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    22.
    发明专利
    未知

    公开(公告)号：ES2133598T3

    公开(公告)日：1999-09-16

    申请号：ES95101741

    申请日：1995-02-09

    Applicant: BASF AG

    Inventor： MARTIN FRIEDRICH-GEORG DR ,  HIBST HARTMUT DR ,  TENTEN ANDREAS DR

    IPC: C01G1/00 ,  B01J23/88 ,  B01J23/885 ,  B01J27/14 ,  B01J27/195 ,  B01J27/199 ,  B01J35/00 ,  C01G1/02 ,  C01G39/00 ,  C07B61/00 ,  C07C51/25 ,  C07C57/055

    Abstract: Multimetal oxide compsn. of formula (I) is new: (A)p(B)q(I): A = Mo12X aX bX cX dSeX fO x; B = X 12CugX hOy; X = P, As, B, Ge and/or Si; X = V, Nb and/or W; X = H, up to 97 mole-% of which may be replaced by K, Rb, Cs and/or NH4; X = Sb and/or Bi; X = Re and/or Rh; X = Mp, W, Nb and/or Ta; X = Li, Na, K, Rb, Cs and/or NH4; a = 1-6; b, d = 0-6; c = 3-5; e, f = 0-3; g = 4-24; h = 0-20; x, y = values depending on the valency and content of elements other than O; p, q = values other than O, with the ratio p/q = 12:0.1 to 12:48. The A and B fractions are each in the form of 3D zones, which differ in chemical compsn. from their local surroundings, and the relative distribution of the A and B zones is as in a mixt. of finely-divided A and finely-divided B.

    26.
    发明专利
    未知

    公开(公告)号：DE59401158D1

    公开(公告)日：1997-01-09

    申请号：DE59401158

    申请日：1994-09-06

    Applicant: BASF AG

    Inventor： HARTH KLAUS DR ,  HIBST HARTMUT DR ,  MATTMANN WOLFGANG DR

    IPC: B01J19/08 ,  B01J2/00 ,  C23C16/44 ,  C23C16/442 ,  C23C16/452 ,  C23C16/50 ,  C23C16/511

    Abstract: Coating of solid particles in a fluidised bed by application of a gaseous coating agent from a plasma, wherein the plasma is generated outside the fluidised bed at a pressure of 0.01 to 500 mbar, and the plasma-activated gas is passed into the fluidised bed which is operated at a pressure of 0.1 to 500 mbar, where a. the plasma is generated from the total amount of gaseous coating agent with or without another gas, or b. the plasma is generated from a portion of the gaseous coating agent with or without another gas, and the remaining portion is introducd directly into the fluidised bed, or c. the plasma is generated from another gas, and the total amount of gaseous coating agent is introduced directly into the fluidised bed.

    27.
    发明专利
    未知

    公开(公告)号：AT145675T

    公开(公告)日：1996-12-15

    申请号：AT94113922

    申请日：1994-09-06

    Applicant: BASF AG

    Inventor： HARTH KLAUS DR ,  HIBST HARTMUT DR ,  MATTMANN WOLFGANG DR

    IPC: B01J19/08 ,  B01J2/00 ,  C23C16/44 ,  C23C16/442 ,  C23C16/452 ,  C23C16/50 ,  C23C16/511

    Abstract: Coating of solid particles in a fluidised bed by application of a gaseous coating agent from a plasma, wherein the plasma is generated outside the fluidised bed at a pressure of 0.01 to 500 mbar, and the plasma-activated gas is passed into the fluidised bed which is operated at a pressure of 0.1 to 500 mbar, where a. the plasma is generated from the total amount of gaseous coating agent with or without another gas, or b. the plasma is generated from a portion of the gaseous coating agent with or without another gas, and the remaining portion is introducd directly into the fluidised bed, or c. the plasma is generated from another gas, and the total amount of gaseous coating agent is introduced directly into the fluidised bed.

    Multi:metal oxide useful as catalyst esp. in gas phase oxidn. of acrolein to acrylic acid
    30.
    发明专利
    Multi:metal oxide useful as catalyst esp. in gas phase oxidn. of acrolein to acrylic acid 未知

    公开(公告)号：DE4405514A1

    公开(公告)日：1995-08-24

    申请号：DE4405514

    申请日：1994-02-22

    Applicant: BASF AG

    Inventor： TENTEN ANDREAS DR ,  HIBST HARTMUT DR ,  MARTIN FRIEDRICH-GEORG DR ,  MAROSI LASZLO DR ,  KOHL VERONIKA DR

    IPC: B01J23/00 ,  B01J23/885 ,  B01J23/887 ,  B01J35/00 ,  C07C51/25 ,  C07C57/055 ,  C01G39/02 ,  B01J23/72

    Abstract: Multimetal oxide compsn. of formula (I) is new: (A)p (B)q (I): A = Mo12VaX bX cX dX eX fX gOx (co-phase); B = X 12CuhHiOy (key phase); X = W, Nb, Ta, Cr and/or Ce; X = Cu, Ni, Co, Fe, Mn and/or Zn; X = Sb and/or Bi; X = Li, Na, K, Rb, Cs and/or H; X = Mg, Ca, Sr and/or Ba; X = Si, Al, Ti and/or Zr; X = Mo, W, V, Nb and/or Ta; a = 1-8; b = 0.2-5; c = 0-23; d, g = 0-50; e = 0-2; f = 0-5; h = 4-30; i = 0-20; x, y = values depending on the valency and content of elements other than O; p, q = values other than O, with the ratio p/q = 160:1 to 1:1. The A and B fractions are each in the form of 30 zones, which differ in chemical compsn. from their local surroundings, and the relative distribution of the A and B zones is as in a mixt. of finely-divided A and finely-divided B. Also claimed are multimetal oxide compsns. of wolframite structural type, of formulae (II), (III), (IV) and (V): in (II), 1/(A+B+C+D+E) = 0.7-1.3; F = 0-1; and B+C+D+E = over 0 to 1. In (III), 1/(A+B+C) = 0.7-1.3; A, B, C all = more than O and B+C = at most 1; In (IV), 1/(A+B) = 0.7-1.3; A, B both = more than O and B = at most 1; In (V), 1/(A+C) = 0.7-1.3; A, C both - more than O and C - at most 1.

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