公开(公告)号：KR1020100077267A

公开(公告)日：2010-07-08

申请号：KR1020080135170

申请日：2008-12-29

Applicant: 제일모직주식회사

Inventor： 이진성 ,  장복남 ,  정인철 ,  남윤구 ,  조미란

IPC: C08L69/00 ,  C08L67/03 ,  C08L53/02 ,  C08K5/521

CPC classification number: C08L69/00 ,  C08K5/523 ,  C08L21/00 ,  C08L67/02 ,  C08L2666/02

Abstract: PURPOSE: A flameproof thermoplastic resin composition is provided to be environment-friendly used without containing halogen and to obtain excellent flame retardant property, shock resistance, heat resistance, and chemical resistance by increasing mobility. CONSTITUTION: A flameproof thermoplastic resin composition is comprised of 100.0 parts by weight of a base resin and 5-30 parts by weight of an aromatic phosphate ester compound. The base resin includes 5-40 weight% of a rubber-modified aromatic vinyl copolymer resin, 30-90 weight% of a polycarbonate resin, and 1-50 weight% of an amorphous polymer resin. The rubber-modified aromatic vinyl copolymer resin includes 10-60 weight% of a rubber elastomer, 20-80 weight% of aromatic vinyl monomer, and 5-45 weight% of a monomer which is capable of being copolymerized with the aromatic vinyl monomer.

Abstract translation: 目的：提供一种防火热塑性树脂组合物，在环境友好的情况下使用而不含卤素，并通过增加流动性获得优异的阻燃性，抗冲击性，耐热性和耐化学性。 构成：防火热塑性树脂组合物由100.0重量份基础树脂和5-30重量份芳族磷酸酯化合物组成。 基础树脂包括5-40重量％的橡胶改性的芳族乙烯基共聚物树脂，30-90重量％的聚碳酸酯树脂和1-50重量％的无定形聚合物树脂。 橡胶改性的芳族乙烯基共聚物树脂包括10-60重量％的橡胶弹性体，20-80重量％的芳族乙烯基单体和5-45重量％的能够与芳族乙烯基单体共聚的单体。

公开(公告)号：KR1020100074965A

公开(公告)日：2010-07-02

申请号：KR1020080133535

申请日：2008-12-24

Applicant: 제일모직주식회사

Inventor： 조미란 ,  장복남 ,  정인철 ,  남윤구 ,  이진성

IPC: C08L69/00 ,  C08L33/06 ,  C08L25/00 ,  C08K5/20

Abstract: PURPOSE: A flame-retarding scratch-resistant thermoplastic resin composition is provided to prevent the degradation of the coloring ability, and to reduce the difference of the refractive index between polycarbonate and an acrylic resin. CONSTITUTION: A flame-retarding scratch-resistant thermoplastic resin composition contains the following: 100 parts of base resin by weight; 0.1~6 parts of fatty acid carboxylic acid amide compound by weight; 1~50 parts of flame retardant by weight; and 1~30 parts of reinforcing agent. The base resin includes 40~80 parts of polycarbonate resin by weight, 1~50 parts of modified (meth)acrylic copolymer resin by weight, and 0.1~50 parts of aromatic vinyl resin by weight. The refractive index of the modified (meth)acrylic copolymer resin is 1.495~1.590.

Abstract translation: 目的：提供阻燃耐刮擦热塑性树脂组合物，以防止着色能力的降低，并减少聚碳酸酯和丙烯酸树脂之间的折射率差异。 构成：阻燃耐刮擦热塑性树脂组合物含有以下物质：100重量份的基础树脂; 按重量计0.1〜6份脂肪酸羧酸酰胺化合物; 1〜50份重量的阻燃剂; 和1〜30份增强剂。 基础树脂包括40〜80重量份的聚碳酸酯树脂，1〜50重量份的改性（甲基）丙烯酸共聚物树脂，和0.1〜50重量份的芳族乙烯基树脂。 改性（甲基）丙烯酸共聚物树脂的折射率为1.495〜1.590。

