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21.
公开(公告)号:ES2219310T3
公开(公告)日:2004-12-01
申请号:ES00906246
申请日:2000-01-29
Applicant: BASF AG
Inventor: FUNK RUDIGER , HERFERT NORBERT , WANIOR MARIOLA , BROWN PATRICIA D , ENGELHARDT FRIEDRICH , WOODRUM GUY T
IPC: A61F13/53 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/60 , B01J20/26 , B01J20/30 , C08F8/00 , C08F20/06 , C08F20/58 , C08F22/02 , C08F22/38 , C08F28/02 , C08F220/04 , C08F291/00 , C08J3/12 , C08J3/24 , C08F220/06 , A61L15/00
Abstract: Hidrogel altamente hinchable, hidrófilo y reticulado a base de monómeros polimerizados o a base de polímeros de injerto, caracterizado porque muestra un Pressure Absorbency Index
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公开(公告)号:AU2003212299A1
公开(公告)日:2003-09-22
申请号:AU2003212299
申请日:2003-03-04
Applicant: BASF AG
Inventor: FUNK RUDIGER , WANIOR MARIOLA , ENGELHARDT FRIEDRICH
IPC: A61F13/49 , A61F5/441 , A61F13/15 , A61F13/20 , A61F13/472 , A61F13/53 , A61L15/60 , C08F265/00 , C08J3/20 , C08L33/02 , C08L33/08 , C08L35/06 , C08L51/00 , C08L51/02 , C08L33/00
Abstract: The present invention relates to polymer mixtures including hydrogel-forming polymers capable of absorbing aqueous fluids and prepared by polymerization of olefinically unsaturated carboxylic acids or derivatives thereof together with copolymers of C 2 -C 8 olefins or styrenes with anhydrides and also their preparation, use and hygiene articles which include same.
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23.
公开(公告)号:AU2003244473A1
公开(公告)日:2003-09-02
申请号:AU2003244473
申请日:2003-01-30
Applicant: BASF AG
Inventor: CHAMP SAMANTHA , HAHNLE HANS-JOACHIM , BECK MARTIN , FUNK RUDIGER
IPC: A61F13/53 , A61F13/00 , A61F13/15 , A61F13/49 , A61L15/00 , C08J9/12 , C08J9/28 , C08J9/30 , C08K3/00 , C08K5/00 , C08L101/14
Abstract: Foams composed of water-absorbing basic polymers, obtainable by (I) foaming a crosslinkable aqueous mixture including (a) at least one basic polymer whose basic groups have optionally been neutralized, (b) at least one crosslinker, (c) at least one surfactant, (d) optionally at least one solubilizer, (e) optionally thickeners, foam stabilizers, fillers, fibers and/or cell nucleators, and (f) optionally particulate water-absorbing acidic polymers, by dissolving a gas which is inert toward free radicals in the crosslinkable aqueous mixture under a pressure from 2 to 400 bar and subsequently decompressing the crosslinkable aqueous mixture to atmospheric or by dispersing fine bubbles of a gas which is inert toward free radicals, and (II) crosslinking the foamed mixture to form a hydrogel foam and if applicable adjusting the water content of the polymer foam to 1-60% by weight. Preparation of the foams by application of the abovementioned measures (I) and (II) and use of the thus obtainable foams in hygiene articles to absorb body fluids, in dressing material to cover wounds, as a sealing material, as a packaging material, as a soil improver, as a soil substitute, to dewater sludges, to absorb aqueous acidic wastes, to thicken waterborne paints or coatings in the course of disposing of residual quantities thereof, to dewater water-containing oils or hydrocarbons or as a material for filters in ventilation systems.
