了一种用于检测实时冲击压力的测试弹头，包括：多个压力检测模块（20,30,40），其设有压力检测传感器（3-1,3-2,3-3），并由 使用由粒状原料火药制成的复杂火药组合物，聚合物粘合剂，增塑剂和催化剂，以及使用无活性颗粒材料的复合火药组合物模拟物，以确保冲击试验或生产中的安全性; 压力测量装置（60），用于处理在传感器中检测的压力信息; 和弹头壳（50），其中形成有模拟物的固溶体的压力检测模块分别位于压力检测位置。 本发明可以精确地测量当测试弹头穿透坚固的结构时传递到主要燃料电荷模拟物的冲击压力，具体可以发展主要的燃烧电荷，即高爆炸性火药，具有耐冲击性和根据操作优化的性能 渗透炸药的条件。 （附图标记）（AA）开始;（S10）制造火药（高爆药）;（S11）准备无活性粒状物质（原料火药）;（S12）准备聚合物粘合剂和增塑剂;（S13） （S14）完成浆料模拟;（S20）制造弹头模块;（S21）将每个形状的框架与传感器和电线组合;（S22）完成第一至第三弹头框架;（S30）注入 将浆料模拟成弹头框架并固化浆料模拟物;（S40）制造压力检测模块并处理形状;（S50）完成第一至第三检测模块
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Patent Agency Ranking
公开(公告)号：KR100514345B1
公开(公告)日：2005-09-13
申请号：KR1020030027807
申请日：2003-04-30
Applicant: 국방과학연구소
IPC: C07D303/12
CPC classification number: C08G65/22 , C07D303/24 , C08G65/2609
Abstract: 본 발명은 고폭 화약의 성능 증대 및 물성 개선을 위하여 사용되는 에너지화 결합제로서 사용될 수 있는 신규한 물질 및 그 제조방법에 관한 것이다. 보다 상세하게, 본 발명은 에너지기로서 니트로기(-NO
2 )를 가지며 니트로기가 결합된 탄소에 결합하는 수소를 갖지 않는 화학식 IV로 표현되는 신규한 화합물 글리시딜 디니트로프로필 포름알(glycidyl dinitropropyl formal), 이를 단량체로 사용하여 중합된 화학식 V로 표현되는 신규한 화합물 폴리(글리시딜 디니트로프로필 포름알) 및 그 제조방법에 관한 것이다.
[화학식 IV]
[화학식 V]-
公开(公告)号：KR100514344B1
公开(公告)日：2005-09-13
申请号：KR1020030027805
申请日：2003-04-30
Applicant: 국방과학연구소
IPC: C07D303/12
CPC classification number: C07D303/08 , C08G65/22 , C08G65/2609
Abstract: 본 발명은 고성능 둔감 화약용 고에너지 결합제로 사용되는 에너지화 예비 중합체(prepolymer)의 합성에 관한 것으로, 더욱 상세하게는, 화학식 III으로 표현되는 신규한 화합물 2-니트레이토에틸 옥시란(2-nitratoethyl oxirane), 이를 단량체로 사용하여 중합되어 얻어지는 화학식 IV로 표현되는 신규한 화합물 폴리(2-니트레이토에틸 옥시란)[poly(2-nitratoethyl oxirane)] 및 그 제조방법에 관한 것이다. 본 발명의 화합물을 에너지화 예비중합체 및 이를 위한 단량체로서 사용함으로써, 지금까지의 에너지화 예비중합체 중에서 가장 성능이 뛰어나고 유망한 것으로 알려져 있으나 폴리우레탄 탄성체를 합성한 후 자기 분해되는 특성을 갖는 기존의 폴리(글리시딜 니트레이트)의 문제점을 해결할 수 있다.
[화학식 III]
[화학식 IV]-
公开(公告)号：KR1020030087341A
公开(公告)日：2003-11-14
申请号：KR1020020025361
申请日：2002-05-08
Applicant: 국방과학연구소
IPC: C07D303/16
CPC classification number: C08G65/22 , C07D303/16
Abstract: PURPOSE: Glycidyl dinitropropyl carbonate and poly(glycidyl dinitropropyl carbonate) are provided. Prepolymer having improved thermal stability is cheaply prepared by substituting a nitrate group by a nitro group as an energy group. CONSTITUTION: Glycidyl dinitropropyl carbonate represented by the formula(I) is provided. Poly(glycidyl dinitropropyl carbonate) represented by the formula(II) and having molecular weight of 2,000 to 3,500 is provided. A process for preparing the glycidyl dinitropropyl carbonate of the formula(I) comprises the steps of: dissolving 2,2-dinitropropanol in methylenechloride; adding pyridine into the mixture; adding allylchloroformate in methylene chloride to the mixture and reacting them; adding methylenechloride and distilled water into the mixture; dehydrating the methylenechloride extract with anhydrous magnesium sulfate; filtering the dehydrated solution to prepare allyl dinitropropyl carbonate; dissolving allyl dinitropropyl carbonate in methanol; adding hydrogen peroxide and NaOH into the mixture and reacting them; adding methylenechloride and distilled water into the mixture; dehydrating the methylenechloride extract with anhydrous magnesium sulfate; and filtering the dehydrated solution. A process for preparing the poly(glycidyl dinitropropyl carbonate) of the formula(II) comprises the steps of: mixing boron trifluoride etherate with 1,4-butanediol and removing ether under reduced pressure; dissolving the glycidyl dinitropropyl carbonate of the formula(I) in the boron trifluoride etherate solution; adding methylenechloride and distilled water into the mixture; dehydrating the mixture with anhydrous magnesium sulfate; adding ethanol into the dehydrated solution; and removing volatile compounds under reduced pressure.
