公开(公告)号：JP2002308816A

公开(公告)日：2002-10-23

申请号：JP2002035329

申请日：2002-02-13

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  PACIELLO ROCCO ,  VOGT DIETER ,  DER VLUGT JARL IVAR VAN

IPC: B01J31/24 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  C07F9/145 ,  C07F9/50

Abstract: PROBLEM TO BE SOLVED: To provide an improved method for the hydroformylation of a compound having at least ethylenically unsaturated double bond. SOLUTION: The hydroformylation method uses at least one kind of a complex of a metal of VIII sub-group having at least one kind of a phosphorus- containing compound, which has two groups each having one P atom bonded to the respective phenyl rings of a molecular skeleton derived from bisphenol A, as a ligand.

公开(公告)号：WO0205955A8

公开(公告)日：2002-03-14

申请号：PCT/EP0108162

申请日：2001-07-13

Applicant: BASF AG ,  AHLERS WOLFGANG ,  MACKEWITZ THOMAS ,  PACIELLO ROCCO ,  MATHEY FRANCOIS ,  LE FLOCH PASCAL ,  SAVA XAVIER

Inventor： AHLERS WOLFGANG ,  MACKEWITZ THOMAS ,  PACIELLO ROCCO ,  MATHEY FRANCOIS ,  LE FLOCH PASCAL ,  SAVA XAVIER

IPC: B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C07C45/50 ,  C07C51/14 ,  C07C253/10 ,  C07F17/02 ,  C08F4/80 ,  C07F9/6568 ,  C07F15/00 ,  C07F17/00

CPC classification number: C07F17/02 ,  B01J31/2295 ,  B01J31/2419 ,  B01J31/2438 ,  B01J31/2461 ,  B01J2231/12 ,  B01J2231/20 ,  B01J2231/321 ,  B01J2231/323 ,  B01J2231/543 ,  B01J2231/645 ,  B01J2531/822 ,  B01J2531/842 ,  C07C45/50 ,  C07C51/14 ,  C07C253/10 ,  C07C57/15 ,  C07C57/04 ,  C07C57/145 ,  C07C57/08 ,  C07C47/02 ,  C07C255/04

Abstract: The invention relates to a method for producing addition products to the C=C double bond of ethylenic unsaturated compound in the presence of a catalyst, comprising at least one complex of a metal of the VIII sub-group with at least one bisphospholyl metallocene as ligand. The invention further relates to novel catalysts with phosphametallocenes as ligands.

Abstract translation: 本发明涉及一种方法，用于制备的加成产物的C = C双键在包含VIII的金属中的至少一种配合物的催化剂存在下烯属不饱和化合物的键。与至少一个Bisphospholylmetallocen作为配体亚类。 本发明还涉及基于磷杂茂基作为配体的新型催化剂。

公开(公告)号：WO2006034812A3

公开(公告)日：2006-07-20

申请号：PCT/EP2005010240

申请日：2005-09-22

Applicant: BASF AG ,  JAEKEL CHRISTOPH ,  HEYDRICH GUNNAR ,  STUERMER RAINER ,  PACIELLO ROCCO

Inventor： JAEKEL CHRISTOPH ,  HEYDRICH GUNNAR ,  STUERMER RAINER ,  PACIELLO ROCCO

IPC: C07C29/141 ,  C07C29/17 ,  C12P7/04 ,  C12P41/00

CPC classification number: C12P7/04 ,  C07B2200/07 ,  C07C29/14 ,  C07C29/141 ,  C07C29/172 ,  C12C11/02 ,  C07C33/025 ,  C07C31/125

Abstract: The invention relates to a method for producing optically active 2-methylalkane-1-ol of general formula (III), comprising the following steps: (i) carbonyl-selective reduction of 2-methylalk-2-en-1-al of general formula (I) to 2-methylalk-2-en-1-ol of general formula (II), (ii) enantioselective hydration of 2-methylalk-2-en-1-ol to give the compound of general formula (III), (iii) increasing the optical yield of the optically active 2-methylalkane-1-ol (III) obtained in step (ii) by way of a lipase-catalyzed acylation reaction, whereby R represents C 1 -C 10 alkyl.

