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公开(公告)号：KR101526690B1
公开(公告)日：2015-06-05
申请号：KR1020130119417
申请日：2013-10-07
Applicant: 현대자동차주식회사
Abstract: 본발명은고내열내충격성폴리유산복합재료조성물에관한것으로서, 더욱상세하게는광학이성질 L타입폴리유산(PLLA) 수지를기본수지로하고여기에광학이성질 D타입폴리유산(PDLA) 수지를특정조건으로가하고충격보강제, 핵제, 유리섬유등을혼합함으로써, 결정구조의변화를유발시켜서부품성형이후치수안정성이높고외관및 물성이우수한고내열내충격성폴리유산복합재료조성물에관한것이다.
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22.发明授权
公开(公告)号：KR101490951B1
公开(公告)日：2015-02-06
申请号：KR1020130119322
申请日：2013-10-07
Applicant: 현대자동차주식회사
Abstract: The present invention relates to a polymer resin composition for interior and exterior materials of vehicles, a molded resin article for interior and exterior materials of vehicles , and a method for preparing the same and, more specifically, to a polymer resin composition for interior and exterior materials of vehicles, which includes a polypropylene resin, a polylactic acid resin, glass fibers, a copolymer including an ethylene repeated unit and a (meth)acrylate-base repeated unit, and a sulfonic acid compound, and a molded resin article. The polymer resin composition and a molded resin article for interior and exterior materials of vehicles contain a certain content or more of a material derived from biomass, thereby being environmentally friendly and having the excellent mechanical properties such as the heat resistance and impact resistance.
Abstract translation: 本发明涉及一种车辆内外用材料用聚合物树脂组合物，车辆内外装饰用树脂成形体及其制造方法，更具体地，涉及内外用聚合物树脂组合物 包括聚丙烯树脂，聚乳酸树脂，玻璃纤维，包含乙烯重复单元和（甲基）丙烯酸酯基重复单元的共聚物）和磺酸化合物以及模制树脂制品的车辆材料。 聚合物树脂组合物和用于车辆内外装饰材料的树脂成型体含有一定量以上来源于生物质的材料，因此是环保的，具有优异的机械性能如耐热性和耐冲击性。
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公开(公告)号：KR1020140087536A
公开(公告)日：2014-07-09
申请号：KR1020120157953
申请日：2012-12-31
Applicant: 현대자동차주식회사
IPC: C07D319/10 , B01J6/00 , C07B61/00
CPC classification number: C07D319/12
Abstract: The present invention relates to a method for producing lactide using a solvent. In a second step when the lactide is produced, an ionic liquid is used as a solvent so that the mobility of a reactant is ensured. Then, reaction temperature is decreased and moisture generated during the reaction is absorbed from the ionic liquid, so that the lactide which is weak in the presence of moisture is not decomposed. In addition, the lactide can be continuously produced by continuously adding oligomers. The contamination of a reactor caused by a reaction by-product is minimized by means of the ionic liquid, and a solvent for washing the reactor is not needed. Furthermore, by means of the high boiling point of the ionic liquid, the ionic liquid can be easily collected and recycled.
