Abstract:
The present invention concerns a new dissymmetrical cationic polyazo compounds of formula (I) Dyel-L-Dye2. The present invention also relates to dye compositions comprising such compounds as direct dye in a medium that is suitable for dyeing keratin fibres, and also to a process for dyeing keratin fibres using this composition and a multi-compartment device. The present invention provides direct dyes with which strong and varied shades that are resistant to external attacking factors such as bad weather and shampooing, for which there is no observation of any problem of change in colour over time.
Abstract:
본 발명은 2-피리디늄기 및 양이온성 또는 비이온성 링커를 갖는 비대칭 양이온성 디아조 화합물에 관한 것이다. 본 발명은 또한, 케라틴 섬유의 염색에 적합한 매질 내에서 직접 염료로서 상기 화합물을 포함하는 염색 조성물, 및 상기 조성물을 이용한 케라틴 섬유의 착색 방법, 및 다수의 구획을 갖는 장치에 관한 것이다.
Abstract:
본 발명은 하나 이상의 2-이미다졸륨 단위체 및 양이온성 또는 비-양이온성 링커를 갖는 비대칭 양이온성 디아조 화합물에 관한 것이다. 본 발명은 또한, 케라틴 섬유의 염색에 적합한 매질 내에 직접 염료로서 상기 화합물을 포함하는 염색 조성물에 관한 것이고, 또한 이 조성물을 이용하는 케라틴 섬유의 착색 방법, 및 복수의 구획을 갖는 장치에 관한 것이다. 비대칭 양이온성 디아조 화합물, 염색 조성물
Abstract:
The present invention relates to symmetrical tetraazo cationic compounds of formula (I), Dyel-L-Dyel in which formula Dyel represents (II); in which: W1, which are identical, represent: (IIa, IIb, IIc); W 2, which are identical, represent (III); W3, which are identical, represent (IV); L represents an optionally substituted C1-C60 hydrocarbon-based chain, optionally bearing at least one cationic charge, optionally interrupted with and/or terminated at one and the other of the ends with at least one hetero atom or group comprising at least one hetero atom; the electrical neutrality of the compounds being ensured by means of one or more cosmetically acceptable, identical or different anions An. A subject of the invention is similarly a composition comprising such a dye asdirect dye, and also a process using the said composition for dyeing keratin fibres.
Abstract:
본 발명은 하기 식의 양이온성 디아조 화합물에 관한 것이다: 염료 1 - LK - 염료 2 [상기 식에서, 염료 1 및 염료 2는 다음과 같다:
{상기 식에서, W 1 , W 6 : -NR 1 R 2 , -OR 3 /W 6 : -NR' 1 - W 2 , W 5 , W' 5 : 하기 화학식 (a) 내지 (c)의 기:
W 3 , W 4 : 양이온성 방향족 헤테로사이클}; LK: 포화 또는 불포화, 선형 또는 분지형, 시클릭 또는 비-시클릭, 방향족 또는 비방향족, 임의로 치환되고 하나 이상의 헤테로 원자 또는 하나 이상의 헤테로 원자를 포함하는 기에 의해 임의로 차단된 C 1 -C 40 탄화수소-기초 사슬]. 또한, 본 발명은 직접 염료로서 상기 화합물을 포함하는 염료 조성물, 이 조성물을 사용하여 케라틴 섬유를 염색하는 방법, 및 다중 구획 장치에 관한 것이다. 직접 염료, 케라틴 섬유, 염색, 다중 구획 장치
Abstract:
New cationic diazo compounds and their acid addition salts are claimed. Cationic diazo compounds and their acid addition salts, are new. Dye 1- L'K' - Dye 2(I) and their acid addition salts, are new. Dye 1W 3-N=N-W 2-W 1-* or W 3-N=N-W 2a(W 1a)-*; Dye 2W 4-N=N-W 5-W 6-* or W 4-N=N-W 5a(W 6a)-*; W 1and W 6-NR 1- or -O-; R 1H and optionally saturated, optionally aromatic, optionally substituted 1-20C hydrocarbon-based chains, which optionally form at least one optionally substituted 3- to 7-membered carbon-based rings, optionally interrupted with at least one hetero atom or with at least one group bearing at least one hetero atom; W 1aand W 6a-NR 1aR 2aor -OR 3a; R 1a, R 2aand R 3aH and optionally saturated, optionally aromatic, optionally substituted 1-20C hydrocarbon-based chains, which can form at least one optionally substituted 3- to 7-membered carbon-based ring, optionally interrupted with at least one hetero atom or with at least one group bearing at least one hetero atom;or NR 1a+R 2aan optionally substituted 5- or 7-membered heterocycle optionally comprising another nitrogen or non-nitrogen hetero atom; W 2, W 5, W 2aand W 5agroups of formulae (i) to (iii); X 1N or CR 7; X 2N or CR 8; Z 1N or CR 10; Z 2N or CR 11; R 4, R 5, R 7, R 8, R 10and R 11G 1, H or a bond from W 2ato W 1aor to the group L'K', or from W 5ato W 6aor to the group L'K'; R 6and R 6aG 1; G 1T 1, hydroxyl, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy, RO-CO-, RCO-O-, amino (optionally substituted by at least one 1-4C alkyl (optionally bearing at least one hydroxyl, and possibly forming with the nitrogen atom to which they are attached, 5- or 6-membered heterocycle optionally bearing another nitrogen or non-nitrogen hetero atom)), RCO-NR-, (R') 2N-CO, N(R') 2-CO-NR' a-, (R') 2N-SO 2-, R'SO 2-NR' a-, (R' a) 2N-C(=NH 2+>(X ->))-NR'-, nitro, cyano or halo; T 1linear or branched, optionally saturated, optionally aromatic, optionally substituted 1-16C hydrocarbon-based chains, which optionally form at least one optionally substituted 3- to 