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    형광 시아닌 염료를 포함하는 조성물의, 라이트닝 효과와함께 케라틴 성분의 염색을 위한 용도
    2.
    发明公开
    형광 시아닌 염료를 포함하는 조성물의, 라이트닝 효과와함께 케라틴 성분의 염색을 위한 용도 有权
    用于包含荧光氰胺染料的组合物的KERATIN物质的照射效果的染色

    公开(公告)号：KR1020080080626A

    公开(公告)日：2008-09-04

    申请号：KR1020087016848

    申请日：2007-01-11

    Applicant: 로레알

    Inventor： 그리브즈앤드류 ,  도브레스니꼴라

    IPC: A61K8/49 ,  A61Q5/06 ,  A61Q5/10

    CPC classification number: A61K8/4926 ,  A61K8/494 ,  A61K2800/434 ,  A61Q5/065 ,  A61Q5/10

    Abstract: The present invention relates to the use, for the dyeing with lightening effect of human keratin substances, and in particular of human keratin fibres such as the hair, of a composition comprising at least one fluorescent cyanine dye. The present invention allows human keratin substances to be both dyed and at the same time lightened without detriment to said substances. The fluorescent dyes employed in the context of the invention also have high tinctorial affinity for keratin substances and good properties of resistance towards external agents, and especially towards shampoos.

    Abstract translation: 本发明涉及一种包含至少一种荧光花青染料的组合物用于人角蛋白物质，特别是人角蛋白纤维如头发的减轻作用的染色用途。 本发明允许人角蛋白物质染色并同时减轻而不损害所述物质。 在本发明上下文中使用的荧光染料还具有对角蛋白物质的高的着色亲和力和对外部药剂的抗性的良好性质，特别是对于洗发剂。

    2-이미다졸륨기 및 비-양이온성 링커를 함유한 대칭 디아조화합물, 이를 함유하는 조성물, 착색 방법 및 장치
    8.
    发明授权
    2-이미다졸륨기 및 비-양이온성 링커를 함유한 대칭 디아조화합물, 이를 함유하는 조성물, 착색 방법 및 장치 失效
    包含2-咪唑烷基组合物和非阳离子连接剂的对映体二氮化合物，包含它们的组合物，着色方法和装置

    公开(公告)号：KR100851260B1

    公开(公告)日：2008-08-08

    申请号：KR1020050124171

    申请日：2005-12-15

    Applicant: 로레알

    Inventor： 다비드에르베 ,  그레아브앤드류 ,  도브레스니꼴라

    IPC: C07D403/06 ,  C07D403/14

    CPC classification number: C07D471/04 ,  A61K8/4946 ,  A61Q5/10 ,  C07D233/88 ,  C07D403/12 ,  C09B44/16 ,  C09B55/008

