公开(公告)号：ES2092817T3

公开(公告)日：1996-12-01

申请号：ES93906587

申请日：1993-03-23

Applicant: BASF AG

Inventor： BURKHART BERND ,  OFTRING ALFRED ,  SCHWENDEMANN VOLKER ,  GLASER KLAUS

IPC: C07F9/54 ,  C25D3/12 ,  C25D3/14

Abstract: PCT No. PCT/EP93/00695 Sec. 371 Date Sep. 30, 1994 Sec. 102(e) Date Sep. 30, 1994 PCT Filed Mar. 23, 1993 PCT Pub. No. WO93/20087 PCT Pub. Date Oct. 14, 1993.Nickelized shaped articles are produced by electrodeposition of nickel from aqueous acidic baths containing as essential constituents one or more nickel salts, one or more inorganic acids and one or more brighteners by a procedure in which the brighteners used are phosphonium salts I (I) where R1 to R3 are each C1-C18-alkyl, which may be carboxyl-, C1-C4-alkoxycarbonyl- or cyano-substituted, C2-C12-alkenyl, C2-C12-alkynyl, C5-C8-cycloalkyl, C7-C12-phenylalkyl, phenyl, which may be substituted by one or two substituents selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy, halogen, hydroxyl, phenyl and C1-C4-alkoxycarbonyl, or mono- or di(C1-C4-alkyl)amino, R4 and R5 are each hydrogen or C1-C4-alkyl, A is hydrogen or a group of the formula -CO-H, -CO-R6, -CO-OH, -CO-OR6, -CO-CH2-CO-OR6, -O-CO-H, -O-CO-R6, -OR6, -SO2-R6, -SO2-OH, -SO2-OR6, -PO(OH)2, -PO(OH)(OR6), -PO(OR6)2, -OPO(OH)2, -OPO(OH)(OR6) or -OPO(OR6)2, where R6 is C1-C12-alkyl, C2-C12-alkenyl, C2-C12-alkynyl, C5-C8-cycloalkyl, C7-C12-phenylalkyl or phenyl, which may be substituted by one or two substituents selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy, halogen, hydroxyl, phenyl and C1-C4-alkoxycarbonyl, Y is -CH=CH- or -C=C-, m is from 0 to 10, n is from 1 to 4, p is 0 or 1, q is from 0 to 10, and X(-) is an n-valent inorganic or organic anion that promotes solubility in water.

公开(公告)号：DE59302278D1

公开(公告)日：1996-05-23

申请号：DE59302278

申请日：1993-05-05

Applicant: BASF AG

Inventor： BURKHART BERND ,  OFTRING ALFRED ,  WIDDER RUDI ,  SCHROEDER ULRICH

IPC: C07D215/10 ,  C07D213/20 ,  C07D217/10 ,  C23C18/00 ,  C25D3/12

Abstract: PCT No. PCT/EP93/01090 Sec. 371 Date Oct. 19, 1994 Sec. 102(e) Date Oct. 19, 1994 PCT Filed May 5, 1993 PCT Pub. No. WO93/23377 PCT Pub. Date Nov. 25, 1993A process for the preparation of N-allyl compounds of the general formula I I in which denotes a nitrogen-containing heterocyclic compound, R1, R3, and R4 independently denote hydrogen or C1-C4 alkyl, R2 denotes hydrogen or methyl, n is equal to 1, 2, 3, or 4, and X denotes a water-solubilizing anion, wherein a compound of formula II II is caused to react, in aqueous medium, with a compound of formula III III in which A denotes a radical which can be eliminated as an anion. The compounds produced by the process of the invention are very well suited for use as brighteners in nickel electroplating.

公开(公告)号：ES2075696T3

公开(公告)日：1995-10-01

申请号：ES92909336

申请日：1992-05-06

Applicant: BASF AG

Inventor： HAHN ERWIN ,  DUNG BERNHARD ,  BURKHART BERND ,  TSCHANG CHUNG-JI

IPC: C25D3/22 ,  C25D3/56

Abstract: PCT No. PCT/EP92/00983 Sec. 371 Date Nov. 9, 1993 Sec. 102(e) Date Nov. 9, 1993 PCT Filed May 6, 1992 PCT Pub. No. WO92/22683 PCT Pub. Date Dec. 23, 1992.The production of shining shaped articles coated with zinc or a zinc alloy by electrodeposition of zinc or a zinc alloy from acidic aqueous electrolytic baths which contain as essential components one or more zinc salts and, where appropriate, salts of the other alloy metals, one or more conducting salts, one or more surfactants and one or more brighteners, entails employing as brighteners compounds of the formula I I where R1 is C1-C8-alkoxy, phenoxy, benzyloxy, amino, C1-C6-alkylamino or di(C1-C6)alkylamino, R2 is C1-C4-alkyl, phenyl, benzyl or the meanings of R1, and Ar is phenyl or naphthyl which can additionally be substituted by one to three C1-C4-alkyl groups or C1-C4-alkoxy groups.