Abstract translation: 一种制备光学活性的2-甲基的通式（III）的烷-1-醇，其包括以下步骤：（ⅰ）carbonylselektive还原的2- methylalk -2-烯-1-醛的通式（I）的2- methylalk -2-烯-1-醇，通式（II），（II）通式（III）的2- methylalk -2-烯-1-醇的对映选择性氢化的，（iii）增加的步骤的光学收率 （ii）所述得到的光学活性2-甲基烷烃-1-醇（III）由脂肪酶催化酰化反应（式I - IV），其中R表示C _{1 -C 10 具有烷基。}

公开(公告)号：WO2005042458A3

公开(公告)日：2005-06-09

申请号：PCT/EP2004011530

申请日：2004-10-14

Applicant: BASF AG ,  VOLLAND MARTIN ,  MACKEWITZ THOMAS ,  AHLERS WOLFGANG ,  SCHAEFER ANSGAR ,  RICHTER WOLFGANG ,  PACIELLO ROCCO

Inventor： VOLLAND MARTIN ,  MACKEWITZ THOMAS ,  AHLERS WOLFGANG ,  SCHAEFER ANSGAR ,  RICHTER WOLFGANG ,  PACIELLO ROCCO

IPC: B01J31/18 ,  B01J31/24 ,  C07C45/50 ,  C07C47/02

CPC classification number: B01J31/186 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/50 ,  C07C47/02

Abstract: The invention relates to a method for the continuous production of aldehydes comprising between 5 and 21 carbon atoms, by the isomerising hydroformylation in a homogenous phase of olefin compositions comprising between 4 and 20 carbon atoms and containing alpha-olefins and olefins with internal double bonds, by means of a synthesis gas, in the presence of a homogeneous rhodium catalyst that is complexed with an organophosphorus ligand containing oxygen atoms and/or nitrogen atoms and a free ligand. Said production is carried out at high temperature and high pressure in a multi-stage reaction system consisting of at least two reaction zones. According to said method, the olefin composition is first reacted in a first reaction zone or a group of several first reaction zones at a total pressure of between 10 and 40 bar, using a synthesis gas with a CO/H2 molar ratio of between 4:1 and 1:2 until a 40 to 95 % conversion of the alpha-olefins is obtained. The hydroformylation product from the first reaction zone or group of several first reaction zones is then reacted in a subsequent reaction zone or group of several reaction zones at a total pressure of between 5 and 30 bar, using a synthesis gas with a CO/H2 molar ratio of between 1:4 and 1:1000. The total pressure in the subsequent reaction zone or zones is respectively 1 to (G1-Gf) bar lower than that of the preceding reaction zone, whereby G1 represents the total pressure in the respective preceding reaction zone and Gf represents the total pressure in the respective reaction zone that succeeds said first reaction zone or zones, with the proviso that the difference between G1 and Gf is greater than 1 bar and the partial CO pressure in the subsequent reaction zone or zones is respectively lower than that of the preceding reaction zone.

Abstract translation: 用于连续制备含有内部双键具有4至20个碳原子的烯烃组合物由合成气的装置在含具有一个氧和/或氮原子的有机磷配体的存在下，通过在α-烯烃的均相异构化的加氢甲酰化的5至21个碳原子的醛和烯烃的配位过程 均相铑催化剂，并在升高的温度和在包括至少两个反应区的多阶段反应系统中升高的压力游离配位体，其中一个最初的烯烃的一组中的一个或多个第一反应区中在10至40巴的总压力与合成气 的CO / H2摩尔比为4：1至1：2的一组的一个或多个在反应至40的α-烯烃的转化率，以95％和加氢甲酰化混合物从该组下方的一个或多个第一反应区 反应1000，其中在一个或多个随后的反应区中的总压力通过1巴下，以（G1 GF）：在5〜30巴以1:1的CO / H 2摩尔比的总压力与合成气连接的反应区：4至1 比在各自的前一反应区中，其中G 1表示用于在一个或多个第一反应区的每个后续反应区中的总压各自的前一反应区和GF的总压力，条件是不同的是G1 GF大于1巴的条件， 并且其中所述一个或多个后续反应区中的CO分压在每种情况下低于在前面的反应区中的CO分压。

公开(公告)号：WO2005009934A2

公开(公告)日：2005-02-03

申请号：PCT/EP2004008209

申请日：2004-07-22

Applicant: BASF AG ,  AHLERS WOLFGANG ,  PACIELLO ROCCO ,  ZELLER EDGAR ,  VOLLAND MARTIN ,  FLORES MIGUEL ANGEL

Inventor： AHLERS WOLFGANG ,  PACIELLO ROCCO ,  ZELLER EDGAR ,  VOLLAND MARTIN ,  FLORES MIGUEL ANGEL

IPC: C07C29/16 ,  C07C29/17 ,  C07C29/38 ,  C07C45/50 ,  C07C45/72 ,  C07C45/74 ,  C07F9/50 ,  C07F9/572 ,  C07C29/00

CPC classification number: C07C45/50 ,  C07C29/16 ,  C07C29/175 ,  C07C29/38 ,  C07C45/72 ,  C07C45/74 ,  C07F9/5027 ,  C07F9/5728 ,  C07C31/125 ,  C07C47/02