Abstract translation: 目的：提供碳酸缩水甘油基二硝基丙酯和聚（缩水甘油基二硝基丙基碳酸酯）。 具有改善的热稳定性的预聚物通过用硝基代替硝基作为能量来廉价地制备。 构成：提供由式（I）表示的缩水甘油基二硝基丙基碳酸酯。 提供由式（II）表示的分子量为2,000至3,500的聚（缩水甘油基二硝基丙基碳酸酯）。 制备式（I）的缩水甘油基二硝基丙基碳酸酯的方法包括以下步骤：将2,2-二硝基丙醇溶解在二氯甲烷中; 向混合物中加入吡啶; 将二氯甲烷中的氯甲酸烯丙酯加入到混合物中并使它们反应; 向混合物中加入二氯甲烷和蒸馏水; 用无水硫酸镁脱水二氯甲烷萃取液; 过滤脱水溶液制备碳酸烯丙酯二硝基丙酯; 将烯丙基二硝基丙酸酯溶于甲醇中; 向混合物中加入过氧化氢和NaOH，使它们反应; 向混合物中加入二氯甲烷和蒸馏水; 用无水硫酸镁脱水二氯甲烷萃取液; 并对脱水溶液进行过滤。 制备式（II）的聚（缩水甘油基二硝基丙基碳酸酯）的方法包括以下步骤：将三氟化硼醚合物与1,4-丁二醇混合并在减压下除去乙醚; 将式（I）的缩水甘油基二硝基丙酸酯溶解在三氟化硼乙醚溶液中; 向混合物中加入二氯甲烷和蒸馏水; 用无水硫酸镁脱水混合物; 将乙醇加入脱水溶液中; 并在减压下除去挥发性化合物。
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27.发明公开비스(2,2-디니트로프로필)포름알, 2,2-디니트로프로필 2,2-디니트로부틸 포름알 및 비스(2,2-디니트로부틸)포름알이 혼합된 공융 혼합물을 함유하는 고에너지 가소제 및 그 제조 방법 有权用于爆炸制剂的能量硝酸盐型塑化剂及其制备方法
公开(公告)号：KR1020010095503A
公开(公告)日：2001-11-07
申请号：KR1020000018625
申请日：2000-04-10
Applicant: 국방과학연구소
IPC: C06B25/00
CPC classification number: C06B45/105
Abstract: PURPOSE: An energetic nitro-formal plasticizer for explosive formulations comprises eutectic mixture mixed with bis(2,2-dinitropropyl)formal(BDNPF), 2,2-dinitropropyl 2,2-dibutyl formal(DNPBF) and bis(2,2-dinitrobutyl)formal(BDNPF). The energetic nitro-formal plasticizer exhibits superior thermal/chemical properties with less production cost. CONSTITUTION: The molecular ratio of BDNPF/DNPBF/BDNPF in formulation of this plasticizer is in the range 20-68%/28-50%/4-30%. The plasticizer is allowed to contain diformal, however its content is desirable controlled to be not more than 3%. The preparation method of this plasticizer comprises the steps of (i) dissolving 2,2-dinitropropanol and 2,2-dinitrobutanol in the mole ratio of 3 to 6:1 at 0 to 30deg.C in an organic solvent like methylene chloride; (ii) at 20deg.C or lower, adding sulfuric acid solution in which formaldehyde sources such as paraformaldehyde and s-trioxane is dissolved; (iii) refining obtained mixture.
Abstract translation: 目的：用于爆炸性制剂的高能硝基形式增塑剂包括与双（2,2-二硝基丙基）甲醛（BDNPF），2,2-二硝基丙基2,2-二丁基甲醛（DNPBF）和双（2,2-二硝基丙基） dinitrobutyl）正式（BDNPF）。 精力充沛的硝基形式增塑剂具有优异的热/化学性能，生产成本较低。 构成：该增塑剂配方中BDNPF / DNPBF / BDNPF的分子比在20-68％/ 28-50％/ 4-30％的范围内。 允许增塑剂含有不均匀性，但其含量优选控制在不超过3％。 该增塑剂的制备方法包括以下步骤：（i）在有机溶剂如二氯甲烷中，在0至30℃下，以3-6:1的摩尔比溶解2,2-二硝基丙醇和2,2-二硝基丁醇; （ii）在20℃以下，加入溶解有多聚甲醛和s-三恶烷等甲醛源的硫酸溶液; （iii）精制所得混合物。
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