公开(公告)号：CA2542994A1

公开(公告)日：2005-05-12

申请号：CA2542994

申请日：2004-10-28

Applicant: BASF AG

Inventor： SCHEIDEL JENS ,  LUYKEN HERMANN ,  SIEGEL WOLFGANG ,  HADERLEIN GERD ,  BAUMANN ROBERT ,  JUNGKAMP TIM ,  BARTSCH MICHAEL

IPC: B01J37/16 ,  B01J31/18 ,  B01J31/24 ,  B01J31/30 ,  C07C253/10 ,  C07C255/04 ,  C07F15/04

Abstract: The present invention provides a process for preparing nickel(0)-phosphorus ligand complexes starting from nickel(II)-ether adducts.

公开(公告)号：CA2542334A1

公开(公告)日：2005-05-12

申请号：CA2542334

申请日：2004-10-28

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  JUNGKAMP TIM ,  SIEGEL WOLFGANG ,  SCHEIDEL JENS

IPC: B01J37/16 ,  B01J31/18 ,  B01J31/24 ,  B01J31/30 ,  C07C253/10 ,  C07C255/04 ,  C07F15/04

Abstract: A process is described for preparing nickel(0)-phosphorus ligand complexes containing at least one nickel(0) central atom and at least one phosphorus ligand. The process comprises reducing a nickel(II) source comprising nickel bromide, nickel iodide or mixtures thereof in the presence of at least one phosphorus ligand.

公开(公告)号：BR0212966A

公开(公告)日：2004-10-13

申请号：BR0212966

申请日：2002-10-01

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  ALTMAYER MARCO ,  SIEGEL WOLFGANG ,  MOLNAR FERENC

IPC: B01J31/22 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/48

Abstract: Phosphonites I of the formula 1 or 2 where R1, R2 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that R1 and R2 are not simultaneously H, R3 is H or methyl, R4 is t-butyl, R5, R6, R7, R8, R9 are each, independently of one another, H or an alkyl or alkylene group having from 1 to 8 carbon atoms.

公开(公告)号：CA2518048A1

公开(公告)日：2004-09-23

申请号：CA2518048

申请日：2004-02-24

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  BARTSCH MICHAEL ,  LUYKEN HERMANN ,  BASSLER PETER ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  FLORES MIGUEL ANGEL ,  HADERLEIN GERD ,  JUNGKAMP TIM

IPC: C07C253/10 ,  C07C253/34 ,  C07C255/04

Abstract: The invention relates to a method for hydrocyanating an olefinically unsaturated nitrile in the presence of a catalyst that contains Ni(0). The inventive method is characterized in that the reaction is carried out in the presence of a hydrocarbon that, under certain pressure, concentration and temperature conditions, leads to the formation of at least two liquid phases of the overall system of which one phase, with regard to the overall weight of the phase, has a higher proportion of the catalyst containing Ni(0) than the other phase or other phases.

公开(公告)号：BR0114273A

公开(公告)日：2003-08-26

申请号：BR0114273

申请日：2001-09-25

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT ,  BASSLER PETER ,  SIEGEL WOLFGANG

IPC: C07C253/34 ,  C07C255/07

Abstract: A process is provided for the distillative separation of pentene nitrile isomers which have a relative volatility alpha ranging from 1.0 to 1.3 in the pressure range from 1 to 500 kPa, wherein the distillation is carried out in the presence of a liquid diluent which forms with the pentene nitrile isomers, under the same pressure conditions, azeotropes whose relative volatility alpha is higher than that of the pentene nitrile isomers to be separated.

公开(公告)号：CA2462720A1

公开(公告)日：2003-04-24

申请号：CA2462720

申请日：2002-10-04

Applicant: BASF AG

Inventor： HADERLEIN GERD ,  SIEGEL WOLFGANG ,  JUNGKAMP TIM ,  ALTMAYER MARCO ,  MOLNAR FERENC ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT ,  BARTSCH MICHAEL

IPC: B01J31/22 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/46 ,  C07F15/04 ,  C07F9/50

Abstract: The invention relates to phosphinites I of formulae (1) or (2) or (3) and mixtures thereof, in which Rl, R2, R4 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms, provided that at least one of the groups Rl, R2, R4 is different from H; R3 is H or methyl; X is F, Cl or CF3 and n is 0, 1 or 2.

