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    Multi:metal oxide useful as catalyst esp. in gas phase oxidn. of acrolein to acrylic acid
    2.
    发明专利
    Multi:metal oxide useful as catalyst esp. in gas phase oxidn. of acrolein to acrylic acid 未知

    公开(公告)号：DE4440891A1

    公开(公告)日：1996-05-23

    申请号：DE4440891

    申请日：1994-11-17

    Applicant: BASF AG

    Inventor： TENTEN ANDREAS DR ,  HIBST HARTMUT DR ,  MARTIN FRIEDRICH-GEORG DR ,  MAROSI LASZLO DR ,  KOHL VERONIKA DR

    IPC: B01J23/00 ,  B01J23/885 ,  B01J23/887 ,  B01J35/00 ,  C07C51/25 ,  C07C57/055 ,  C01G1/02 ,  B01J21/00 ,  C01G39/00 ,  C01G41/00

    Abstract: Multimetal oxide compsn. of formula (I) is new: (A)p (B)q (I): A = Mo12VaX bX cX dX eX fX gOx (co-phase); B = X 12CuhHiOy (key phase); X = W, Nb, Ta, Cr and/or Ce; X = Cu, Ni, Co, Fe, Mn and/or Zn; X = Sb and/or Bi; X = Li, Na, K, Rb, Cs and/or H; X = Mg, Ca, Sr and/or Ba; X = Si, Al, Ti and/or Zr; X = Mo, W, V, Nb and/or Ta; a = 1-8; b = 0.2-5; c = 0-23; d, g = 0-50; e = 0-2; f = 0-5; h = 4-30; i = 0-20; x, y = values depending on the valency and content of elements other than O; p, q = values other than O, with the ratio p/q = 160:1 to 1:1. The A and B fractions are each in the form of 30 zones, which differ in chemical compsn. from their local surroundings, and the relative distribution of the A and B zones is as in a mixt. of finely-divided A and finely-divided B. Also claimed are multimetal oxide compsns. of wolframite structural type, of formulae (II), (III), (IV) and (V): in (II), 1/(A+B+C+D+E) = 0.7-1.3; F = 0-1; and B+C+D+E = over 0 to 1. In (III), 1/(A+B+C) = 0.7-1.3; A, B, C all = more than O and B+C = at most 1; In (IV), 1/(A+B) = 0.7-1.3; A, B both = more than O and B = at most 1; In (V), 1/(A+C) = 0.7-1.3; A, C both more than O and C at most 1.

    Multi:metal oxide useful as catalyst esp. in gas phase oxidn. of acrolein to acrylic acid
    7.
    发明专利
    Multi:metal oxide useful as catalyst esp. in gas phase oxidn. of acrolein to acrylic acid 未知

    公开(公告)号：DE4405514A1

    公开(公告)日：1995-08-24

    申请号：DE4405514

    申请日：1994-02-22

    Applicant: BASF AG

    Inventor： TENTEN ANDREAS DR ,  HIBST HARTMUT DR ,  MARTIN FRIEDRICH-GEORG DR ,  MAROSI LASZLO DR ,  KOHL VERONIKA DR

    IPC: B01J23/00 ,  B01J23/885 ,  B01J23/887 ,  B01J35/00 ,  C07C51/25 ,  C07C57/055 ,  C01G39/02 ,  B01J23/72

    Abstract: Multimetal oxide compsn. of formula (I) is new: (A)p (B)q (I): A = Mo12VaX bX cX dX eX fX gOx (co-phase); B = X 12CuhHiOy (key phase); X = W, Nb, Ta, Cr and/or Ce; X = Cu, Ni, Co, Fe, Mn and/or Zn; X = Sb and/or Bi; X = Li, Na, K, Rb, Cs and/or H; X = Mg, Ca, Sr and/or Ba; X = Si, Al, Ti and/or Zr; X = Mo, W, V, Nb and/or Ta; a = 1-8; b = 0.2-5; c = 0-23; d, g = 0-50; e = 0-2; f = 0-5; h = 4-30; i = 0-20; x, y = values depending on the valency and content of elements other than O; p, q = values other than O, with the ratio p/q = 160:1 to 1:1. The A and B fractions are each in the form of 30 zones, which differ in chemical compsn. from their local surroundings, and the relative distribution of the A and B zones is as in a mixt. of finely-divided A and finely-divided B. Also claimed are multimetal oxide compsns. of wolframite structural type, of formulae (II), (III), (IV) and (V): in (II), 1/(A+B+C+D+E) = 0.7-1.3; F = 0-1; and B+C+D+E = over 0 to 1. In (III), 1/(A+B+C) = 0.7-1.3; A, B, C all = more than O and B+C = at most 1; In (IV), 1/(A+B) = 0.7-1.3; A, B both = more than O and B = at most 1; In (V), 1/(A+C) = 0.7-1.3; A, C both - more than O and C - at most 1.

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