公开(公告)号：FR2744332B1

公开(公告)日：2003-09-19

申请号：FR9701289

申请日：1997-02-05

Applicant: BASF AG

Inventor： KOBER REINER ,  SCHNEIDER KARL HEINRICH ,  RADEMACHER WILHELM ,  STADLER REINHOLD ,  BURKHART BERND ,  OETTER GUNTER ,  GERBER MATTHIAS ,  NUYKEN WESSEL ,  SCHMIDT OSKAR ,  ZIEGLER HANS

IPC: A01N37/04 ,  A01N25/22 ,  A01N25/04

Abstract: A mixture consisting essentially of: a) one or more dicarboxylic acid esters of the formula I ROOC-A-COOR (I) in which the radicals R independently of one another are alkyl groups having 1 to 20 carbon atoms and A is alkylene having 1 to 20 carbon atoms, alkenylene or alkynylene each having 2 to 20 carbon atoms, cycloalkylidene or cycloalkenylidene each having 5 or 6 carbon atoms or phenylene and b) the product (II) of the reaction of a triglyceride based on carboxylic acids having 2 to 30 carbon atoms and ethylene oxide and/or propylene oxide in the presence of a base, which is useful for the production of crop protection compositions, for herbicidal crop protection compositions, and for controlling undesired plant growth, and spray mixtures comprising the compositions.

公开(公告)号：GB2309904B

公开(公告)日：1999-11-24

申请号：GB9702214

申请日：1997-02-04

Applicant: BASF AG

Inventor： KOBER REINER ,  SCHNEIDER KARL-HEINRICH ,  RADEMACHER WILHELM ,  STADLER REINHOLD ,  BURKHART BERND ,  OETTER GUENTER ,  GERBER MATTHIAS ,  NUYKEN WESSEL ,  SCHMIDT OSKAR ,  ZIEGLER HANS ,  KIBLER ELMAR ,  KROEHL THOMAS

IPC: A01N37/04 ,  A01N25/00

Abstract: A mixture consisting essentially of: a) one or more dicarboxylic acid esters of the formula I ROOC-A-COOR (I) in which the radicals R independently of one another are alkyl groups having 1 to 20 carbon atoms and A is alkylene having 1 to 20 carbon atoms, alkenylene or alkynylene each having 2 to 20 carbon atoms, cycloalkylidene or cycloalkenylidene each having 5 or 6 carbon atoms or phenylene and b) the product (II) of the reaction of a triglyceride based on carboxylic acids having 2 to 30 carbon atoms and ethylene oxide and/or propylene oxide in the presence of a base, which is useful for the production of crop protection compositions, for herbicidal crop protection compositions, and for controlling undesired plant growth, and spray mixtures comprising the compositions.

公开(公告)号：IT1289581B1

公开(公告)日：1998-10-15

申请号：ITMI970161

申请日：1997-01-29

Applicant: BASF AG

Inventor： KOBER REINER ,  SCHNEIDER KARL-HEINRICH ,  RADEMACHER WILHELM ,  STADLER REINHOLD ,  BURKHART BERND ,  OETTER GUNTER ,  GERBER MATTHIAS ,  NUYKEN WESSEL ,  SCHMIDT OSKAR ,  ZIEGLER HANS ,  KIBLER ELMAR ,  KROHL THOMAS

IPC: A01N37/04

Abstract: A mixture consisting essentially of: a) one or more dicarboxylic acid esters of the formula I ROOC-A-COOR (I) in which the radicals R independently of one another are alkyl groups having 1 to 20 carbon atoms and A is alkylene having 1 to 20 carbon atoms, alkenylene or alkynylene each having 2 to 20 carbon atoms, cycloalkylidene or cycloalkenylidene each having 5 or 6 carbon atoms or phenylene and b) the product (II) of the reaction of a triglyceride based on carboxylic acids having 2 to 30 carbon atoms and ethylene oxide and/or propylene oxide in the presence of a base, which is useful for the production of crop protection compositions, for herbicidal crop protection compositions, and for controlling undesired plant growth, and spray mixtures comprising the compositions.

