公开(公告)号：CA2518048A1

公开(公告)日：2004-09-23

申请号：CA2518048

申请日：2004-02-24

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  BARTSCH MICHAEL ,  LUYKEN HERMANN ,  BASSLER PETER ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  FLORES MIGUEL ANGEL ,  HADERLEIN GERD ,  JUNGKAMP TIM

IPC: C07C253/10 ,  C07C253/34 ,  C07C255/04

Abstract: The invention relates to a method for hydrocyanating an olefinically unsaturated nitrile in the presence of a catalyst that contains Ni(0). The inventive method is characterized in that the reaction is carried out in the presence of a hydrocarbon that, under certain pressure, concentration and temperature conditions, leads to the formation of at least two liquid phases of the overall system of which one phase, with regard to the overall weight of the phase, has a higher proportion of the catalyst containing Ni(0) than the other phase or other phases.

公开(公告)号：BR0114273A

公开(公告)日：2003-08-26

申请号：BR0114273

申请日：2001-09-25

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT ,  BASSLER PETER ,  SIEGEL WOLFGANG

IPC: C07C253/34 ,  C07C255/07

Abstract: A process is provided for the distillative separation of pentene nitrile isomers which have a relative volatility alpha ranging from 1.0 to 1.3 in the pressure range from 1 to 500 kPa, wherein the distillation is carried out in the presence of a liquid diluent which forms with the pentene nitrile isomers, under the same pressure conditions, azeotropes whose relative volatility alpha is higher than that of the pentene nitrile isomers to be separated.

公开(公告)号：CA2462720A1

公开(公告)日：2003-04-24

申请号：CA2462720

申请日：2002-10-04

Applicant: BASF AG

Inventor： HADERLEIN GERD ,  SIEGEL WOLFGANG ,  JUNGKAMP TIM ,  ALTMAYER MARCO ,  MOLNAR FERENC ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT ,  BARTSCH MICHAEL

IPC: B01J31/22 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/46 ,  C07F15/04 ,  C07F9/50

Abstract: The invention relates to phosphinites I of formulae (1) or (2) or (3) and mixtures thereof, in which Rl, R2, R4 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms, provided that at least one of the groups Rl, R2, R4 is different from H; R3 is H or methyl; X is F, Cl or CF3 and n is 0, 1 or 2.

公开(公告)号：CA2462719A1

公开(公告)日：2003-04-24

申请号：CA2462719

申请日：2002-10-01

Applicant: BASF AG

Inventor： ALTMAYER MARCO ,  SIEGEL WOLFGANG ,  MOLNAR FERENC ,  JUNGKAMP TIM ,  HADERLEIN GERD ,  BARTSCH MICHAEL ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT

IPC: B01J31/22 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/48

Abstract: Phosphonite I of formula l 1 or 2 wherein Rl and R2 independently represent hydrogen, an alkyl group or an alkene group having 1 - 8 carbon atoms, or an alkoxy group having 1-8 carbon atoms, with the proviso that RI and R2 are no t simultaneously H, R3 is H or methyl, R4 is t-butyl, R5, R6, R7, R8 and R9 independently represent H or an alkyl group or an alkylene group having 1 - 8 carbon atoms.

公开(公告)号：CA2423564A1

公开(公告)日：2003-03-24

申请号：CA2423564

申请日：2001-09-25

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  BASSLER PETER ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  JUNGKAMP TIM ,  SIEGEL WOLFGANG

IPC: C07C253/34 ,  C07C255/07

Abstract: The invention relates to a method for separating pentenenitrile isomers havi ng a relative volatility alpha in the region 1.0 - 1.3 in a pressure range of 1 - 500 kPa by means of separation. According to said method, the distillation i s carried out in the presence of a liquid diluent which forms azeotropes with the pentenenitrile isomers in the same pressure conditions, whose relative volatility alpha is higher than the pentenenitrile isomers which are to be separated.

公开(公告)号：CA2454912A1

公开(公告)日：2003-02-13

申请号：CA2454912

申请日：2002-07-16

Applicant: BASF AG

Inventor： SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  ALTMAYER MARCO ,  JUNGKAMP TIM

IPC: B01J31/22 ,  B01J23/755 ,  B01J31/18 ,  B01J31/24 ,  C07B61/00 ,  C07C253/10 ,  C07C255/04

Abstract: A catalyst system containing a) Ni (0), b) 4 -10 mol per mol Ni (0) accordin g to a) a compound (I) of formula P (X1R1) (X2R2) (X3R3) (I) wherein X1, X2, X 3 independently represent oxygen or a single bond R1, R2, R3 represent independently, the same or different organic radicals, and c) 1 -4 mol per m ol Ni (0) according to a) a compound (II) of formula (II) wherein X11, X12, X13 , X21, X22, X23 independnetly represent oxygen or a single bond, R11, R12 independently represent the same or different individual or bridged organic radicals, R21, R22 independently represent the same or different, individual or bridged organic radicals, Y represents a bridge group. The invention also relates to a method for the production of mixtures of monoolefin C5- mononitrils with a n-conjugated C=C and C=N bond by hydrocyanation of a hydrocarbon mixture containing 1,3-butadiene in the presence of at least one such system and to a method for the production of a dinitrile by hydrocyanation of a mixture of monoolefin C5-mononitriles with a non- conjugated C=C- and C=N bond in the presence of at least one such system.