公开(公告)号：CA2462719A1

公开(公告)日：2003-04-24

申请号：CA2462719

申请日：2002-10-01

Applicant: BASF AG

Inventor： ALTMAYER MARCO ,  SIEGEL WOLFGANG ,  MOLNAR FERENC ,  JUNGKAMP TIM ,  HADERLEIN GERD ,  BARTSCH MICHAEL ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT

IPC: B01J31/22 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/48

Abstract: Phosphonite I of formula l 1 or 2 wherein Rl and R2 independently represent hydrogen, an alkyl group or an alkene group having 1 - 8 carbon atoms, or an alkoxy group having 1-8 carbon atoms, with the proviso that RI and R2 are no t simultaneously H, R3 is H or methyl, R4 is t-butyl, R5, R6, R7, R8 and R9 independently represent H or an alkyl group or an alkylene group having 1 - 8 carbon atoms.

公开(公告)号：CA2423564A1

公开(公告)日：2003-03-24

申请号：CA2423564

申请日：2001-09-25

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  BASSLER PETER ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  JUNGKAMP TIM ,  SIEGEL WOLFGANG

IPC: C07C253/34 ,  C07C255/07

Abstract: The invention relates to a method for separating pentenenitrile isomers havi ng a relative volatility alpha in the region 1.0 - 1.3 in a pressure range of 1 - 500 kPa by means of separation. According to said method, the distillation i s carried out in the presence of a liquid diluent which forms azeotropes with the pentenenitrile isomers in the same pressure conditions, whose relative volatility alpha is higher than the pentenenitrile isomers which are to be separated.

公开(公告)号：CA2454912A1

公开(公告)日：2003-02-13

申请号：CA2454912

申请日：2002-07-16

Applicant: BASF AG

Inventor： SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  ALTMAYER MARCO ,  JUNGKAMP TIM

IPC: B01J31/22 ,  B01J23/755 ,  B01J31/18 ,  B01J31/24 ,  C07B61/00 ,  C07C253/10 ,  C07C255/04

Abstract: A catalyst system containing a) Ni (0), b) 4 -10 mol per mol Ni (0) accordin g to a) a compound (I) of formula P (X1R1) (X2R2) (X3R3) (I) wherein X1, X2, X 3 independently represent oxygen or a single bond R1, R2, R3 represent independently, the same or different organic radicals, and c) 1 -4 mol per m ol Ni (0) according to a) a compound (II) of formula (II) wherein X11, X12, X13 , X21, X22, X23 independnetly represent oxygen or a single bond, R11, R12 independently represent the same or different individual or bridged organic radicals, R21, R22 independently represent the same or different, individual or bridged organic radicals, Y represents a bridge group. The invention also relates to a method for the production of mixtures of monoolefin C5- mononitrils with a n-conjugated C=C and C=N bond by hydrocyanation of a hydrocarbon mixture containing 1,3-butadiene in the presence of at least one such system and to a method for the production of a dinitrile by hydrocyanation of a mixture of monoolefin C5-mononitriles with a non- conjugated C=C- and C=N bond in the presence of at least one such system.

公开(公告)号：DE10136488A1

公开(公告)日：2003-02-06

申请号：DE10136488

申请日：2001-07-27

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  KUNSMANN-KEITEL DAGMAR PSACA ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  ALTMAYER MARCO ,  SIEGEL WOLFGANG

IPC: B01J31/22 ,  B01J23/755 ,  B01J31/18 ,  B01J31/24 ,  C07B61/00 ,  C07C253/10 ,  C07C255/04 ,  C07B43/08

Abstract: A catalyst system comprises Ni(0) and phosphorous ligands. A catalyst system (I) comprises: (A) 1 mol Ni(0); (B) 4-10 mol of a compound of formula P(X R )(X R )(X R ) (1); and (C) 1-4 mol of a compound of formula (2); P(R -X )(R -X )-X -Y-X -P(X -R )(X -R ) (2); X ,X ,X ,X ,X ,X ,X , X ,X = oxygen or a single bond; R -R = organic groups; R ,R ,R ,R = single or bridged organic group; Y = bridging group. Independent claims are included for: (i) a process for the production of the system (I) by reaction of Ni(O) with a compound (B) in the presence of a liquid diluent; reaction of the resulting product with a compound (C) in the presence of a liquid diluent to yield the system (I); (ii) a process for the production of 5C-monoolefinic mononitrile having nonconjugated C=C and C=N bonds by hydrogenation of a 1,3-butadiene containing hydrocarbon mixture in the presence of a catalyst whereby the hydrocyanation is carried out in the presence of the catalyst system (I).