公开(公告)号：FR2744332A1

公开(公告)日：1997-08-08

申请号：FR9701289

申请日：1997-02-05

Applicant: BASF AG

Inventor： KOBER REINER ,  SCHNEIDER KARL HEINRICH ,  RADEMACHER WILHELM ,  STADLER REINHOLD ,  BURKHART BERND ,  OETTER GUNTER ,  GERBER MATTHIAS ,  NUYKEN WESSEL ,  SCHMIDT OSKAR ,  ZIEGLER HANS

IPC: A01N37/04 ,  A01N25/22 ,  A01N25/04

Abstract: A mixture consisting essentially of: a) one or more dicarboxylic acid esters of the formula I ROOC-A-COOR (I) in which the radicals R independently of one another are alkyl groups having 1 to 20 carbon atoms and A is alkylene having 1 to 20 carbon atoms, alkenylene or alkynylene each having 2 to 20 carbon atoms, cycloalkylidene or cycloalkenylidene each having 5 or 6 carbon atoms or phenylene and b) the product (II) of the reaction of a triglyceride based on carboxylic acids having 2 to 30 carbon atoms and ethylene oxide and/or propylene oxide in the presence of a base, which is useful for the production of crop protection compositions, for herbicidal crop protection compositions, and for controlling undesired plant growth, and spray mixtures comprising the compositions.

公开(公告)号：DE59304205D1

公开(公告)日：1996-11-21

申请号：DE59304205

申请日：1993-03-23

Applicant: BASF AG

Inventor： BURKHART BERND ,  OFTRING ALFRED ,  SCHWENDEMANN VOLKER ,  GLASER KLAUS

IPC: C07F9/54 ,  C25D3/12 ,  C25D3/14

Abstract: PCT No. PCT/EP93/00695 Sec. 371 Date Sep. 30, 1994 Sec. 102(e) Date Sep. 30, 1994 PCT Filed Mar. 23, 1993 PCT Pub. No. WO93/20087 PCT Pub. Date Oct. 14, 1993.Nickelized shaped articles are produced by electrodeposition of nickel from aqueous acidic baths containing as essential constituents one or more nickel salts, one or more inorganic acids and one or more brighteners by a procedure in which the brighteners used are phosphonium salts I (I) where R1 to R3 are each C1-C18-alkyl, which may be carboxyl-, C1-C4-alkoxycarbonyl- or cyano-substituted, C2-C12-alkenyl, C2-C12-alkynyl, C5-C8-cycloalkyl, C7-C12-phenylalkyl, phenyl, which may be substituted by one or two substituents selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy, halogen, hydroxyl, phenyl and C1-C4-alkoxycarbonyl, or mono- or di(C1-C4-alkyl)amino, R4 and R5 are each hydrogen or C1-C4-alkyl, A is hydrogen or a group of the formula -CO-H, -CO-R6, -CO-OH, -CO-OR6, -CO-CH2-CO-OR6, -O-CO-H, -O-CO-R6, -OR6, -SO2-R6, -SO2-OH, -SO2-OR6, -PO(OH)2, -PO(OH)(OR6), -PO(OR6)2, -OPO(OH)2, -OPO(OH)(OR6) or -OPO(OR6)2, where R6 is C1-C12-alkyl, C2-C12-alkenyl, C2-C12-alkynyl, C5-C8-cycloalkyl, C7-C12-phenylalkyl or phenyl, which may be substituted by one or two substituents selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy, halogen, hydroxyl, phenyl and C1-C4-alkoxycarbonyl, Y is -CH=CH- or -C=C-, m is from 0 to 10, n is from 1 to 4, p is 0 or 1, q is from 0 to 10, and X(-) is an n-valent inorganic or organic anion that promotes solubility in water.

公开(公告)号：AU4065195A

公开(公告)日：1996-07-04

申请号：AU4065195

申请日：1995-12-21

Applicant: BASF AG

Inventor： WEHLAGE THOMAS ,  BURKHART BERND ,  OFTRING ALFRED ,  SCHRODER ULRICH ,  WIDDER RUDI

IPC: C07C45/74 ,  C07C67/343 ,  C07C67/30 ,  C07C67/317 ,  C07C231/12

公开(公告)号：BR9501924A

公开(公告)日：1996-03-05

申请号：BR9501924

申请日：1995-05-05

Applicant: BASF AG

Inventor： OFTRING ALFRED ,  BURKHART BERND ,  WEHLAGE THOMAS ,  DYLLICK-BRENZINGER RAINER ,  BECK KARIN HEIDRUN

IPC: C07D231/12 ,  C07D233/58 ,  G03G9/097 ,  C08K5/34 ,  C09K15/30 ,  C07D213/16

Abstract: Electrostatic toner contains a polymeric binder and, as charge stabiliser, a phenylacyl cpd. of formula (I): Het (+) - L - CD - Phe-R An (-) (I); Het (+) = a positively charged gp. derived from an heterocycle of the pyrazole, imidazole, pyridine, (iso)quinoline series; L = 1-8C alkylene; Phe = phenylene, opt. with an annelated benzene ring; R = H, OH, 1-4C alkoxy, NH2, 1-4C mono- or dialkylamino or an opt. substd. 1-6C alkyl, phenyl, phenoxy, mono- or diphenylamino or N-(1-4C alkyl)-N-phenyl-amino gp.; and An (-) = the equiv. of an anion. Also claimed is the use of (I) as charge stabiliser in electrostatic toners.