내마모성 초고분자량 폴리에틸렌 복합체 및 그의 제조 방법
    23.
    发明公开
    내마모성 초고분자량 폴리에틸렌 복합체 및 그의 제조 방법 失效
    耐磨超高分子量聚乙烯复合材料及其制备方法

    公开(公告)号:KR1020050060147A

    公开(公告)日:2005-06-22

    申请号:KR1020030091232

    申请日:2003-12-15

    Abstract: 본 발명은 인공관절 등에 사용되는 초고분자량 폴리에틸렌의 내마모성이 향상된 내마모성 초고분자량 폴리에틸렌 복합체 및 그의 제조방법에 관한 것이다. 본 발명에 따르면, 충전제로 사용되는 무기입자 표면에 초고분자량 폴리에틸렌 중합용 전이금속 촉매/조촉매를 담지하고, 담지된 촉매 위치로부터 초고분자량 폴리에틸렌을 중합함으로써 무기입자 표면이 초고분자량 폴리에틸렌으로 피막된 복합 분말을 얻고, 이들 분말을 직접 성형해 고함량의 무기물 충전과 균일한 무기물 분산을 갖는 인공관절용 초고분자량 폴리에틸렌 복합체를 얻는다. 본 발명에 의해 제조된 무기입자가 충전된 초고분자량 폴리에틸렌 인공관절 재료는 충전되지 않은 초고분자량 폴리에틸렌 재료에 비해 뛰어난 내마모성을 보여 준다.

    내마모성이 향상된 무기입자 충전 초고분자량 폴리에틸렌조성물 및 그의 제조방법
    24.
    发明公开
    내마모성이 향상된 무기입자 충전 초고분자량 폴리에틸렌조성물 및 그의 제조방법 失效
    超高分子量聚乙烯组合物,包含超高分子量聚乙烯和无机颗粒,其制备方法及其人造连接或机器部件的模制产品

    公开(公告)号:KR1020050013005A

    公开(公告)日:2005-02-02

    申请号:KR1020030051822

    申请日:2003-07-26

    Abstract: PURPOSE: Provided are an ultra-high molecular weight polyethylene composition which is improved in abrasion resistance by charging an inorganic material, its preparation method, and an ultra-high molecular weight polyethylene molded product used in an artificial joint or a machine part prepared by using the composition. CONSTITUTION: The ultra-high molecular weight polyethylene composition comprises an ultra-high molecular weight polyethylene; and 5-50 wt% of an inorganic particle selected from the group consisting of kaolinite, talc, smectite, montmorillonite and mica. Preferably the ultra-high molecular weight polyethylene has a molecular weight of 1,750,000-6,000,000. The method comprises the step of mixing the ultra-high molecular weight polyethylene fine particle and the inorganic particle with stirring, or mixing them in a suitable solvent and drying the mixture.

    Abstract translation: 目的:提供一种超高分子量聚乙烯组合物,其通过加入无机材料,其制备方法和用于人造接头的超高分子量聚乙烯模塑产品或通过使用 组成。 构成:超高分子量聚乙烯组合物包含超高分子量聚乙烯; 和5-50重量%的选自高岭石,滑石,蒙皂石,蒙脱石和云母的无机颗粒。 优选地,超高分子量聚乙烯的分子量为1,750,000-6,000,000。 该方法包括在搅拌下混合超高分子量聚乙烯微粒和无机颗粒,或将其混合在合适的溶剂中并干燥该混合物的步骤。

    폴리에스터/클레이 나노 복합 재료 및 그 제조방법
    25.
    发明公开
    폴리에스터/클레이 나노 복합 재료 및 그 제조방법 失效
    聚酯/粘土纳米复合材料,其包含环状酯低聚物间隔拉曼结构粘土及其制造方法

    公开(公告)号:KR1020040110891A

    公开(公告)日:2004-12-31

    申请号:KR1020030040376

    申请日:2003-06-20

    CPC classification number: C08J5/005 B82Y30/00 C08J2367/02 C08K9/08

    Abstract: PURPOSE: Provided are a polyester/clay nanocomposite material having low melt flow index, excellent processability, good mechanical and electrical properties, thereby being capable of utilizing as a substitute for a polyester resin and as a compatibilizer, and a manufacturing method thereof. CONSTITUTION: The polyester/clay nanocomposite material comprises a lamella structure of clay in which a cyclic ester oligomer is intercalated in a weight ratio of the cyclic ester oligomer : clay to 100:0.1-10. The cyclic ester oligomer is selected from the group consisting of poly(ethylene terephthalate), poly(ethylene isophthalate), poly(butylene terephthalate), poly(2,6-dinaphthoate) and poly(ethylene 2,6-naphthalenedicarboxylate), and the clay is comprised of phyllosilicate consisted of an aluminum silicate or magnesium silicate layer, and a sodium or potassium ion filled between the phyllosilicate layer. The polyester/clay nanocomposite material is manufactured by the method comprising mixing a cyclic ester oligomer and an organic clay to obtain a mixture in which the cyclic ester oligomer is intercalated between the lamella structure of clay, and polymerizing the cyclic ester oligomer to release the lamella structure of clay greater than 50nm.