    Abstract: Cationic dissymmetrical diazo compounds (I), their resonance forms, acid addition salts an acid and/or their solvates are new. Cationic dissymmetrical diazo compounds of formula (I) (where electroneutrality of (I) is ensured by one or more anions (An)), their resonance forms, acid addition salts an acid and/or their solvates are new. R11-4C alkyl, phenyl or benzyl (all optionally substituted); R3X or 1-16C alkyl (optionally substituted, and optionally interrupted by one or more heteroatoms or groups containing heteroatoms (preferably O, N, S, -CO and/or -SO2)); X : OH, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy, RO-CO-, RCO-O-, R-CO-, amino (optionally substituted by one or two radicals 1-4C alkyl (optionally carrying OH), where the two alkyl radicals with N optionally form T), alkylcarbonylamino (RCO-NR1-), aminocarbonyl ((R1)2N-CO), ureido (N(R1)2-CO-NR1), aminosulfonyl ((R1)2N-SO2), alkylsulfonylamino (RSO2-NR1-), alkylsulfinyl (R-SO-), alkylsulfonyl (R-SO2-), nitro, CN, halo (Cl or F), HS- or RS; R2X, 1-16C alkyl (optionally substituted by HS, 1-4C thioalkyl, 1-4C alkylsulfinyl or 1-4C alkylsulfonyl, and optionally interrupted by one or more heteroatoms or groups containing heteroatoms (preferably O, N, S, -CO and/or -SO2)), substituted aryl or 1-4C arylalkyl (optionally substituted); e, m1 : 0-4; T : 5-7 membered optionally aromatic heterocycle (containing 1-3 (preferably 1-2) heteroatoms N (preferred), O or S); W1H, halo (Br, Cl or F (preferably Cl or F)), NR5R6, OR7, -NR4-Ph-NR5R6, -NR4-Ph-OR7, -O-Ph-OR7 or -O-Ph-NR5R6; R4, R71-20C (preferably 1-16C) alkyl, 1-3C aralkyl, phenyl (all optionally substituted) or H; either R5, R61-20C (preferably 1-16C) alkyl, 1-3C aralkyl, phenyl (all optionally substituted), H or R-CO-; or NR5R6T; or R5 + R6 + C (of aromatic cycle adjacent to that to which -NR5R6 is attached) : 5-6 membered saturated heterocycle; Ph : optionally substituted phenyl; L : covalent bond, 1-40C (preferably 1-20C) alkyl (optionally substituted and optionally interrupted by 3-7 membered optimally aromatic heterocycle (optionally fused and optionally substituted), one or more heteroatoms or groups containing heteroatoms (O, N, S, CO and/or SO2)) or optionally substituted phenyl; R : 1-4C alkyl; and R1H or R. Provided that when e is 2, then two adjacent R2 together forms with carbon atom to which they are attached a 5-6 (preferably 6) membered secondary cycle (optionally substituted by 1-4C alkyl, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy or amino (optionally substituted by 1-4C alkyl (optionally carrying OH)). Provided that when m1 is 2, then two adjacent R3 together forms with carbon atom to which they are attached a 6 membered secondary cycle (optionally substituted by OH, 1-4C alkyl, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy or amino (optionally substituted by 1-4C alkyl (optionally carrying OH)). Provided that when e and m1 are lower than 4, the carbon atoms of unsubstituted heterocycle carry a hydrogen atom. Provided that OR7 and NR5R6 groups form substitutions i.e. when two adjacent R3 form a 6-membered aromatic ring, which is optionally substituted by NR4-Ph, NR4-Ph-OR7 or NR4-Ph-NR5R6. Provided that L is not azo, nitro, nitroso or peroxo. Independent claims are included for: (1) a tinctorial composition (A) comprising (I), in a medium for the dyeing of keratinous fibers, as direct dye; (2) a process of dyeing keratinous fiber comprising contacting (A) with the dry or wet fibers to obtain the desired effect; and (3) a device with several compartments, comprising a first compartment comprising (A) and a second compartment containing an oxidizing composition. [Image]

    하나 이상의 2-이미다졸륨 단위체 및 양이온성 또는비-양이온성 링커를 가지는 비대칭 디아조 화합물, 이를포함하는 조성물, 착색 방법, 및 장치
    9.
    发明公开
    하나 이상의 2-이미다졸륨 단위체 및 양이온성 또는비-양이온성 링커를 가지는 비대칭 디아조 화합물, 이를포함하는 조성물, 착색 방법, 및 장치 失效
    具有至少一个2-咪唑烷单元和阳离子或非阳离子连接体的组合物，包含它们的组合物，着色方法和装置

    公开(公告)号：KR1020070119598A

    公开(公告)日：2007-12-20

    申请号：KR1020070123806

    申请日：2007-11-30

    Applicant: 로레알

    Inventor： 다비드에르베 ,  그레아브앤드류 ,  도브레스니꼴라

    IPC: C07D403/12 ,  C07D403/14

    CPC classification number: C07D213/77 ,  A61K8/4946 ,  A61Q5/065 ,  C07D233/88 ,  C07D401/06 ,  C07D401/14 ,  C09B43/40 ,  C09B44/10 ,  C09B50/10

