Abstract:
본 발명은 높은 열전도도와 낮은 열팽창 계수를 갖는 전자 패키징용 열관리재료 및 그 제조방법에 관한 것으로, 보다 상세하게는, 고분자 수지 내에 서로 다른 형상의 무기입자를 충전함으로써 열전도 네트워크를 형성하고, 고열전도도와 저열팽창계수를 가지는 전자 패키징용 열전도성 재료에 관한 것이다.
Abstract:
본 발명은 인공관절 등에 사용되는 초고분자량 폴리에틸렌의 내마모성이 향상된 내마모성 초고분자량 폴리에틸렌 복합체 및 그의 제조방법에 관한 것이다. 본 발명에 따르면, 충전제로 사용되는 무기입자 표면에 초고분자량 폴리에틸렌 중합용 전이금속 촉매/조촉매를 담지하고, 담지된 촉매 위치로부터 초고분자량 폴리에틸렌을 중합함으로써 무기입자 표면이 초고분자량 폴리에틸렌으로 피막된 복합 분말을 얻고, 이들 분말을 직접 성형해 고함량의 무기물 충전과 균일한 무기물 분산을 갖는 인공관절용 초고분자량 폴리에틸렌 복합체를 얻는다. 본 발명에 의해 제조된 무기입자가 충전된 초고분자량 폴리에틸렌 인공관절 재료는 충전되지 않은 초고분자량 폴리에틸렌 재료에 비해 뛰어난 내마모성을 보여 준다.
Abstract:
PURPOSE: Provided are an ultra-high molecular weight polyethylene composition which is improved in abrasion resistance by charging an inorganic material, its preparation method, and an ultra-high molecular weight polyethylene molded product used in an artificial joint or a machine part prepared by using the composition. CONSTITUTION: The ultra-high molecular weight polyethylene composition comprises an ultra-high molecular weight polyethylene; and 5-50 wt% of an inorganic particle selected from the group consisting of kaolinite, talc, smectite, montmorillonite and mica. Preferably the ultra-high molecular weight polyethylene has a molecular weight of 1,750,000-6,000,000. The method comprises the step of mixing the ultra-high molecular weight polyethylene fine particle and the inorganic particle with stirring, or mixing them in a suitable solvent and drying the mixture.
Abstract:
PURPOSE: Provided are a polyester/clay nanocomposite material having low melt flow index, excellent processability, good mechanical and electrical properties, thereby being capable of utilizing as a substitute for a polyester resin and as a compatibilizer, and a manufacturing method thereof. CONSTITUTION: The polyester/clay nanocomposite material comprises a lamella structure of clay in which a cyclic ester oligomer is intercalated in a weight ratio of the cyclic ester oligomer : clay to 100:0.1-10. The cyclic ester oligomer is selected from the group consisting of poly(ethylene terephthalate), poly(ethylene isophthalate), poly(butylene terephthalate), poly(2,6-dinaphthoate) and poly(ethylene 2,6-naphthalenedicarboxylate), and the clay is comprised of phyllosilicate consisted of an aluminum silicate or magnesium silicate layer, and a sodium or potassium ion filled between the phyllosilicate layer. The polyester/clay nanocomposite material is manufactured by the method comprising mixing a cyclic ester oligomer and an organic clay to obtain a mixture in which the cyclic ester oligomer is intercalated between the lamella structure of clay, and polymerizing the cyclic ester oligomer to release the lamella structure of clay greater than 50nm.
Abstract:
PURPOSE: A method for preparing a clay-dispersed olefin-based polymer nanocomposite and a polyolefin resin by using the nanocomposite are provided, to improve the tensile strength and the heat transformation temperature without deterioration of the transparency. CONSTITUTION: The method comprises the steps of dipping a catalyst for polymerization of olefin into clay, dipping a co-catalyst into clay, and polymerizing the olefin, wherein the clay is an organic treated clay having a functional group capable of a catalyst being supported to, the catalyst for polymerization of olefin is a Ziegler-Natta catalyst where chlorine or oxychloride is bonded with titanium or vanadium, and the co-catalyst is an organoaluminum. Preferably the clay is selected from the group consisting of montmorillonite, hectorite, saponite, sauconite, vermiculite, magadiite and kenyaite; the catalyst for polymerization of olefin is an organometal complex bonded with a metal selected from Zr, Ti, Ni and Pd; and the organoaluminum used as a co-catalyst is selected from (C2H5)3Al, (C2H5)2AlCl, (C2H5)AlCl2, (t-C4H9)3Al and (iso-C4H9)3Al.
