公开(公告)号：DE10005794A1

公开(公告)日：2001-08-16

申请号：DE10005794

申请日：2000-02-10

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  ROEPER MICHAEL ,  HOFMANN PETER ,  WARTH DANIEL CHRISTIAN MARKUS

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C07B37/12 ,  C07C2/50 ,  C07C13/44 ,  C07C13/64 ,  C07C13/68 ,  C07C45/50 ,  C07C51/14 ,  C07C253/10 ,  C07F9/46 ,  C07F9/50 ,  C07F9/6561 ,  C07F9/6571 ,  C07F9/6574 ,  C07F15/00 ,  C07F15/04 ,  C07F15/06 ,  C08F4/42 ,  C07F9/66 ,  C07F9/92 ,  C07B35/02 ,  C07C2/08 ,  C07C6/00

Abstract: Diaryl-anellated bicyclo[2.2.n] compounds (I) containing phosphorus, arsenic and/or antimony are new. Diaryl-anellated bicyclo[2.2.n] compounds of formula (I), containing phosphorus, arsenic and antimony, are new: [Image] A 1>, A 2>boron (B), nitrogen (N), phosphorus (P) or CR 5>; R 5>hydrogen (H), (cyclo)alkyl or (het)aryl; X : oxygen (O), sulfur (S), NRa or a divalent bridging group; Ra : H, (cyclo)alkyl or aryl; Y 1>, Y 2>groups containing P, arsenic (As) and/or antimony (Sb) atom(s), attached to the phenyl ring directly or by an O atom; R 1>, R 2>, R 3>, R 4>H, (cyclo)alkyl, aryl, alkoxy, halogen, NE 1>E 2>, alkylene-NE 1>E 2>, trifluoromethyl (CF 3), nitro (NO 2), alkoxycarbonyl or cyano (CN); E 1>, E 2>(cyclo)alkyl or aryl. Independent claims are also included for: (a) new catalysts comprising complex(es) of a sub-group VIII metal and ligand(s) (I); (b) preparation of compounds (I).

公开(公告)号：BR0108254A

公开(公告)日：2003-03-05

申请号：BR0108254

申请日：2001-02-09

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  PER MICHAEL R ,  HOFMANN PETER ,  WARTH DANIEL C M ,  PACIELLO ROCCO ,  AMERICANO

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C07B37/12 ,  C07C2/50 ,  C07C13/44 ,  C07C13/64 ,  C07C13/68 ,  C07C45/50 ,  C07C51/14 ,  C07C253/10 ,  C07F9/46 ,  C07F9/50 ,  C07F9/6561 ,  C07F9/6571 ,  C07F9/6574 ,  C07F15/00 ,  C07F15/04 ,  C07F15/06 ,  C08F4/42

Abstract: Diaryl-anellated bicyclo[2.2.n] compounds (I) containing phosphorus, arsenic and/or antimony are new. Diaryl-anellated bicyclo[2.2.n] compounds of formula (I), containing phosphorus, arsenic and antimony, are new: [Image] A 1>, A 2>boron (B), nitrogen (N), phosphorus (P) or CR 5>; R 5>hydrogen (H), (cyclo)alkyl or (het)aryl; X : oxygen (O), sulfur (S), NRa or a divalent bridging group; Ra : H, (cyclo)alkyl or aryl; Y 1>, Y 2>groups containing P, arsenic (As) and/or antimony (Sb) atom(s), attached to the phenyl ring directly or by an O atom; R 1>, R 2>, R 3>, R 4>H, (cyclo)alkyl, aryl, alkoxy, halogen, NE 1>E 2>, alkylene-NE 1>E 2>, trifluoromethyl (CF 3), nitro (NO 2), alkoxycarbonyl or cyano (CN); E 1>, E 2>(cyclo)alkyl or aryl. Independent claims are also included for: (a) new catalysts comprising complex(es) of a sub-group VIII metal and ligand(s) (I); (b) preparation of compounds (I).

公开(公告)号：DE10101939A1

公开(公告)日：2002-07-18

申请号：DE10101939

申请日：2001-01-17

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  PACIELLO ROCCO ,  ROEPER MICHAEL ,  HOFMANN PETER ,  TENSFELDT MARKUS ,  GOETHLICH ALEXANDER

IPC: C07F9/00 ,  C07F15/00 ,  C07F15/06 ,  C07F9/50 ,  B01J31/12 ,  B01J31/24 ,  C07C45/50 ,  C07F9/141 ,  C07F9/46 ,  C07F9/48 ,  C07F9/6574 ,  C07F9/66 ,  C07F9/90

Abstract: Hydroformylation of olefins is carried out in presence of a catalyst comprising a Sub-Group VIII metal complex with a ligand in which two phenyl groups substituted with phosphorus-, arsenic- or antimony-containing residues are attached to a non-aromatic, 3- to 8-membered, carbo- or hetero-cyclic, divalent bridging group. A method for the hydroformylation of compounds with ethylenic double bond(s) by reaction with hydrogen and carbon monoxide in presence of a hydroformylation catalyst, in which the catalyst comprises complex(es) of Sub-Group VIII metal(s) with ligand(s) of formula (I). X = a non-aromatic, 3- to 8-membered, carbo- or hetero-cyclic divalent bridging group with 1, 2 or 3 double bonds and 1, 2, 3 or 4 substituents selected from alkyl, cycloalkyl, aryl, heteroaryl, alkoxy, acyl, carboxyl, alkoxycarbonyl, hydroxy, nitro, cyano, trifluoromethyl, oxo (or their ketals) or -NE E , and X may be part of a condensed ring system with 1, 2 or 3 other rings (optionally with 1, 2 or 3 substituents as above), and X itself may be bridged by -O-, -S-, -N(Ra)- or another bridging group; E , E = alkyl, cycloalkyl or aryl; Ra = H, alkyl, cycloalkyl or aryl; Z , Z = a phosphorus-, arsenic- or antimony-containing residue. An Independent claim is also included for a catalyst as above.

公开(公告)号：ZA9309229B

公开(公告)日：1995-06-09

申请号：ZA9309229

申请日：1993-12-09

Applicant: BASF AG

Inventor： SCHLECKER RAINER ,  TREIBER HANS-JOERG ,  BEHL BERTHOLD ,  HOFMANN PETER

IPC: C07D487/04 ,  A61K31/505 ,  A61P25/00 ,  A61P25/08 ,  A61P25/20 ,  A61P25/28 ,  A61K

CPC classification number: A61K31/505