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公开(公告)号:AU2003244472A1
公开(公告)日:2003-09-02
申请号:AU2003244472
申请日:2003-01-30
Applicant: BASF AG
Inventor: HAHNLE HANS-JOACHIM , FUNK RUDIGER , HEIDER WOLFGANG , SCHORNICK GUNNAR , FRENZ VOLKER
IPC: A61F13/53 , A61F13/00 , A61F13/49 , A61L15/16 , A61L15/60 , C08F6/00 , C08J9/00 , C08J9/36 , C08L101/14 , C08F6/10
Abstract: A process for the reduction of the residual monomer content and enhancement of the wet strength of articles formed from water absorbent crosslinked polymer foams containing units derived from monoethylenically unsaturated acids, which comprises treating the formed articles with at least 0.5% by weight of a polymer containing primary and/or secondary amino groups and having a molar mass of at least 300, the formed foam articles thus obtainable and use of the wet strength enhanced formed foam articles in hygiene articles.
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公开(公告)号:AU1232502A
公开(公告)日:2002-04-29
申请号:AU1232502
申请日:2001-10-17
Applicant: BASF AG
Inventor: FRENZ VOLKER , HERFERT NORBERT , WEISMANTEL MATTHIAS , RIEGEL ULRICH , ENGELHARDT FRIEDRICH , FUNK RUDIGER
IPC: A61L15/60 , C08F220/04 , C08F271/02
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26.
公开(公告)号:CA2361577A1
公开(公告)日:2000-08-10
申请号:CA2361577
申请日:2000-01-29
Applicant: BASF AG
Inventor: BROWN PATRICIA D , WOODRUM GUY T , ENGELHARDT FRIEDRICH , FUNK RUDIGER , HERFERT NORBERT , WANIOR MARIOLA
IPC: A61F13/53 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/60 , B01J20/26 , B01J20/30 , C08F8/00 , C08F20/06 , C08F20/58 , C08F22/02 , C08F22/38 , C08F28/02 , C08F220/04 , C08F291/00 , C08J3/12 , C08J3/24 , C08F220/06 , A61L15/00
Abstract: The invention relates to cross-linked, hydrophilic highly swellable hydrogel s on the basis of polymerized monomers or on the basis of graft polymers that have a pressure absorbency index of ~100 and a vertical absorption under a pressure of 1922.8 Pa of at least 12 g/g. The invention further relates to a method for producing such hydrogels by radical polymerization of hydrophilic monomers containing acidic groups, their alkali metal or ammonium salts with (a) a copolymerization cross-linking agent which contains at least two ethylenically unsaturated double bonds in the molecule, and (b) with a reactive cross-linking agent A which has an ethylenically unsaturated double bond and at least one functional group that forms covalent bonds with the acidic groups of the hydrophilic polymers, a reactive cross-linking agent B which has at least two functional groups that form covalent bonds with the acidic groups of the hydrophilic polymers, and/or with ions of polyvalent alcohols, optionally in the presence of at least one graft base, to give a cross-linked, hydrophilic base polymer, reducing the base polymer in size an d subjecting the surface of the particles of the base polymer to a secondary cross-linking step. The invention further relates to the use of the highly swellable hydrogels as absorption agents for water and aqueous liquids.
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公开(公告)号:CA2320778A1
公开(公告)日:1999-08-26
申请号:CA2320778
申请日:1999-02-19
Applicant: BASF AG
Inventor: WEISMANTEL MATTHIAS , ENGELHARDT FRIEDRICH , DANIEL THOMAS , RIEGEL ULRICH , FRENZ VOLKER , FUNK RUDIGER
IPC: C07D263/20 , A61L15/00 , A61L15/60 , C08F8/30
Abstract: The invention relates to a method for the gel-phase or surface secondary crosslinking of water-absorbent polymers, characterized in that the polymer is treated with a solution for surface secondary cross-linking, during or after treatment undergoes secondary cross-linking by temperature elevation and is then dried. Dissolved in an inert solvent the cross-linking agent contains a compound of formula (I), where R1 and R2 independently of each other are H, hydroxy, phenyl or C1-C6-alkyl, R3 is hydrogen, C1-C12-alkyl, C1-C12-alkenyl or C6-C12-aryl and R4 and R5 independently of each other are C1-C12-alkyl, C1C12-alkenyl, C6-C12-aryl, hydroxy, C1-C12-alkoxy or hydrogen. The invention also relates to water-absorbent polymers obtained according to the above method, and to their use in hygiene articles, packaging materials and nonwoven materials.