Abstract: The invention relates to a method for production of hydroformylated olefins, whereby a) an olefin-containing feed, carbon monoxide and hydrogen are fed into a first reaction zone and reacted in the presence of a first catalyst system, b) a liquid stream essentially comprising unreacted olefins and optionally saturated hydrocarbons is separated from the discharge from the first reaction zone, c) the liquid stream obtained in step b), carbon monoxide and hydrogen are fed into a second reaction zone and reacted in the presence of a second catalyst system.

Abstract translation: 本发明涉及一种用于制备烯烃的加氢甲酰化产物，在第一反应区，其一个）馈送一个含烯烃的进料，以及一氧化碳和氢气并在从所述流出物的第一催化剂体系，10 b）中的从所述第一反应区中的存在 从没有设置烯烃和任选饱和烃基本上分离现有的液体流，c）将）在第二反应区，并在第二催化剂体系的存在下，在步骤b中得到的足流以及一氧化碳和氢。

公开(公告)号：WO0222261A2

公开(公告)日：2002-03-21

申请号：PCT/EP0110735

申请日：2001-09-17

Applicant: BASF AG ,  AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

CPC classification number: C07F9/65746 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/22 ,  B01J2231/321 ,  B01J2531/0266 ,  B01J2531/80 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/845 ,  C07C45/50 ,  C07F9/65522 ,  C07F9/65719 ,  C07C47/02

Abstract: The invention relates to a method for the hydroformylation of ethylenically unsaturated compounds, whereby at least one complex of a metal of subgroup VIII is used as the hydroformylation catalyst, having at least one compound containing phosphorus, arsenic, or antimony as a ligand. Each compound comprises two groups having a P, As, or Sb atom and at least two other heteroatoms, said groups being bound to a xanthene-type molecular structure. The invention also relates to novel compounds of this type and catalysts comprising at least one complex of a metal of subgroup VIII having at least one such compound as a ligand.

Abstract translation: 本发明涉及用于烯属不饱和化合物的加氢甲酰化过程中，被用作羰基化催化剂包括VIII的金属中的至少一种配合物。具有至少一个磷，砷或含锑化合物作为配体的亚组，该化合物为二P- 含有基团As或Sb原子和至少两个另外的杂原子附接至具有呫吨状分子骨架。 本发明还涉及到这种类型和催化剂包括VIII的金属中的至少一种配合物的新化合物。与作为配体的至少一个这样的化合物亚类。

公开(公告)号：WO2007082928A3

公开(公告)日：2008-04-10

申请号：PCT/EP2007050530

申请日：2007-01-19

Applicant: BASF AG ,  JAEKEL CHRISTOPH ,  HETTCHE FRANK ,  RUDOLPH JENS ,  PACIELLO ROCCO

Inventor： JAEKEL CHRISTOPH ,  HETTCHE FRANK ,  RUDOLPH JENS ,  PACIELLO ROCCO

IPC: B01J37/04 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C07F15/00

CPC classification number: C07F15/0046 ,  B01J31/1805 ,  B01J31/1815 ,  B01J31/182 ,  B01J31/183 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/186 ,  B01J31/1865 ,  B01J31/1875 ,  B01J31/2291 ,  B01J31/2295 ,  B01J31/24 ,  B01J31/2409 ,  B01J31/2414 ,  B01J31/2419 ,  B01J31/2438 ,  B01J31/2452 ,  B01J31/2457 ,  B01J31/2471 ,  B01J31/248 ,  B01J31/2495 ,  B01J37/04 ,  B01J2231/643 ,  B01J2531/0263 ,  B01J2531/0266 ,  B01J2531/821 ,  C07F15/0053

Abstract: The invention relates to a method for production of a ruthenium catalyst comprising i) a bidentate phosphorous ligand or two monodentate phosphorus ligands and ii) a bidentate nitrogen ligand or two monodentate nitrogen ligands.

