公开(公告)号：BG102027A

公开(公告)日：1998-08-31

申请号：BG10202797

申请日：1997-11-06

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM ,  FLICK KLEMENS

IPC: C07D201/08

Abstract: The method is used for the preparation of cyclic lactams inthe reaction between nitriles of aminocarboxylic acids and water.The cyclization occurs in liquid phase in the presence ofheterogeneous catalysts based on rutile-containing titaniumdioxide from 0.1 to 95 wt.%, and anatase from 99.9 to 5 wt.%,determined in respect of the total weight of the titanium dioxide,respectively.5 claims

公开(公告)号：ID18456A

公开(公告)日：1998-04-09

申请号：ID973147

申请日：1997-09-10

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FLICK KLEMENS ,  LUYKEN HERMANN ,  REHFINGER ALWIN ,  BASSLER PETER

IPC: C07B61/00 ,  B01J23/78 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07

Abstract: PCT No. PCT/EP97/04542 Sec. 371 Date Mar. 10, 1999 Sec. 102(e) Date Mar. 10, 1999 PCT Filed Aug. 21, 1997 PCT Pub. No. WO98/11051 PCT Pub. Date Mar. 19, 1998A process for coproduction of 6-aminocapronitrile and hexamethylenediamine starting from a mixture comprising a phosphorus-containing compound and essentially adiponitrile and obtained by reaction of butadiene with hydrocyanic acid in the presence of a catalyst comprising a phosphorus-containing compound comprises (1) reducing the weight proportion of phosphorus-containing compound, calculated as phosphorus, in the mixture, (2) partially hydrogenating the resulting mixture in the presence of a catalyst to form an alpha , omega -aminonitrile, and (3) removing 6-aminocapronitrile and hexamethylenediamine from the mixture.

公开(公告)号：CA2265513A1

公开(公告)日：1998-03-19

申请号：CA2265513

申请日：1997-09-01

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  EBEL KLAUS ,  FISCHER ROLF ,  VOIT GUIDO ,  MERGER MARTIN

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: Process for the manufacture of aliphatic alpha, omega amino nitriles by partial hydrogenation of aliphatic alpha, omega dinitriles in the presence of a catalyst, characterized by the fact that a catalyst is used for partial hydrogenation containing (a) iron or a compound based on iron or its mixtures and (b) 0.01 - 5 wt % related to (a) of a promotor on the basis of 2,3,4 or 5 elements selected from aluminium, silicon, zirconium, titanium and vanadium and (c) 0 - 5 wt % related to (a) of a compound based on an alkali metal or alkaline earth metal.

公开(公告)号：CA2263111A1

公开(公告)日：1998-03-19

申请号：CA2263111

申请日：1997-08-21

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  FISCHER ROLF ,  VOIT GUIDO ,  SCHNURR WERNER ,  EBEL KLAUS

IPC: B01J23/75 ,  B01J23/74 ,  B01J23/76 ,  B01J25/00 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24 ,  C07C255/25

Abstract: The invention concerns catalysts suitable for preparing aliphatic alpha-, omega-aminonitriles by partial hydrogenation of aliphatic dinitriles, containing: (a) metallic cobalt, a cobalt compound or their mixtures, the metallic cobalt portion being between 20 and 100 wt % relative to (a); (b) between 10 and 70 wt %, relative to (a), of metallic iron, iron oxide, a further iron compound or their mixtures, the iron oxide portion being between 20 and 100 wt % relative to (b); and (c) between 0 and 1 wt %, relative to (a), of a compound based on an alkali metal, alkaline earth metal or zinc.

公开(公告)号：MX9708676A

公开(公告)日：1998-02-28

申请号：MX9708676

申请日：1996-05-07

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM ,  FLICK KLEMENS

IPC: C07D201/08

Abstract: Las lactamas cíclicas se preparan mediante la reaccion de amino carbonitrilos con agua, en fase líquida, en presencia de catalizadores heterogéneos basados en dioxido de titanio con un contenido de rutilo en el rango desde 0.1 a 95 % por peso y un contenido de anatasa en el rango de 99.9 a 5 % por peso, en cada caso con base en el contenido total del dioxido de titanio.

