Abstract:
본 발명은 하나 이상의 2-이미다졸륨 단위체 및 양이온성 또는 비-양이온성 링커를 갖는 비대칭 양이온성 디아조 화합물에 관한 것이다. 본 발명은 또한, 케라틴 섬유의 염색에 적합한 매질 내에 직접 염료로서 상기 화합물을 포함하는 염색 조성물에 관한 것이고, 또한 이 조성물을 이용하는 케라틴 섬유의 착색 방법, 및 복수의 구획을 갖는 장치에 관한 것이다.
Abstract:
Diazoic cationic compounds of specified formula and their acid addition salts. The compounds are of Formula Col1-LK-Col2 (I); W1, W'6-NR1R2, -OR3; Col1 : compound of formula (i); Col2 : compound of formula (ii) or (iii); R1, R2, R3H, 1-20C (preferably 1-16C) hydrocarbon chain optionally forming one or more optionally substituted 3-7 link carbon cycles optionally interrupted by one or more heteroatoms or by one or more groups bearing a heteroatom preferably O or N, optionally when part of W'6 independently together with part of LK and the N or O to which they are attached an optionally substituted 5-7 link heterocycle; R1 + R2optionally with the N to which they are attached a 5-7 link cycle optionally substituted and optionally comprising N or another heteroatom; W6-NR'1, -O-; R'11-20C (preferably 1-16C) hydrocarbon chain optionally forming one or more optionally substituted 3-7 link carbon cycles optionally interrupted by one or more heteroatoms or by one or more groups bearing a heteroatom preferably O or N, optionally together with the N to which it is attached and part of LK a 5-7 link cycle optionally substituted and optionally comprising N or another heteroatom; W2, W5, W'5formulae (a), (b), (c); X1N, CR7; X2N, CR8; Z1N, CR10; Z2N, CR11; R4, R5, R6, R'6, R7, R8, R10, R111-16C hydrocarbon chain optionally forming one or more optionally substituted 3- 7 link carbon cycles optionally interrupted by one or more heteroatoms or by one or more groups bearing a heteroatom preferably O or N, OH, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy, alkoxy(1-4C)carbonyl, alkyl(1-4C)carbonyloxy, amino optionally substituted with one or more 1-4C alkyl optionally bearing at least one hydroxyl the two alkyl radicals optionally forming together with the N to which they are attached a 5-6 link heterocycle optionally bearing N or another heteroatom, alkylcarbonylamino (RCO-NR), carbamoyl ((R)2N-CO), ureido (N(R))2-CO-NR'-), alkylsulfonylamino (RSO2-NR'), guanidium ((R')2N-C(=NH2+>)- NR-), nitro, cyano, halogen (preferably Cl or F), optionally all or part of W1, W6 or W'6 a 5-7 link optionally substituted heterocycle, the bond W2 to W1 or W5 to W or W'5 to W'6 or the group LK; R, R' : H, 1-4C alkyl; a : the bond of W2, W5 and W'5 to the azoic group - N=N-; b : the bond W5 to W'6 or the group LK; R9H, 1-16C hydrocarbon chain optionally forming one or more optionally substituted 3-7 link cycles; n, n' : sum of integers, 6 or less; W3, W4formulae (1) to (11); R'41-16C hydrocarbon chain optionally forming one or more optionally substituted 3-7 link carbon cycles optionally interrupted by one or more heteroatoms or by one or more groups bearing a heteroatom preferably O or N, OH, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy, alkoxy(1-4C)carbonyl, alkyl(1-4C)carbonyloxy, amino optionally substituted with one or more 1-4C alkyl optionally bearing at least one hydroxyl the two alkyl radicals optionally forming together with the N to which they are attached a 5-6 link heterocycle optionally bearing N or another heteroatom, alkylcarbonylamino (RCO-NR), carbamoyl ((R)2N-CO), ureido (N(R))2-CO-NR'-), alkylsulfonylamino (RSO2-NR'), guanidium ((R')2N-C(=NH2+>)- NR-), nitro, cyano, halogen (preferably Cl or F), together when borne by adjacent carbon atoms a 5-6 link secondary cycle optionally substituted with at least one H or hydroxyl or 1- 4C alkyl or alkoxy or 2-4C (poly)hydroxyalkoxy or amino or amino substituted with one or more identical or different radicals and preferably a substituted 6 link cycle; R'5when borne by W4 1-16C hydrocarbon chain optionally forming one or more optionally substituted 3-7 link carbon cycles optionally interrupted by one or more heteroatoms or by one or more groups bearing a heteroatom preferably O or N and is linked to the quaternized N by a carbon atom, when borne by W3 a link to LK; R'71-4C alkyl, optionally substituted phenyl, optionally substituted benzyl; c : a linkage to the azoic group on either the principal (preferred) or secondary cycle; p : 0-4; p' : 0-2; p" : 0-3; LK : 2- 40C (preferably 2-20C) hyd
Abstract:
본 발명은 직접 염색약으로서 사용될 수 있는 신규한 2가 양이온성 비스-하이드라존 화합물 패밀리, 및 적합한 염색 매질 중에 하나 이상의 상기 화합물을 포함하는, 케라틴 섬유, 특히 인간 케라틴 섬유 예컨대 모발 염색용 염색조성물에 관한 것이다. 본 발명은 또한 상기 조성물을 사용하는 염색 방법 및 조성물의 용도에 관한 것이다. 2가 양이온성 비스-하이드라존 화합물, 염색, 모발, 직접 염색.