Abstract:
PURPOSE: A gel polymer electrolyte is provided be manufactured even in low monomer concentration without separate hardening devices, to have improved ion conductivity, and to able to improve charging/discharging performance of a lithium battery. CONSTITUTION: A gel polymer electrolyte comprises an organic solvent, and a lithium salt capable of generating one or more of protonic acid and Lewis acid by reacting with residual moisture in the organic solvent. The lithium salt is one or more selected from a group consisting of LiBF4, LiPF6, LiAsF6, LiSbF6, and LiPF3(CF2CF3)3. The lithium battery comprises a positive electrode, a negative electrode, a separator, and the gel polymer electrolyte.
Abstract:
PURPOSE: A positive electrode is provided to restrain side reaction with electrolyte, and to retrain the elution of transition metal at high temperatures. CONSTITUTION: A positive electrode comprises a current collector, and a positive electrode active material layer arranged on the current collector. The positive electrode active material layer comprises lithium transition metal oxide with spinel structure, conducting material, and a binder. The average operation potential of the lithium transition metal oxide with spinel structure is 4.6V or higher, and the average diameter is 20nm - 10 micron. A manufacturing method of the positive electrode comprises a step of forming a positive electrode active material on a current collector, and a step of fluorinating the surface of the positive electrode active material layer.
Abstract:
PURPOSE: A negative electrode active material is provided to improve lifetime properties of a lithium battery by including a molybdenum-based core in which nitrides and/or nitride coating layer is formed. CONSTITUTION: A negative electrode active material comprises: a core including a molybdenum-based material; and a coating layer formed on at least a part of the core surface. The coating layer includes one or more selected from the group consisting of molybdenum oxynitride and molybdenum nitride. The core is completely coated by the coating layer. The average thickness of the coating layer is 10-40 nm. A method for manufacturing the negative electrode active material comprises a step of contacting the molybdenum-based material with nitrogen precursor gas.
Abstract:
PURPOSE: A negative electrode comprising metal nanotube, a lithium battery comprising the same, and a preparation method thereof are provided to improve the discharge capacity, capacity retention rate, charge and discharge efficiency, and high efficiency of a lithium battery. CONSTITUTION: A negative electrode comprises: a conductive substrate; and nanotubes comprising a metal/metalloid, disposed on the conductive substrate, and having opened ends. The nanotubes comprise one selected from the group consisting of silicon(Si), germanium(Ge), tin(Sn), aluminum(Al), zinc(Zn), silver(Ag), gold(Au), platinum(Pt), and an alloy thereof. The nanotubes further comprise a dopant.
Abstract:
PURPOSE: A negative electrode, a lithium battery including thereof, and a manufacturing method thereof are provided to improve the discharge capacity of the lithium battery, the capacity retention rate, and the initial charging/discharging efficiency. CONSTITUTION: A negative electrode comprises a conductive substrate, and plural 4B metal nanotubes separately arranged on the substrate. A manufacturing method of the negative electrode comprises the following steps; growing nanorods on the substrate; coating the nanorods with a 4B metal layer; and selectively removing the nanorods only, by heat-processing the nanorods.
Abstract:
PURPOSE: A gel polymer electrolyte, a lithium battery including thereof, a manufacturing method thereof, and a manufacturing method of the lithium battery are provided to control the irreversible reaction of the electrolyte with an irregular complex negative electrode active material. CONSTITUTION: A gel polymer electrolyte contains a first lithium salt, an organic solvent, fluorid, and a polymer formed by polymerizing H2C=C-(OR1)n-OCH=CH2 monomer. In the monomer, R refers to an alkylene group with the carbon number of 2~10, and n refers to 1~1000. The fluorid forms protonic acid or lewis acid by reacting with residual moisture among the organic solvent. The first lithium salt is inactive with the residual moisture. The polymer is produced by the reaction between the protonic acid or the lewis acid with the monomer.
Abstract:
PURPOSE: A secondary battery is provided to secure stable flexibility, to ensure stable performance of a battery, and to achieve miniaturization and lightweight of electronic devices. CONSTITUTION: A secondary battery comprises a substrate(10); a first electrode current collector(20) that is installed on the substrate and integrated with the substrate; a first electrode material layer(30), an electrolyte layer(40), and a second electrode material layer(50) which are laminated on the first electrode current collector in order; and a metal net-shaped second electrode current collector(60) which is integrally combined with the second electrode material layer.
Abstract:
An electrode, its preparation method, a lithium battery using the electrode, and an electrode coating composition are provided to maintain the potential of an active material layer even without using an excessive amount of a conductor and a binder and to prevent the cracking of an active material layer in case of charge/discharge. An electrode comprises an active material layer which is coated on a current collector and has a network structure, wherein the network structure comprises a carbon nanotube and a binder. The electrode is prepared by coating a dispersion comprising a carbon nanotube and a binder on a current collector to form a coating layer; and printing an electrode ink on the coating layer to form an active material layer.
Abstract:
An electrode ink for an inkjet print, an electrode and a lithium battery prepared using the same are provided to reduce the viscosity of the electrode ink and improve nozzle clogging by applying a polyol compound to the electrode ink. An electrode ink for the inkjet print comprises an electrode active material, a polar medium, and a moisturizer. The moisturizer comprises a polyol compound which is indicated by formula 1. The content of the polyol compound is 10 or 40 weight% of the electrode ink total weight. An R1 to r5 independently represent hydrogen, alkoxy group, alkyl group, carbon ring, aryl group, alkylaryl group, arylakyl, heteroaryl, and n represent an integral number.
Abstract translation:提供用于喷墨印刷的电极油墨,电极和使用其的锂电池,以通过将多元醇化合物施加到电极油墨来降低电极油墨的粘度并改善喷嘴堵塞。 用于喷墨打印的电极墨水包括电极活性材料,极性介质和保湿剂。 保湿剂包括由式1表示的多元醇化合物。多元醇化合物的含量为电极油墨总重量的10或40重量%。 R 1至R 5独立地表示氢,烷氧基,烷基,碳环,芳基,烷基芳基,芳基烷基,杂芳基,n表示整数。