公开(公告)号：DE10136488A1

公开(公告)日：2003-02-06

申请号：DE10136488

申请日：2001-07-27

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  KUNSMANN-KEITEL DAGMAR PSACA ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  ALTMAYER MARCO ,  SIEGEL WOLFGANG

IPC: B01J31/22 ,  B01J23/755 ,  B01J31/18 ,  B01J31/24 ,  C07B61/00 ,  C07C253/10 ,  C07C255/04 ,  C07B43/08

Abstract: A catalyst system comprises Ni(0) and phosphorous ligands. A catalyst system (I) comprises: (A) 1 mol Ni(0); (B) 4-10 mol of a compound of formula P(X R )(X R )(X R ) (1); and (C) 1-4 mol of a compound of formula (2); P(R -X )(R -X )-X -Y-X -P(X -R )(X -R ) (2); X ,X ,X ,X ,X ,X ,X , X ,X = oxygen or a single bond; R -R = organic groups; R ,R ,R ,R = single or bridged organic group; Y = bridging group. Independent claims are included for: (i) a process for the production of the system (I) by reaction of Ni(O) with a compound (B) in the presence of a liquid diluent; reaction of the resulting product with a compound (C) in the presence of a liquid diluent to yield the system (I); (ii) a process for the production of 5C-monoolefinic mononitrile having nonconjugated C=C and C=N bonds by hydrogenation of a 1,3-butadiene containing hydrocarbon mixture in the presence of a catalyst whereby the hydrocyanation is carried out in the presence of the catalyst system (I).

公开(公告)号：BRPI0507197B1

公开(公告)日：2014-12-30

申请号：BRPI0507197

申请日：2005-01-27

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  AECHTNER TOBIAS ,  PFAB PETER ,  DECKERT PETRA ,  BASSLER PETER

IPC: C07C253/10 ,  C07C255/07

Abstract: A process is described for preparing 3-pentenenitrile, characterized by the following process steps: (a) isomerizing a reactant stream which comprises 2-methyl-3-butenenitrile over at least one dissolved or dispersed isomerization catalyst to give a stream 1 which comprises the at least one isomerization catalyst, 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, (b) distilling stream 1 to obtain a stream 2 as the top product which comprises 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, and a stream 3 as the bottom product which comprises the at least one isomerization catalyst, (c) distilling stream 2 to obtain a stream 4 as the top product which, compared to stream 2, is enriched in (Z)-2-methyl-2-butenenitrile, based on the sum of all pentenenitriles in stream 2, and a stream 5 as the bottom product which, compared to stream 2, is enriched in 3-pentenenitrile and 2-methyl-3-butenenitrile, based on the sum of all pentenenitriles in stream 2, (d) distilling stream 5 to obtain a stream 6 as the bottom product which comprises 3-pentenenitrile and a stream 7 as the top product which comprises 2-methyl-3-butenenitrile.

公开(公告)号：ES2289689T3

公开(公告)日：2008-02-01

申请号：ES05701205

申请日：2005-01-27

Applicant: BASF AG

Inventor： SCHEIDEL JENS ,  JUNGKAMP TIM ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  BAUMANN ROBERT ,  LUYKEN HERMANN

IPC: C07F9/00 ,  C07C253/34 ,  C07C255/04 ,  C07F9/02

Abstract: Procedimiento para la separación por extracción de complejos de níquel (0) con ligandos fosforados y/o ligandos fosforados libres a partir de una descarga de reacción de un hidrocianado de mononitrilos insaturados para dar dinitrilos, mediante extracción por medio de un hidrocarburo efectuándose una separación de fases de hidrocarburo y descarga de reacción en dos fases a una temperatura T (en ºC), caracterizado porque, en la descarga de reacción de hidrocianado, el contenido en complejos de níquel (0) con ligandos fosforados y/o ligandos fosforados libres, dependiendo de la temperatura T, asciende al menos a y % en peso, e independientemente de la temperatura T asciende a un máximo de un 60 % en peso, determinándose el valor numérico del contenido mínimo y mediante la ecuación Y = 0, 5 . T + 20 y debiéndose emplear T en la ecuación como valor numérico adimensional.

公开(公告)号：PL1713816T3

公开(公告)日：2007-12-31

申请号：PL05701205

申请日：2005-01-27

Applicant: BASF AG

Inventor： SCHEIDEL JENS ,  JUNGKAMP TIM ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  BAUMANN ROBERT ,  LUYKEN HERMANN ,  DECKERT PETRA ,  PFAB PETER ,  SIEGEL WOLFGANG ,  AECHTNER TOBIAS

IPC: C07F9/00 ,  C07C253/34 ,  C07C255/04 ,  C07F9/02