Abstract translation: 本发明涉及使用溶剂制备丙交酯的方法。 在制备丙交酯的第二步中，使用离子液体作为溶剂，从而确保反应物的迁移率。 然后，反应温度降低，反应中产生的水分从离子液体吸收，使得在水分存在下弱的丙交酯不分解。 此外，丙交酯可以通过连续添加低聚物连续制备。 由反应副产物引起的反应器的污染通过离子液体被最小化，并且不需要用于洗涤反应器的溶剂。 此外，通过离子液体的高沸点，可以容易地收集和再循环离子液体。
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公开(公告)号：KR1020140048698A
公开(公告)日：2014-04-24
申请号：KR1020120114956
申请日：2012-10-16
Applicant: 현대자동차주식회사
Abstract: The present invention relates to a high heat dissipation polylactic acid composite material composition and a method of manufacturing the same, and more specifically, to a high heat dissipation polylactic acid composite material composition in which an L-polylactic acid resin, a D-polylactic acid resin, and a carbon fiber are mixed so that heat dissipation and mechanical properties are improved; has a low environmental load effect by replacing to a low-carbon-biomass based material instead of an existing general-purpose polymer resin; and can be used in various industrial material fields such as automobile parts, electronic equipment housing, etc. using the same, and a method of manufacturing the same. [Reference numerals] (AA) Carbon fiber (CNT growth on surface); (BB) Housing; (CC) Heat generating device
Abstract translation: 本发明涉及一种高散热聚乳酸复合材料组合物及其制造方法，更具体地说，涉及一种高散热聚乳酸复合材料组合物，其中L-聚乳酸树脂，D-聚乳酸 树脂和碳纤维混合，从而提高散热和机械性能; 通过替代低碳生物质材料而不是现有的通用聚合物树脂，具有低的环境负荷效应; 并且可以使用它们的各种工业材料领域，例如汽车部件，电子设备外壳等，及其制造方法。 （AA）碳纤维（表面CNT生长）; （BB）房屋; （CC）发热装置
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公开(公告)号：KR101326524B1
公开(公告)日：2013-11-07
申请号：KR1020120048680
申请日：2012-05-08
Applicant: 현대자동차주식회사
IPC: C08G63/78 , C08G63/08 , C07D319/12 , C08L67/04
Abstract: The present invention relates to a preparing method of lactide from a lactic acid at high yield. A low molecular weight polylactic acid is obtained by a polymerization reaction based on a D type lactic acid as a starting material and is thermally decomposed to manufacture D type lactide to obtain the D type lactide at high yield based on a simple method. The manufacturing costs of polylactic acid resin can be reduced using the D type lactide as the raw material of a D type polylactic acid. The lactide can be used for various uses such as vehicle engine, chassis parts, bioplastic, and display housing as biomass derived materials. [Reference numerals] (AA) Perform fermentation from biomass;(BB) Extract and separate D type lactic acid;(CC) Convert the D type lactic acid into D type lactide;(DD) Polymerize D type polylactic acid;(EE) Pulverize the polymer
Abstract translation: 本发明涉及以高产率从乳酸制备丙交酯的方法。 通过基于D型乳酸作为原料的聚合反应获得低分子量聚乳酸，并且通过简单的方法被热分解以制备D型丙交酯以获得高产率的D型丙交酯。 使用D型丙交酯作为D型聚乳酸的原料，可以降低聚乳酸树脂的制造成本。 丙交酯可用作各种用途，例如车辆发动机，底盘部件，生物塑料和显示器壳体作为生物质衍生材料。 （AA）从生物质进行发酵;（BB）提取和分离D型乳酸;（CC）将D型乳酸转化为D型丙交酯;（DD）聚合D型聚乳酸;（EE）粉碎 聚合物
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Patent Agency Ranking
公开(公告)号：KR101326521B1
公开(公告)日：2013-11-07
申请号：KR1020110050307
申请日：2011-05-26
Applicant: 현대자동차주식회사
IPC: C07D319/12 , C07C59/08
CPC classification number: C07D319/12
Abstract: 본 발명은 액상의 D타입 유산으로부터 D타입 락타이드를 제조하는 방법 및 제조된 D타입 락타이드로부터 중량평균 분자량 50,000 ~ 20,000g/mol의 D타입 폴리유산을 제조하는 방법에 관한 것이다.
