Abstract:
The invention relates to a method for reesterifying or esterifying side chains in polymers. Said method comprises the following steps: a) a copolymer is produced which is obtained by polymerizing aa) at least one (meth)acrylate of general formula (I) as component A, wherein R 1 represents H or CH 3 while R 2 represents H or an alkyl radical that can be optionally substituted with functional groups such as acryl groups, ether groups, amino groups, epoxy groups, halogen groups, or sulfonic acid groups, and ab) at least one monomer of general formula (II) as component B, wherein R 3 has the same meaning as R 1 , R 4 has the same meaning as R 2 , and n = 1 to 40, and b) reesterifying or esterifying the carboxyl group containing the radical R 4 with an alcohol in the presence of an enzyme catalyzing the reesterification or esterification process. The invention also relates to said polymers and the use thereof.
Abstract:
The invention relates to a mewthod for controlling the thickening of aqueous systems containing silicates, characterized in that at least one copolymer having an average molecular weight Mw of more than 60000 g/mol is added to said aqueous system and that the copolymer consists, essentially statistically, of monoethylenically unsaturated monocarboxylic acids, monoethylenically unsaturated dicarboxylic acids and, optionally, other ethylenically unsaturated comonomers, the indicated amounts referring to the total amount of all used monomers, respectively.
Abstract:
Disclosed is a method for applying corrosion-resistant layers, especially integrated pretreatment layers or layers for atmospheric corrosion protection, to metallic surfaces. In said method, copolymers are used which contain monomers comprising 20 to 70 percent by weight of nitrogen heterocyles, monomers comprising 10 to 50 percent of acidic groups, 10 to 50 percent by weight of vinyl aromatic monomers, and 0 to 25 percent by weight of other optional monomers as monomeric constitutional units. Also disclosed are copolymers having said composition as well as preparations for applying corrosion-resistant layers.
Abstract:
The invention relates to copolymers comprising dicarboxylic acid units modified by -SR, -CSNR2 and/or -CN-units and at least one other type of copolymer. A method for producing said copolymers by a polymer-analogous reaction and the use of said copolymers in the form of a corrosion inhibitor are also disclosed.
Abstract:
The invention relates to a method for controlling the thickening of aqueous, silicate-containing systems, characterized in that at least one copolymer having an average molecular weight (Mw) of at least 3000 g/mol and not more than 60000 g/mol is added to said aqueous system and that the copolymer is, essentially statistically, made of monoethylenically unsaturated monocarboxylic acids, monoethylenically unsaturated dicarboxylic acids and eventually ethylenically unsaturated comonomers. The method is also characterized in that the polymerization is carried out in the presence of 0.01 to 100 mol-%, in relation to the total amount of all COOH groups of the mono- and dicarboxylic acids, of at least one base for producing the copolymer, the indicated amounts in wt.-% each referring to the total amount of all used monomers.
Abstract:
The invention relates to a method for controlling the thickening of aqueous, silicate-containing systems, characterized in that at least one copolymer having an average molecular weight (Mw) of at least 3000 g/mol and not more than 60000 g/mol is added to said aqueous system and that the copolymer is, essentially statistically, made of monoethylenically unsaturated monocarboxylic acids, monoethylenically unsaturated dicarboxylic acids and eventually ethylenically unsaturated comonomers. The method is also characterized in that the polymerization is carried out in the presence of 0.01 to 100 mol-%, in relation to the total amount of all COOH groups of the mono- and dicarboxylic acids, of at least one base for producing the copolymer, the indicated amounts in wt.-% each referring to the total amount of all used monomers.
Abstract:
The invention relates to a method for applying integrated pre-treatment layers with a thickness of between 1 and 25 µm to metallic surfaces, especially the surfaces of strip metals, by treatment with a composition containing at least one binding agent, a cross-linking agent, a fine-particle inorganic filler, and a dicarboxylic acid olefin copolymer. The invention also relates to metallic moulded bodies provided with one such integrated pre-treatment layer, and a formulation for carrying out the method.
Abstract:
Preparation for and a method of applying corrosion control coats to metallic surfaces, particularly the surfaces of metallic structures or metal constructions, the preparation comprising at least one binder system curable under atmospheric conditions, a dicarboxylic acid-olefin copolymer, and a finely divided filler, pigment or dye. Coated metallic surface obtainable by means of the method, especially the surface of metallic structures or metal constructions.
Abstract:
Method of passivating metallic surfaces and a preparation which is suitab le for carrying out the method and comprises at least water, an acid and a c opolymer of functionalized (meth)acrylic esters, monomers having phosphoric acid and/or phosphonic acid groups, monomers having COOH groups and, if desi red, further monomers. Copolymer containing the monomers mentioned.
Abstract:
Use of coating substances comprising at least one compound (D) that comprises at least one thioamide group in corrosion protection atmosphere. Use of coating substances comprising at least one compound (D) that comprises at least one thioamide group of formula (-(C=S)-NR 1>R 2>) in corrosion protection atmosphere. Independent claims are included for: (1) a mixture comprising at least a dispersed binding agent, at least one (D), optionally at least one solvent and water; and (2) the preparation of coating substances.