Abstract translation:目的:提供一种通过使用该纳米复合材料制备粘土分散的烯烃基聚合物纳米复合材料和聚烯烃树脂的方法,以提高拉伸强度和热转变温度而不会使透明度劣化。 构成:该方法包括将用于烯烃聚合的催化剂浸渍到粘土中,将助催化剂浸渍到粘土中并使烯烃聚合的步骤,其中粘土是具有能够将催化剂负载的官能团的有机处理粘土 用于烯烃聚合的催化剂是其中氯或氯氧化物与钛或钒结合的齐格勒 - 纳塔催化剂,并且该助催化剂是有机铝。 优选地,粘土选自蒙脱石,锂蒙脱石,皂石,锌蒙脱石,蛭石,magadiite和肯纳石; 用于烯烃聚合的催化剂是与选自Zr,Ti,Ni和Pd的金属键合的有机金属配合物; 并且用作助催化剂的有机铝选自(C 2 H 5)3 Al,(C 2 H 5)2 AlCl,(C 2 H 5)AlCl 2,(tC 4 H 9)3 Al和(isoC 4 H 9)3 Al。
Abstract:
PURPOSE: A method for shielding electromagnetic interference waves by using form-in-place type electrically conductive silicone pastes is provided to be capable of finding a viscosity condition suitable for form-in-place of a paste having a very low volume resistivity. CONSTITUTION: An application-type silicon paste is formed to have the viscosity over 3000 Pa.s at the shear velocity below 0.1/sec and the viscosity over 100 Pa.s at the shear velocity below 100/sec and has a volume resistivity below 0.01 ohm.cm. The application-type silicon paste contains a conductive metal particle over 80 weight% and a silicon component below 20 weight%. The conductive metal particle is adjusted to have a diameter below 7 micrometers, a distribution degree over 4 and a shaping rate over 1.
Abstract:
PURPOSE: A method for preparing a clay-dispersed olefin-based polymer nanocomposite and a polyolefin resin by using the nanocomposite are provided, to improve the tensile strength and the heat transformation temperature without deterioration of the transparency. CONSTITUTION: The method comprises the steps of dipping a catalyst for polymerization of olefin into clay, dipping a co-catalyst into clay, and polymerizing the olefin, wherein the clay is an organic treated clay having a functional group capable of a catalyst being supported to, the catalyst for polymerization of olefin is a Ziegler-Natta catalyst where chlorine or oxychloride is bonded with titanium or vanadium, and the co-catalyst is an organoaluminum. Preferably the clay is selected from the group consisting of montmorillonite, hectorite, saponite, sauconite, vermiculite, magadiite and kenyaite; the catalyst for polymerization of olefin is an organometal complex bonded with a metal selected from Zr, Ti, Ni and Pd; and the organoaluminum used as a co-catalyst is selected from (C2H5)3Al, (C2H5)2AlCl, (C2H5)AlCl2, (t-C4H9)3Al and (iso-C4H9)3Al.
Abstract:
PURPOSE: A manufacturing method of carbon fiber reinforced C-shaped structure is provided to obtain a carbon fiber reinforced C-shaped structure having the improved physical property by winding plural one-directional carbon fiber prepreg units on a cylindrical roller. CONSTITUTION: A sheet of one-directional carbon fiber prepreg is sheared into a tape form and then cut at specific length to prepare plural sheets of one-directional carbon fiber prepreg units(11)(S1). The plural one-directional carbon fiber prepreg units are piled up and wound on a cylindrical roller to form a C-shaped or ring-shaped preform(13)(S2). The preform is wound up as taffeta or satin label prepreg(15)(S3). Then, the preform is heated in a compression mold having a vacuum device to obtain a C-shaped structure(S4). If the preform is molded in the compression mold, the inside of an outer fixing unit has not pores. Thereby, the physical property of the C-shaped structure is improved.