公开(公告)号：KR1020100070000A

公开(公告)日：2010-06-25

申请号：KR1020080128585

申请日：2008-12-17

Applicant: 제일모직주식회사

Inventor： 남윤구 ,  장복남 ,  정인철 ,  이진성 ,  조미란

IPC: C08L53/02 ,  C08L33/06 ,  C08K7/16 ,  C08K5/02

Abstract: PURPOSE: A flame-retardant thermoplastic resin composition is provided to improve the flame retardant, the scratch resistance, the impact strength, and the transparency of the composition. CONSTITUTION: A flame-retardant thermoplastic resin composition contains the following: 100 parts of base resin by weigh formed with 50~90wt% of rubber-modified aromatic vinyl group copolymer resin, and 10~50wt% of (meth)acrylate resin; 0.1~20 parts of (meth)acrylate-based polymer bead by weight; 1~30 parts of halogen based compound by weight; and 0.1~15 parts of flame-retardant adjuvant by weight. The rubber-modified aromatic vinyl group copolymer resin is formed with 10~40wt% of aromatic vinyl group graft copolymer resin, and 60~90wt% of aromatic vinyl group copolymer resin.

Abstract translation: 目的：提供阻燃热塑性树脂组合物，以改善组合物的阻燃性，耐擦伤性，冲击强度和透明度。 构成：阻燃性热塑性树脂组合物含有：由50〜90重量％的橡胶改性芳香族乙烯基共聚树脂构成的100重量份的基础树脂和10〜50重量％的（甲基）丙烯酸酯树脂; 0.1〜20份（甲基）丙烯酸酯类聚合物珠粒; 1〜30份重量的卤素类化合物; 和0.1〜15份阻燃助剂。 橡胶改性芳族乙烯基共聚物树脂由10〜40wt％的芳香族乙烯基接枝共聚物树脂和60〜90wt％的芳香族乙烯基共聚物树脂形成。

公开(公告)号：KR1020100069998A

公开(公告)日：2010-06-25

申请号：KR1020080128582

申请日：2008-12-17

Applicant: 제일모직주식회사

Inventor： 남윤구 ,  장복남 ,  정인철 ,  이진성 ,  조미란

IPC: C08L69/00 ,  C08L33/06 ,  C08K7/16 ,  C08K5/00

Abstract: PURPOSE: A flame-retardant thermoplastic resin composition is provided to improve the fire retardant property without using the high contents of fire retardants, and to improve the heat resistance the impact strength of the composition. CONSTITUTION: A flame-retardant thermoplastic resin composition with the improved scratch resistance contains the following: 100 parts of base resin by weight formed with 50~90wt% of polycarbonate resin, and 10~50wt% of (meth)acrylate-based resin; 1~50 parts of flame retardant by weight; and 0.1~20 parts of cross-linked (meth)acrylate polymer bead by weight. The (meth)acrylate-based resin is a copolymer including 50~100wt% of alkyl (meth)acrylate with the carbon number of 1~4, and 0.5~50wt% of monomer capable of interpolymerizing with the alkyl (meth)acrylate.

Abstract translation: 目的：提供阻燃热塑性树脂组合物以提高阻燃性能，而不使用高含量的阻燃剂，并提高组合物的抗冲击强度。 构成：具有改善的耐刮擦性的阻燃热塑性树脂组合物包含：100重量份由50〜90重量％的聚碳酸酯树脂形成的基础树脂和10〜50重量％的（甲基）丙烯酸酯类树脂; 1〜50份重量的阻燃剂; 和0.1〜20份交联的（甲基）丙烯酸酯聚合物珠粒。 （甲基）丙烯酸酯系树脂是包含50〜100重量％的碳原子数为1〜4的（甲基）丙烯酸烷基酯和能够与（甲基）丙烯酸烷基酯共聚的单体的0.5〜50重量％的共聚物。

公开(公告)号：KR1020100049458A

公开(公告)日：2010-05-12

申请号：KR1020080108619

申请日：2008-11-03

Applicant: 제일모직주식회사

Inventor： 장복남 ,  정인철 ,  남윤구 ,  이진성 ,  조미란 ,  최진환

IPC: C08L69/00 ,  C08L33/06 ,  C08L101/12

Abstract: PURPOSE: A scratch resistance thermoplastic resin composition is provided to minimize refractive index difference between resins and to ensure commerciality. CONSTITUTION: A scratch resistance thermoplastic resin composition contains: 30-80 weight% of polycarbonate resin, and 20-70 weight% of copolymer having (metha)acrylate having aromatic family of 1-10 carbon atoms or aliphatic substituent and vinylic monomer. The vinylic monomer has 1.6 or more refractive index in a homopolymer. The refractive index of the polycarbonate resin is 1.57-1.59. The (meta)acrylate has 80 weight% or more of methylmethacrylate.