본 발명의 방법은 기존의 제조 방법에 비해 간단한 공법으로 고수율의 D타입락타이드를 얻을 수 있는 장점이 있다. 결국 상기 D타입 락타이드로부터 최종적으로 얻어지는 D타입 폴리유산의 원가를 낮출 수 있는 장점이 있다.Abstract translation: 本发明涉及一种方法，用于生产d型锁定方法用于生产捆和具有d型丙交酯从在d式液体乳酸制备50000〜20000克/ mol的重均分子量d型聚乳酸。
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公开(公告)号：KR1020120131851A
公开(公告)日：2012-12-05
申请号：KR1020110050307
申请日：2011-05-26
Applicant: 현대자동차주식회사
IPC: C07D319/12 , C07C59/08
CPC classification number: C07D319/12
Abstract: PURPOSE: A method for preparing type D lactide from type D lactic acid of a liquid phase is provided to lower cost for preparing type D polylactic acid. CONSTITUTION: A method for preparing type D lactide comprises: a step of converting type D lactic acid into type D polylactic acid at 130-150 Deg. C. and a pressure of 10-200 torr; a step of heating the type D polylactic acid under a zinc oxide catalyst at 230-240 Deg. C. to convert the liquid phase into a gas phase stream; a step of cooling the gas phase stream at -78 Deg. C. to 10 Deg. C. and separating the gas phase stream into unreacted lactic acid and a mixture; a step of mixing the mixture and water and isolating type D lactide. [Reference numerals] (a) Reactor; (b) Mixture; (c) Lactic acid recycle; (d) Water; (e) Pure lactide
Abstract translation: 目的：提供一种从液相D型乳酸制备D型丙交酯的方法，以降低制备D型聚乳酸的成本。 构成：制备D型丙交酯的方法包括：将D型乳酸转化为130-150度的D型聚乳酸的步骤。 C.压力为10-200乇; 在氧化锌催化剂下以230-240度加热D型聚乳酸的步骤。 C.将液相转化成气相物流; 在-78度下冷却气相物流的步骤。 C.到10度 并将气相物流分离成未反应的乳酸和混合物; 将混合物和水混合并分离D型丙交酯的步骤。 （附图标记）（a）反应器; （b）混合物; （c）乳酸回收; （d）水; （e）纯丙交酯
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公开(公告)号：KR101583924B1
公开(公告)日：2016-01-08
申请号：KR1020140055411
申请日：2014-05-09
Applicant: 현대자동차주식회사
Abstract: 본발명은 (A) 폴리프로필렌수지 80 ~ 83 중량%; 및 (B) 폴리유산수지 17 ~ 20 중량%를포함하는베이스수지 100 중량부에대해, (C) 충격보강제 5 ~ 10 중량부; (D) 실란계화합물로표면처리한목분 8 ~ 15 중량부; 및 (E) 상용화제 3 ~ 5 중량부를포함하는것을특징으로하는폴리프로필렌-폴리유산복합재조성물및 이의제조방법을제공한다. 본발명은실란계화합물로표면처리한목분을포함함으로써, 베이스수지와의계면상호작용성을증대시켜최종복합재의기계적, 열적물성을향상시키는, 고내열, 내충격성, 인장강도및 굴곡강도등의물성밸런스가우수하여자동차내장재부품으로더욱적합하게사용될수 있다.
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公开(公告)号：KR101567173B1
公开(公告)日：2015-11-06
申请号：KR1020130165868
申请日：2013-12-27
Applicant: 현대자동차주식회사
IPC: C08L67/04 , C08K3/04 , C08K7/22 , C08L101/12 , H01B1/24
Abstract: 본발명은탄소나노튜브-스테레오콤플렉스폴리락트산복합재료에관한것으로, 폴리락트산스테레오콤플렉스결정을이용하여탄소나노튜브의연결성(conectivity)을향상시켜전도성물성을향상시킨복합재료인것이다. 본발명에따른복합재료는소량의탄소나노튜브로극대화된전기전도도효율을얻을수 있어전도성이필요한소재에다양하게활용될수 있다.
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公开(公告)号：KR1020150105095A
公开(公告)日：2015-09-16
申请号：KR1020140027310
申请日：2014-03-07
Applicant: 현대자동차주식회사
Abstract: 본 발명은 바이오 나일론-46과 석유계 나일론-6을 메트릭스 수지로 포함하고 있고, 유리섬유를 강화재로 포함하고 있음으로써 기존의 석유계 나일론 복합재에 대비하여 열적 및 기계적 물성이 보다 향상되는 효과를 나타내는 친환경 바이오 나일론 복합재에 관한 것이다. 본 발명의 바이오 나일론 복합재는 고 내열성 및 고 물성을 가지고 있음으로써, 현재 차량용 소재로 적용되는 석유계 나일론-6과 유리섬유로 된 복합재를 대체하여 사용할 수 있는 친환경 소재로 적합하다.
Abstract translation: 本发明涉及一种环保生物尼龙复合材料，包括生物尼龙46和基于石油的尼龙-6作为基体树脂，以及用于增强的玻璃纤维。 因此，与传统的石油基尼龙复合材料相比，本发明可以改善热和机械性能。 根据本发明的生物尼龙复合材料具有高的耐热性和优异的物理性能，可用作替代用作车辆材料并由石油基尼龙-6和玻璃纤维制成的复合材料的环境友好材料 。
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