    Abstract translation: 目的:提供具有低熔体流动指数,优异的加工性能,良好的机械和电学性能的聚酯/粘土纳米复合材料,从而能够用作聚酯树脂和增容剂的替代品及其制造方法。 构成:聚酯/粘土纳米复合材料包括粘土薄片结构,其中环酯低聚物以环酯低聚物:粘土的重量比插入到100:0.1-10。 环状酯低聚物选自聚对苯二甲酸乙二醇酯,聚(乙烯间苯二甲酸酯),聚对苯二甲酸丁二醇酯,聚(2,6-二萘酸)和聚(2,6-萘二甲酸乙二醇酯))和 粘土由硅酸铝或硅酸镁层构成的页硅酸盐和填充在页硅酸盐层之间的钠或钾离子组成。 聚酯/粘土纳米复合材料通过以下方法制造:将环状酯低聚物和有机粘土混合,得到其中环状酯低聚物插入粘土层状结构之间并使环状酯低聚物聚合以释放薄片的混合物 粘土结构大于50nm。

    클레이가 분산된 올레핀계 고분자 나노 복합체 제조방법
    26.
    发明授权
    클레이가 분산된 올레핀계 고분자 나노 복합체 제조방법 失效
    클레이가분산된올레핀계고분자나노복합체제조방클

    公开(公告)号:KR100445237B1

    公开(公告)日:2004-08-18

    申请号:KR1020010050871

    申请日:2001-08-23

    Abstract: PURPOSE: A method for preparing a clay-dispersed olefin-based polymer nanocomposite and a polyolefin resin by using the nanocomposite are provided, to improve the tensile strength and the heat transformation temperature without deterioration of the transparency. CONSTITUTION: The method comprises the steps of dipping a catalyst for polymerization of olefin into clay, dipping a co-catalyst into clay, and polymerizing the olefin, wherein the clay is an organic treated clay having a functional group capable of a catalyst being supported to, the catalyst for polymerization of olefin is a Ziegler-Natta catalyst where chlorine or oxychloride is bonded with titanium or vanadium, and the co-catalyst is an organoaluminum. Preferably the clay is selected from the group consisting of montmorillonite, hectorite, saponite, sauconite, vermiculite, magadiite and kenyaite; the catalyst for polymerization of olefin is an organometal complex bonded with a metal selected from Zr, Ti, Ni and Pd; and the organoaluminum used as a co-catalyst is selected from (C2H5)3Al, (C2H5)2AlCl, (C2H5)AlCl2, (t-C4H9)3Al and (iso-C4H9)3Al.

    Abstract translation: 目的:提供一种通过使用该纳米复合材料制备粘土分散的烯烃基聚合物纳米复合材料和聚烯烃树脂的方法,以提高拉伸强度和热转变温度而不会使透明度劣化。 构成:该方法包括将用于烯烃聚合的催化剂浸渍到粘土中,将助催化剂浸渍到粘土中并使烯烃聚合的步骤,其中粘土是具有能够将催化剂负载的官能团的有机处理粘土 用于烯烃聚合的催化剂是其中氯或氯氧化物与钛或钒结合的齐格勒 - 纳塔催化剂,并且该助催化剂是有机铝。 优选地,粘土选自蒙脱石,锂蒙脱石,皂石,锌蒙脱石,蛭石,magadiite和肯纳石; 用于烯烃聚合的催化剂是与选自Zr,Ti,Ni和Pd的金属键合的有机金属配合物; 并且用作助催化剂的有机铝选自(C 2 H 5)3 Al,(C 2 H 5)2 AlCl,(C 2 H 5)AlCl 2,(tC 4 H 9)3 Al和(isoC 4 H 9)3 Al。

    도포형 실리콘 페이스트를 이용한 현장성형 방식의 전자파차폐 방법
    27.
    发明授权

    公开(公告)号:KR100403549B1

    公开(公告)日:2003-10-30

    申请号:KR1020010067599

    申请日:2001-10-31

    Abstract: PURPOSE: A method for shielding electromagnetic interference waves by using form-in-place type electrically conductive silicone pastes is provided to be capable of finding a viscosity condition suitable for form-in-place of a paste having a very low volume resistivity. CONSTITUTION: An application-type silicon paste is formed to have the viscosity over 3000 Pa.s at the shear velocity below 0.1/sec and the viscosity over 100 Pa.s at the shear velocity below 100/sec and has a volume resistivity below 0.01 ohm.cm. The application-type silicon paste contains a conductive metal particle over 80 weight% and a silicon component below 20 weight%. The conductive metal particle is adjusted to have a diameter below 7 micrometers, a distribution degree over 4 and a shaping rate over 1.