Abstract translation: 本发明涉及一种方法，用于制备的钌催化剂，其中ⅰ）的磷二齿配位体或两个单齿磷配体，和ii）一个氮二齿配位体或两个单齿氮配位体。

公开(公告)号：WO2006002999A3

公开(公告)日：2006-09-08

申请号：PCT/EP2005007289

申请日：2005-07-06

Applicant: BASF AG ,  HETTCHE FRANK ,  JAEKEL CHRISTOPH ,  FRIEDRICH MARKO ,  PACIELLO ROCCO

Inventor： HETTCHE FRANK ,  JAEKEL CHRISTOPH ,  FRIEDRICH MARKO ,  PACIELLO ROCCO

IPC: C07C67/303 ,  C07C69/34

CPC classification number: C07C67/303 ,  C07B2200/07 ,  C07C69/34

Abstract: The invention relates to a method for producing optically active alkyl succinic acid monoalkyl esters of formula (I), wherein D and E independently represent H, C 1 -C 10 alkyl, RC 1 -C 10 alkyl, aryl, or alkylaryl.

Abstract translation: 本发明涉及一种制备式的旋光活性Alkylbernsteinsäuremonoalkylestern（I），其中D和E彼此独立地H，C _{1 -C 10 烷基，RC 的制备 1 -C 10 - 烷基，芳基，或烷芳基。}

公开(公告)号：WO0200669A3

公开(公告)日：2002-06-20

申请号：PCT/EP0107219

申请日：2001-06-25

Applicant: BASF AG ,  MACKEWITZ THOMAS ,  AHLERS WOLFGANG ,  ZELLER EDGAR ,  ROEPER MICHAEL ,  PACIELLO ROCCO ,  KNOLL KONRAD ,  PAPP RAINER ,  VOSS HARTWIG

Inventor： MACKEWITZ THOMAS ,  AHLERS WOLFGANG ,  ZELLER EDGAR ,  ROEPER MICHAEL ,  PACIELLO ROCCO ,  KNOLL KONRAD ,  PAPP RAINER ,  VOSS HARTWIG

IPC: B01J31/24 ,  B01J31/28 ,  C07C45/50 ,  C07F9/6568 ,  C07F15/00 ,  C07F15/04 ,  C07F15/06

CPC classification number: B01J31/2466 ,  B01J31/20 ,  B01J31/2423 ,  B01J31/2433 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/822 ,  C07C45/50 ,  C07F9/65683 ,  C07F15/0026 ,  C07F15/0053 ,  C07F15/0066 ,  C07F15/008 ,  C07F15/045 ,  C07F15/065 ,  C07C47/21 ,  C07C47/02

Abstract: The invention relates to phosphacyclohexanes of general formulae I and II, wherein the following designations, among others, apply: R can represent hydrogen, C1-100-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl; R to R can independently represent hydrogen, C1-20-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl; W, W' can independently represent single bonds or bridges comprising 1 to 20 carbon atoms, which can form part of a cyclic or aromatic group and can be interrupted by heteroatoms. Said phosphacyclohexanes are used as ligands in transition metal complexes of transition metals belonging to groups VIII to X of the periodic table.

Abstract translation: Phosphacyclohexanes通式（I）和（II），除其他外，以下含义：R是氢，烷基C1-100，C7-20芳烷基，C7-20烷芳基，C 6-12 - 芳基，R <1>至R <10>独立地是氢，C 1-20烷基，C 7-20 - 芳烷基，C7-20烷芳基，C 6-12 - 芳基; W，W“各自独立地为单键或具有1至20个碳原子，其可以是环状或芳族基团的一部分，并且可以被杂原子间隔的桥梁，被用作在第八的过渡金属的过渡金属配合物的配体的元素的周期表的第10组 ，

公开(公告)号：CA2670935A1

公开(公告)日：2008-06-05

申请号：CA2670935

申请日：2007-11-29

Applicant: BASF AG

Inventor： SIGL MARCUS ,  HEIMANN FRANK ,  POPLOW FRANK ,  VOLLAND MARTIN ,  BITTERLICH STEFAN ,  PAPP RAINER ,  MACKEWITZ THOMAS ,  CRONE SVEN ,  HEIDEMANN THOMAS ,  UEBLER CHRISTOPH ,  PACIELLO ROCCO ,  WIEBELHAUS DAG

IPC: C07C5/25 ,  C07C11/08 ,  C07C45/50 ,  C07C47/02

Abstract: The present invention relates to a method for the production of hydroform ylation products from olefins having at least four carbon atoms. A high amou nt of the linear Ci-olefins with terminal double bonds that are present in t he inlet comprising olefins, and also of the linear Ci-olefins having intern al double bonds are converted to hydroformylation products. The invention fu rther relates to a method for the production of 2-propylheptanol, comprising said hydroformylation method.