    Abstract: A dissymmetrical cationic diazo compound is provided to secure effective resistance against an external application agent such as shampoo and provide improved dyeing characteristics such as chromaticity, coloring powder and low distinction, thereby capable of more uniform coloration between the tip and root of hair. A dissymmetrical cationic diazo compound is represented by the formula(I), (II), (III) or (IV), wherein R1 is independently C1-4 alkyl radical, phenyl radical, or benzyl radical; R2 is independently C1-16 alkyl radical optionally interrupted by at least one heteroatom and/or at least one group containing at least one heteroatom, hydroxyl, C1-4 alkoxy, C2-4 (poly)hydroxyalkoxy, alkoxycarbonyl, alkylcarbonyloxy radical, alkylcarbonyl radical, amino group, amino group substituted by at least one C1-4 alkyl radical optionally carrying at least one hydroxyl, alkylcarbonylamino, aminocarbonyl, ureido, aminosulfonyl, alkylsulphonylamino, aryl radical, (C1-4)alkylaryl radical, alkylsulphinyl, alkylsulphonyl, nitro, cyano, halogen, thio, alkylthio group; R3 is independently selected from C1-16 alkyl radical optionally interrupted by at least one heteroatom or by at least one group containing at least one heteroatom, hydroxyl, C1-4 alkoxy, C2-4 (poly)hydroxyalkoxy, alkoxycarbonyl, alkylcarbonyloxy, alkylcarbonyl, amino group, amino group substituted by at least one C1-4 alkyl radical optionally carrying at least one hydroxyl, alkylcarbonylamino, aminocarbonyl, ureido, aminosulfonyl, alkylsulphonylamino, alkylthio, alkylsulfinyl, alkylsulfonyl, nitro, cyano, and halogen group. A dyeing composition comprises at least one compound selected from the formulae(I), (II), (III), and (IV), acid addition salts thereof and solvates thereof in a medium appropriate for dyeing keratin fibers.

    Abstract translation: 提供了一种不对称的阳离子重氮化合物以确保对诸如洗发剂之类的外用施用剂的有效抗性，并且提供改善的染色特性，例如色度，着色粉末和低分辨率，从而能够使头发和头发根部之间更均匀的着色。 不对称阳离子重氮化合物由式（I），（II），（III）或（IV）表示，其中R 1独立地为C 1-4烷基，苯基或苄基; R2独立地为C1-16烷基，任选地被至少一个杂原子和/或至少一个含有至少一个杂原子，羟基，C 1-4烷氧基，C 2-4（多）羟基烷氧基，烷氧基羰基，烷基羰基氧基，烷基羰基 氨基，被至少一个任选带有至少一个羟基的C 1-4烷基取代的氨基，烷基羰基氨基，氨基羰基，脲基，氨基磺酰基，烷基磺酰基氨基，芳基，（C 1-4）烷基芳基，烷基亚磺酰基，烷基磺酰基，硝基， 氰基，卤素，硫代，烷硫基; R 3独立地选自任选地被至少一个杂原子中断的C 1-16烷基或至少一个含有至少一个杂原子，羟基，C 1-4烷氧基，C 2-4（多）羟基烷氧基，烷氧基羰基，烷基羰基氧基，烷基羰基， 氨基，被至少一个C 1-4烷基取代的氨基，任选地带有至少一个羟基，烷基羰基氨基，氨基羰基，脲基，氨基磺酰基，烷基磺酰基氨基，烷硫基，烷基亚磺酰基，烷基磺酰基，硝基，氰基和卤素基团。 染色组合物在适于染色角蛋白纤维的介质中包含至少一种选自式（I），（II），（III）和（IV）的化合物，其酸加成盐和溶剂合物。

    2-이미다졸륨기 및 비-양이온성 링커를 함유한 대칭 디아조화합물, 이를 함유하는 조성물, 착색 방법 및 장치
    10.
    发明公开
    2-이미다졸륨기 및 비-양이온성 링커를 함유한 대칭 디아조화합물, 이를 함유하는 조성물, 착색 방법 및 장치 失效
    包含2-咪唑烷基组合物和非阳离子连接剂的对映体二氮化合物，包含它们的组合物，着色方法和装置

    公开(公告)号：KR1020060067914A

    公开(公告)日：2006-06-20

    申请号：KR1020050124171

    申请日：2005-12-15

    Applicant: 로레알

    Inventor： 다비드에르베 ,  그레아브앤드류 ,  도브레스니꼴라

    IPC: C07D403/06 ,  C07D403/14

    CPC classification number: C07D471/04 ,  A61K8/4946 ,  A61Q5/10 ,  C07D233/88 ,  C07D403/12 ,  C09B44/16 ,  C09B55/008