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公开(公告)号:CA2319457A1
公开(公告)日:1999-08-26
申请号:CA2319457
申请日:1999-02-19
Applicant: BASF AG
Inventor: FRENZ VOLKER , FUNK RUDIGER , ENGELHARDT FRIEDRICH , STUVEN UWE , DANIEL THOMAS
IPC: A61L15/00 , A61L15/60 , C08F8/40 , C08J3/24 , D06M15/263
Abstract: The invention relates to a method for the surface secondary cross-linking of water-absorbent polymers, according to which the polymer is sprayed with a solution for surface secondary cross-linking. As cross-linking agent said solution contains phosphoric acid esters of the formula (1) or (2), where X is OH or NH2 and R is C1-C12 alkylene, or a mixture of such esters dissolved in an inert solvent. The moist product during or after spraying is subjected to secondary cross-linking and dried by raising the temperature to 50-250 ~C. The invention also relates to water-absorbent polymers obtainable in accordance with the above method and to their use in hygiene articles, packing materials and non-woven materials.
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公开(公告)号:ES2266783T3
公开(公告)日:2007-03-01
申请号:ES03708172
申请日:2003-03-04
Applicant: BASF AG
Inventor: ENGELHARDT FRIEDRICH , FUNK RUDIGER , WANIOR MARIOLA
IPC: A61F13/49 , C08L33/00 , A61F5/441 , A61F13/15 , A61F13/20 , A61F13/472 , A61F13/53 , A61L15/24 , A61L15/60 , C08F265/00 , C08J3/20 , C08L23/00 , C08L33/02 , C08L33/08 , C08L35/06 , C08L51/00 , C08L51/02
Abstract: Mezclas de polímeros que contienen los componentes (i) de los polímeros formadores de hidrogel que absorben líquidos acuosos, elaborados mediante polimerización de ácidos carboxílicos olefínicamente insaturados o sus derivados, y los componentes (ii) de copolímeros de olefinas de 2 hasta 8 átomos de carbono o de estirenos con anhídridos, cuya relación molar entre olefinas de 2 hasta 8 átomos de carbono o de estireno y anhídrido es de 3 a 1 y de 1 a 3.
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公开(公告)号:MY124251A
公开(公告)日:2006-06-30
申请号:MYPI9900614
申请日:1999-02-22
Applicant: BASF AG
Inventor: FUNK RUDIGER , FRENZ VOLKER , RIEGEL ULRICH , WEISMANTEL MARTHIAS , ENGELHARDT FRITZ , DANIEL THOMAS
IPC: C07D263/20 , C08F8/30 , A61L15/00 , A61L15/60
Abstract: THE INVENTION RELATES TO A PROCESS FOR THE GEL OR SURFACE POSTCROSSLINKING OF WATER- ABSORBING POLYMERS IN WHICH THE POLYMERS ARE TREATED WITH A SURFACE POSTCROSSLINKING SOLUTION AND DURING OR AFTER THE TREATMENT ARE POSTCROSSLINKED AND DRIED BY MEANS OF AN INCREASE IN TEMPERATURE, THE CROSSLINKER BEING A COMPOUND OF THE FORMULA IN WHICH R1 AND R2 INDEPENDENTLY OF ONE ANOTHER ARE H , HYDROXYL, PHENYL OR C1-C6- ALKYL, R3 IS HYDROGEN. C1-C12- ALKYL , C1-C12- ALKYL, C1-C12- ALKENYL OR C6-C12-ARYL AND R4 AND R5 INDEPENDENTLY OF ONE ANOTHER ARE C1-C12- ALKYL, C1-C12- ALKENYL, C6-C12- ARYL, HYDROXYL, C1-C12- ALKOXY OR HYDROGEN, DISSOLVED IN AN INERT SOLVENT, TO WATER- ABSORBING POLYMERS WHICH CAN BE OBTAINED BY SAID PROCESS, AND TO THEIR USE IN HYGIENE ARTICLES, PACKAGING MATERIALS AND NONWOVENS.
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