7-membered carbon-based ring, optionally interrupted with at least one hetero atom or with at least one group bearing at least one hetero atom; R : 1-4C alkyl; R' and R' aH or 1-4C alkyl; a' : bond from W 2, W 5, W 2aor W 5ato the azo group -N = N-; b' : bond from W 2to W 1, from W 5to W 6, from W' 2to W' 1or to the group L'K', or from W' 5to W' 6or to the group L'K'; R 9H, linear or branched, optionally saturated, optionally aromatic, optionally substituted 1-16C hydrocarbon-based chains, which can form at least one optionally substituted 3- to 7-membered carbon-based ring; n and n' : integers; n+n' : = 6; W 3and W 4cationic heteroaromatic radicals selected from formulae (ia) to (ih) or (ij) to (il); R 4aG 1;or R 4a+R 4aoptionally aromatic, 5- or 6-membered secondary ring, optionally substituted by at least one of H, hydroxyl, 1-4C alkyl radicals, 1-4C alkoxy, 2-4C(poly)hydroxyalkoxy, amino (optionally substituted by at least one 1-4C alkyl, optionally bearing at least one hydroxyl); R 5aT 1; R 7a1-4C alkyl, phenyl or benzyl (all optionally substituted); p : 0 to 4; r : 0 to 2; t : 0 to 3; L'K' : optionally saturated, optionally substituted 2-40C hydrocarbon-based chains, optionally interrupted with at least one hetero atom or group comprising at least one hetero atom; X ->anions. The group R 1of W 1and W 6, together or separately, optionally form with all or part of the group L'K' and with the nitrogen atom to which each is attached optionally saturated, optionally aromatic, optionally substituted 5- to 7-membered heterocycle. The radicals R 1a, R 2aor R 3aof W 1aand W 6a, together or separately, optionally form, with all or part of the group L'K' and with the nitrogen or oxygen atom to which each is attached, optionally saturated, aromatic or non-aromatic, optionally substituted 5- to 7-membered heterocycle. The groups R 4-R 8, R 6a, R 10and R 11, independently of each other, optionally form, with all or some of the groups W 1aor W 6a, or alternatively, all or some of the groups W 1or W 6, optionally saturated, optionally aromatic, optionally substituted 5- to 7-membered heterocycle. The bond c' links the cationic radical (ia) to (ih) and (ij) to (ik) to the azo group, where the bond is optionally on the main or secondary ring. Provided that: (1) Dye 1and Dye 2are such that the compound of formula (I) is not symmetrical; (2) when the main ring does not bear the maximum number of substituents, then the unsubstituted position(s) bear(s) a nitrogen atom; with the condition that at least one of the two groups W 3and W 4are not selected from unsubstituted imidazolium groups; (3) the group L'K' does not comprise any nitro, nitroso or peroxo groups or bonds; (4) if L'K' is linked to W' 2or W' 5, then L'K' may end with a hetero atom or group bearing at least one hetero atom; and (5) if L'K' is linked to W 6or W 1, then L'K' may end with a group bearing at least one of -CO- or -SO 2-. Independent claims are included for the following: (1) a dye composition comprising, in a medium that is suitable for dyeing keratin fibers, at least one direct dye selected from the compounds (I) and their acid addition salts; and (2) a multi-compartment kit comprising at least one first compartment comprising the dye composition and at least one second compartment comprising at least one oxidizing composition comprising at least one oxidizing agent. [Image] [Image] [Image] [Image] [Image].
Abstract:
본 발명은 하나 이상의 4-피리디늄 단위 및 양이온성 또는 비이온성 링커를 갖는 비대칭 양이온성 디아조 화합물에 관한 것이다. 본 발명은 또한, 케라틴 섬유의 염색에 적합한 매질 내에서 직접 염료로서 상기 화합물을 포함하는 염색 조성물, 및 상기 조성물을 이용한 케라틴 섬유의 착색 방법, 및 다수의 구획을 갖는 장치에 관한 것이다.
Abstract:
본 발명은 비대칭 양이온성 디아조 화합물, 이의 공명형, 이의 산 첨가염 및 이의 용매화물에 관한 것이다:
(식 중, 동일한 W 1 라디칼은 수소 원자, 할로겐 원자, 또는 -NR 5 R 6 , OR 7 , -NR 4 -Ph-NR 5 R 6 , -NR 4 -Ph-OR 7 , -O-Ph-OR 7 또는 O-Ph-NR 5 R 6 기를 나타내고, L 은 양이온성 또는 비양이온성 링커를 나타낸다). 본 발명은 또한, 케라틴 섬유의 염색에 적합한 매질 내에서 직접 염료로서 상기 화합물을 포함하는 염색 조성물, 및 상기 조성물을 이용한 케라틴 섬유의 착색 방법, 및 다수의 구획을 갖는 장치에 관한 것이다.
Abstract:
본 발명은 하나 이상의 4-피리디늄 단위 및 양이온성 또는 비이온성 링커를 갖는 비대칭 양이온성 디아조 화합물에 관한 것이다. 본 발명은 또한, 케라틴 섬유의 염색에 적합한 매질 내에서 직접 염료로서 상기 화합물을 포함하는 염색 조성물, 및 상기 조성물을 이용한 케라틴 섬유의 착색 방법, 및 다수의 구획을 갖는 장치에 관한 것이다.
Abstract:
The present disclosure relates to cationic diazo dye compounds of formula (I): Dye1-LK-Dye2 (I): it also relates to dye compositions comprising the direct dye compounds, and also to a process for dyeing fibers using this composition and a multi-component kit.