    Abstract: Cationic dissymmetrical diazo compounds (I), their resonance forms, acid addition salts an acid and/or their solvates are new. Cationic dissymmetrical diazo compounds of formula (I) (where electroneutrality of (I) is ensured by one or more anions (An)), their resonance forms, acid addition salts an acid and/or their solvates are new. R11-4C alkyl, phenyl or benzyl (all optionally substituted); R3X or 1-16C alkyl (optionally substituted, and optionally interrupted by one or more heteroatoms or groups containing heteroatoms (preferably O, N, S, -CO and/or -SO2)); X : OH, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy, RO-CO-, RCO-O-, R-CO-, amino (optionally substituted by one or two radicals 1-4C alkyl (optionally carrying OH), where the two alkyl radicals with N optionally form T), alkylcarbonylamino (RCO-NR1-), aminocarbonyl ((R1)2N-CO), ureido (N(R1)2-CO-NR1), aminosulfonyl ((R1)2N-SO2), alkylsulfonylamino (RSO2-NR1-), alkylsulfinyl (R-SO-), alkylsulfonyl (R-SO2-), nitro, CN, halo (Cl or F), HS- or RS; R2X, 1-16C alkyl (optionally substituted by HS, 1-4C thioalkyl, 1-4C alkylsulfinyl or 1-4C alkylsulfonyl, and optionally interrupted by one or more heteroatoms or groups containing heteroatoms (preferably O, N, S, -CO and/or -SO2)), substituted aryl or 1-4C arylalkyl (optionally substituted); e, m1 : 0-4; T : 5-7 membered optionally aromatic heterocycle (containing 1-3 (preferably 1-2) heteroatoms N (preferred), O or S); W1H, halo (Br, Cl or F (preferably Cl or F)), NR5R6, OR7, -NR4-Ph-NR5R6, -NR4-Ph-OR7, -O-Ph-OR7 or -O-Ph-NR5R6; R4, R71-20C (preferably 1-16C) alkyl, 1-3C aralkyl, phenyl (all optionally substituted) or H; either R5, R61-20C (preferably 1-16C) alkyl, 1-3C aralkyl, phenyl (all optionally substituted), H or R-CO-; or NR5R6T; or R5 + R6 + C (of aromatic cycle adjacent to that to which -NR5R6 is attached) : 5-6 membered saturated heterocycle; Ph : optionally substituted phenyl; L : covalent bond, 1-40C (preferably 1-20C) alkyl (optionally substituted and optionally interrupted by 3-7 membered optimally aromatic heterocycle (optionally fused and optionally substituted), one or more heteroatoms or groups containing heteroatoms (O, N, S, CO and/or SO2)) or optionally substituted phenyl; R : 1-4C alkyl; and R1H or R. Provided that when e is 2, then two adjacent R2 together forms with carbon atom to which they are attached a 5-6 (preferably 6) membered secondary cycle (optionally substituted by 1-4C alkyl, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy or amino (optionally substituted by 1-4C alkyl (optionally carrying OH)). Provided that when m1 is 2, then two adjacent R3 together forms with carbon atom to which they are attached a 6 membered secondary cycle (optionally substituted by OH, 1-4C alkyl, 1-4C alkoxy, 2-4C (poly)hydroxyalkoxy or amino (optionally substituted by 1-4C alkyl (optionally carrying OH)). Provided that when e and m1 are lower than 4, the carbon atoms of unsubstituted heterocycle carry a hydrogen atom. Provided that OR7 and NR5R6 groups form substitutions i.e. when two adjacent R3 form a 6-membered aromatic ring, which is optionally substituted by NR4-Ph, NR4-Ph-OR7 or NR4-Ph-NR5R6. Provided that L is not azo, nitro, nitroso or peroxo. Independent claims are included for: (1) a tinctorial composition (A) comprising (I), in a medium for the dyeing of keratinous fibers, as direct dye; (2) a process of dyeing keratinous fiber comprising contacting (A) with the dry or wet fibers to obtain the desired effect; and (3) a device with several compartments, comprising a first compartment comprising (A) and a second compartment containing an oxidizing composition. [Image]

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