公开(公告)号：BG101631A

公开(公告)日：1998-02-27

申请号：BG10163197

申请日：1997-06-17

Applicant: BASF AG

Inventor： MELDER JLHANN-PETER ,  SCHNURR WERNER ,  FLICK KLEMENS ,  EBEL KLAUS ,  WITZEL TOM ,  FISCHER ROLF ,  HARDER WOLFGANG ,  REHFINGER ALWIN

IPC: B01J23/89 ,  B01J23/76 ,  B01J23/889 ,  B01J27/18 ,  B01J37/02 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24

Abstract: The invention relates to the preparation of aliphatic-aminonitriles by partial hydrogenation of aliphatic dinitriles atelevated temperature and higher pressure, in the presence of asolvent and catalyst. Catalyst, containing the following is used:(a) compound based on metal, e.g. nickel, cobalt, iron, rutheniumand rhodium; (b) from 0.01 to 25 wt.% promotor to component (a)based on metal such as palladium, platinum, iridium, osmium,copper, silver, gold, chromium, molybdenum, tungsten, manganese,rhenium, zinc, cadmium, lead, aluminium, tin, phosphorus, arsenic,antimony, bismith, silicon, titanium, zirconium and the rare earthelements, and (c) from 0 to 5 wt.% compound to component (a) basedon alkali or alkaliearth metal, provided that component (a) isdifferent from an iron-based compound or from iron, as well asfrom the metals cobalt, ruthenium or rhodium when component (b) ispromotor based on a metal from the group containing titanium,managanese, chromium and molybdenum. An additional condition isthat when component (a) is a compound based on ruthenium orrhodium separately, or of ruthenium and rhodium, or of nickel andrhodium, promotor (b) can optionally be dropped.

公开(公告)号：CA2261614A1

公开(公告)日：1998-02-05

申请号：CA2261614

申请日：1997-07-29

Applicant: BASF AG

Inventor： FISCHER ROLF ,  FLICK KLEMENS ,  VOIT GUIDO ,  SCHNURR WERNER

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B43/04 ,  C07B61/00 ,  C07C20060101 ,  C07C209/48 ,  C07C209/52 ,  C07C211/12 ,  C07C211/35 ,  C07C253/30 ,  C07C255/24

Abstract: The invention concerns the production of compounds containing NH2-groups by hydrogenating compounds containing at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures not below room temperature and under increased hydrogen partial-pressure, preferably in the presence of a solvent, in which one (a) uses a cobalt and/or ironcontaining catalyst, and (b), after conversion of the compound to be hydrogenated and/or the selectivity of the product desired drops below a defined value, or after an increase in the quantity of an undesired by-product beyond a defined value, one breaks off the hydrogenation by stopping the supply of the compounds to be hydrogenated and, if desired, of any solvents present, (c) one treats the catalyst with hydrogen at a temperature between 150 to 400 ~C and a hydrogen pressure between 0.1 to 30 MPa and selects a treatment time of 2 to 48 hours, and (d) one subsequently continues the hydrogenation of a least one compound containing an unsaturated carbonnitrogen bond as well as the regeneration of cobalt and/or iron-containing catalysts.

公开(公告)号：BR9510109A

公开(公告)日：1997-11-25

申请号：BR9510109

申请日：1995-12-16

Applicant: BASF AG

Inventor： MELDER JOHANN-PETER ,  SCHNURR WERNER ,  FLICK KLEMENS ,  EBEL KLAUS ,  WITZEL TOM ,  FISCHER ROLF ,  HARDER WOLFGANG ,  REHFINGER ALWIN

IPC: B01J23/89 ,  B01J23/76 ,  B01J23/889 ,  B01J27/18 ,  B01J37/02 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24

Abstract: Aliphatic alpha,omega-aminonitriles are prepared by partial hydrogenation of aliphatic alpha,omega-dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst by a process which comprises using a catalyst which (a) contains a compound based on a metal selected from the group consisting of nickel, cobalt, iron, ruthenium and rhodium and (b) contains from 0.01 to 25% by weight, based on (a), of a promoter based on a metal selected from the group consisting of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminum, tin, phosphorus, arsenic, antimony, bismuth and rare earth metals and (c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or on an alkaline earth metal. with the proviso that the component (a) is not based on iron or iron and one of the metals selected from the group consisting of cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group consisting of titanium, manganese, chromium and molybdenum, and with the further proviso that, when a compound based on only ruthenium or rhodium or ruthenium and rhodium or nickel and rhodium is selected as component (a), the promoter (b) may be dispensed with.

公开(公告)号：PL321062A1

公开(公告)日：1997-11-24

申请号：PL32106295

申请日：1995-12-16

Applicant: BASF AG

Inventor： VICARI MAXIMILIAN ,  FLICK KLEMENS ,  MELDER JOHANN-PETER ,  SCHNURR WERNER ,  WULFF-DOERING JOACHIM

IPC: B01J25/00 ,  B01J25/02 ,  B01J37/00 ,  C07B31/00 ,  C07C253/30

Abstract: A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.

公开(公告)号：NO975268D0

公开(公告)日：1997-11-17

申请号：NO975268

申请日：1997-11-17

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM ,  FLICK KLEMENS

IPC: C07D201/08

Abstract: Production of cyclic lactams by the reaction of amino carboxylic acid nitriles with water, performed in the liquid phase in the presence of heterogeneous catalysts based on titanium dioxide with a rutile content in the range from 0.1 to 95 wt.% and an anatase content in the range from 99.9 to 5 wt.% in relation to the total titanium dioxide content.