    Abstract translation: 目的:提供一种通过使用就地型导电硅酮糊来屏蔽电磁干扰波的方法,其能够找到适合于体积电阻率非常低的糊就地形成的粘度条件。 组成:应用型硅膏的形成在低于0.1 /秒的剪切速度下具有超过3000帕·秒的粘度,并且在低于100 /秒的剪切速度下粘度超过100帕·秒,并且体积电阻率低于0.01 欧·厘米。 应用型硅膏包含超过80重量%的导电金属颗粒和低于20重量%的硅组分。 导电金属颗粒被调整为具有低于7微米的直径,分布度超过4并且成形率超过1。

    클레이가 분산된 올레핀계 고분자 나노 복합체 제조방법
    28.
    发明公开
    클레이가 분산된 올레핀계 고분자 나노 복합체 제조방법 失效
    基于烯烃的聚合物纳米复合材料的制备方法

    公开(公告)号:KR1020030025308A

    公开(公告)日:2003-03-29

    申请号:KR1020010050871

    申请日:2001-08-23

    Abstract: PURPOSE: A method for preparing a clay-dispersed olefin-based polymer nanocomposite and a polyolefin resin by using the nanocomposite are provided, to improve the tensile strength and the heat transformation temperature without deterioration of the transparency. CONSTITUTION: The method comprises the steps of dipping a catalyst for polymerization of olefin into clay, dipping a co-catalyst into clay, and polymerizing the olefin, wherein the clay is an organic treated clay having a functional group capable of a catalyst being supported to, the catalyst for polymerization of olefin is a Ziegler-Natta catalyst where chlorine or oxychloride is bonded with titanium or vanadium, and the co-catalyst is an organoaluminum. Preferably the clay is selected from the group consisting of montmorillonite, hectorite, saponite, sauconite, vermiculite, magadiite and kenyaite; the catalyst for polymerization of olefin is an organometal complex bonded with a metal selected from Zr, Ti, Ni and Pd; and the organoaluminum used as a co-catalyst is selected from (C2H5)3Al, (C2H5)2AlCl, (C2H5)AlCl2, (t-C4H9)3Al and (iso-C4H9)3Al.

    Abstract translation: 目的:提供使用纳米复合材料制备粘土分散的烯烃类聚合物纳米复合材料和聚烯烃树脂的方法,以提高拉伸强度和热转变温度,而不会降低透明度。 方法:该方法包括将用于烯烃聚合的催化剂浸入粘土中,将助催化剂浸入粘土中并使烯烃聚合的步骤,其中粘土是具有能够将催化剂的官能团负载的有机处理的粘土 ,烯烃聚合催化剂是齐格勒 - 纳塔催化剂,其中氯或氯氯化物与钛或钒结合,助催化剂是有机铝。 优选地,粘土选自蒙脱石,锂蒙脱石,皂石,琥珀酸盐,蛭石,麦草碱和肯尼亚; 用于烯烃聚合的催化剂是与选自Zr,Ti,Ni和Pd的金属结合的有机金属络合物; 用作助催化剂的有机铝选自(C2H5)3A1,(C2H5)2AlCl,(C2H5)AlCl2,(t-C4H9)3A1和(iso-C4H9)3Al。

    외고정기기용 탄소섬유 보강 ˝C˝자형 구조재 및 그의제조방법
    29.
    发明授权
    외고정기기용 탄소섬유 보강 ˝C˝자형 구조재 및 그의제조방법 失效
    외고정기기용탄소섬유보강˝C​​˝자형구조재및그의제조방외

    公开(公告)号:KR100370592B1

    公开(公告)日:2003-02-05

    申请号:KR1020000040024

    申请日:2000-07-12

    Abstract: PURPOSE: A manufacturing method of carbon fiber reinforced C-shaped structure is provided to obtain a carbon fiber reinforced C-shaped structure having the improved physical property by winding plural one-directional carbon fiber prepreg units on a cylindrical roller. CONSTITUTION: A sheet of one-directional carbon fiber prepreg is sheared into a tape form and then cut at specific length to prepare plural sheets of one-directional carbon fiber prepreg units(11)(S1). The plural one-directional carbon fiber prepreg units are piled up and wound on a cylindrical roller to form a C-shaped or ring-shaped preform(13)(S2). The preform is wound up as taffeta or satin label prepreg(15)(S3). Then, the preform is heated in a compression mold having a vacuum device to obtain a C-shaped structure(S4). If the preform is molded in the compression mold, the inside of an outer fixing unit has not pores. Thereby, the physical property of the C-shaped structure is improved.

    Abstract translation: 目的:提供碳纤维增强C形结构的制造方法,以通过将多个单向碳纤维预浸料单元缠绕在圆柱形辊上来获得具有改善的物理性能的碳纤维增强的C形结构。 组成:将一片单向碳纤维预浸料剪切成带状,然后切割成特定长度以制备多片单向碳纤维预浸料坯(S1)(S1)。 将多个单向碳纤维预浸渍体单元堆积并缠绕在圆柱形辊上以形成C形或环形预成型体(13)(S2)。 预成型件作为塔夫绸或缎标签预浸料(15)卷绕(S3)。 然后,在具有真空装置的压缩模具中加热预成型体以获得C形结构(S4)。 如果预成型件在压缩模具中成型,则外部固定单元的内部不具有孔。 由此,C形结构的物理特性得到改善。

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