Abstract translation: 目的：提供耐刮擦热塑性树脂组合物以使树脂之间的折射率差异最小化并确保商业性。 构成：耐刮擦热塑性树脂组合物包含：30-80重量％的聚碳酸酯树脂和20-70重量％的具有1-10个碳原子的芳族族的（甲基）丙烯酸酯或脂族取代基和乙烯基单体的共聚物。 乙烯基单体在均聚物中的折射率为1.6以上。 聚碳酸酯树脂的折射率为1.57-1.59。 （甲基）丙烯酸酯具有80重量％以上的甲基丙烯酸甲酯。

公开(公告)号：KR100877296B1

公开(公告)日：2009-01-07

申请号：KR1020070141289

申请日：2007-12-31

Applicant: 제일모직주식회사

Inventor： 정인철 ,  장복남 ,  이혜진 ,  조미란 ,  윤정환 ,  최진환

IPC: C08L69/00 ,  C08L33/10 ,  C08K9/02 ,  B82Y30/00

Abstract: A thermoplastic resin composition is provided to secure excellent fire retardancy and scratch resistance by using halloysite as an aluminum silicate inorganic filler. A scratch-resistant flame retardant thermoplastic resin composition comprises a base resin 100.0 parts by weight, a flame retardant 1-50 parts by weight, and halloysite 1-20 parts by weight of the chemical formula of Al2Si2O5(OH)4. The base resin is made of (A) polycarbonate-based resin 20-90 weight% and (B) methacrylate-based 10-80 weight%. The methacrylate-based resin (B) is a methylmethacrylate 50-100 weight%, and a monomer 0-50 weight% capable of being copolymerized with the methylmethacrylate. The halloysite has a diameter of 40-200 nanometer.

Abstract translation: 提供一种热塑性树脂组合物，通过使用多水高岭土作为硅酸铝无机填料来确保优异的阻燃性和耐划伤性。 耐刮擦阻燃热塑性树脂组合物包含100.0重量份的基础树脂，1-50重量份的阻燃剂和约100重量份的化学式为Al 2 Si 2 O 5（OH）4的多水高岭土。 基础树脂由（A）20-90重量％的聚碳酸酯基树脂和（B）甲基丙烯酸酯基10-80重量％制成。 甲基丙烯酸酯系树脂（B）为甲基丙烯酸甲酯50-100重量％，能够与甲基丙烯酸甲酯共​​聚的0-50重量％的单体。 多水高岭土的直径为40-200纳米。

公开(公告)号：KR1020080089121A

公开(公告)日：2008-10-06

申请号：KR1020070046739

申请日：2007-05-14

Applicant: 제일모직주식회사

Inventor： 장복남 ,  정인철 ,  박희정 ,  조미란 ,  조진경 ,  최진환

IPC: C08F230/02 ,  C08F212/00 ,  C08F212/10

CPC classification number: C08F230/02 ,  C08F212/10 ,  C08L25/12 ,  C08L43/02 ,  C08L2201/02

Abstract: A flame retardant copolymer, and a flame retardant thermoplastic resin composition are provided to improve flame retardancy, to prevent the deterioration of mechanical properties of the copolymer, and to enhance the balance of physical properties of the composition. A flame retardant copolymer comprises 5-98 wt% of a vinyl cyano monomer; 1-94 wt% of an aromatic vinyl monomer; and 1-30 wt% of a vinyl group-containing phosphorus-based monomer. Preferably the vinyl group-containing phosphorus-based monomer is represented by the formula 1, 2, 3 or 4, wherein R1 is H or a methyl group; R2 and R3 are independently a methyl group or an ethyl group; and n is 0 or 1. A flame retardant thermoplastic resin composition comprises 100 parts by weight of the flame retardant copolymer; and 0.001-50 30 parts by weight of an impact modifier.

Abstract translation: 提供阻燃共聚物和阻燃热塑性树脂组合物以改善阻燃性，防止共聚物的机械性能的劣化，并提高组合物的物理性能的平衡。 阻燃共聚物包含5-98重量％的乙烯基氰基单体; 1-94重量％的芳族乙烯基单体; 和1-30重量％的含乙烯基的磷基单体。 优选地，含乙烯基的磷基单体由式1,2,3或4表示，其中R1是H或甲基; R2和R3独立地是甲基或乙基; n为0或1.阻燃热塑性树脂组合物包含100重量份的阻燃共聚物; 和0.001-50 30重量份的抗冲改性剂。