-
公开(公告)号:DE59306546D1
公开(公告)日:1997-07-03
申请号:DE59306546
申请日:1993-02-08
Applicant: BASF AG
Inventor: ROEPER MICHAEL PROF DR , LORZ PETER MICHAEL DR , KOEFFER DIETER DR
IPC: C07C67/313 , C07C67/347 , C07C69/66 , C07C69/716 , C07F9/6574
Abstract: Preparation of omega -formyl-C4-C20-alkanecarboxylic esters by reacting C4-C20-alkenecarboxylic esters with carbon monoxide and hydrogen at a temperature from 30 to 150 DEG C under a pressure of 0.01 to 30 bar in the presence of rhodium carbonyl complexes which are modified with polyphosphites.
-
公开(公告)号:DE4405622A1
公开(公告)日:1995-08-24
申请号:DE4405622
申请日:1994-02-22
Applicant: BASF AG
Inventor: BALZER WOLF-DIETER DR , FLORY KLAUS DR , KOEFFER DIETER DR , MOHR JUERGEN DR
IPC: C07C41/42 , C07F5/04 , C10M111/04 , C10M175/00 , C07C43/11 , C10M105/18 , C10M107/34
Abstract: Reprocessing hydraulic fluids contg. glycol ether borate(s) comprises adding a mixt. of oligo-glycol ethers and/or oligo-glycols to the hydraulic fluids before or during distillation. the mixt. has a higher boiling pt. than that of the mixt. obtd. from the hydraulic fluid.
-
公开(公告)号:ES2063199T3
公开(公告)日:1995-01-01
申请号:ES90110993
申请日:1990-06-11
Applicant: BASF AG
Inventor: KOEFFER DIETER DR , MAERKL ROBERT DR , BERTLEFF WERNER DR
IPC: B01J31/04 , B01J31/20 , B01J31/24 , C07B61/00 , C07C45/49 , C07C45/50 , C07C47/198 , C07C49/175
-
公开(公告)号:ES2054961T3
公开(公告)日:1994-08-16
申请号:ES89116513
申请日:1989-09-07
Applicant: BASF AG
Inventor: KOEFFER DIETER DR , BERTLEFF WERNER DR
IPC: B01J31/20 , B01J31/26 , C07B61/00 , C07D325/00 , C07C41/48 , C07C43/315
Abstract: 1,1,2-Trialkoxyethanes of the general formula I (I) where R1 to R3 are each independently of the others C1-C20-alkyl or cycloalkyl, or R1 and R2 may be linked together to form a 5-, 6- or 7-membered ring, are prepared by reacting formaldehyde dialkyl acetals of the general formula II (II) where R1 and R2 are each as defined above, or compounds which are capable of forming formaldehyde dialkyl acetals under the reaction conditions, with carbon monoxide, hydrogen and alkanols R3OH under superatmospheric pressure at elevated temperature in the presence of a catalyst composed of a cobalt carbonyl compound and a promotor, wherein the promotor is an alkali metal, alkaline earth metal or ammonium salt of a protogenic compound having an acid constant Ka of from 10-2 to 10-14, an alkali metal or alkaline earth metal hydroxide or an aminocarboxylic acid.
-
公开(公告)号:ES2044335T3
公开(公告)日:1994-01-01
申请号:ES90113714
申请日:1990-07-18
Applicant: BASF AG
Inventor: KOEFFER DIETER DR , BERTLEFF WERNER DR , ROEPER MICHAEL DR
Abstract: Olefinically unsaturated compounds are hydroformylated in an organic reaction medium with the aid of rhodium complex catalysts which are soluble in the reaction medium by performing the reaction in the presence of water-insoluble rhodium complex catalysts and also in the presence of arylthiols of the general formula I Ar-SH I where Ar is substituted or unsubstituted aryl.
-
公开(公告)号:DE59100170D1
公开(公告)日:1993-08-05
申请号:DE59100170
申请日:1991-08-10
Applicant: BASF AG
Inventor: LORZ PETER MICHAEL DR , BERTLEFF WERNER DR , ROEPER MICHAEL DR , KOEFFER DIETER DR
Abstract: Rhodiumhydroformylation catalysts with bis-phosphite ligands of the formula I in which -X- is a divalent bisarylene radical or R , W is a divalent arylene, bisarylene or alkylene radical and R and R are identical or different and are a substituted or unsubstituted alkylene or ortho-arylene radical.
-
公开(公告)号:DE58904614D1
公开(公告)日:1993-07-15
申请号:DE58904614
申请日:1989-09-07
Applicant: BASF AG
Inventor: KOEFFER DIETER DR , BERTLEFF WERNER DR
IPC: B01J31/20 , B01J31/26 , C07D325/00 , C07B61/00 , C07C41/48 , C07C43/315
Abstract: 1,1,2-Trialkoxyethanes of the general formula I (I) where R1 to R3 are each independently of the others C1-C20-alkyl or cycloalkyl, or R1 and R2 may be linked together to form a 5-, 6- or 7-membered ring, are prepared by reacting formaldehyde dialkyl acetals of the general formula II (II) where R1 and R2 are each as defined above, or compounds which are capable of forming formaldehyde dialkyl acetals under the reaction conditions, with carbon monoxide, hydrogen and alkanols R3OH under superatmospheric pressure at elevated temperature in the presence of a catalyst composed of a cobalt carbonyl compound and a promotor, wherein the promotor is an alkali metal, alkaline earth metal or ammonium salt of a protogenic compound having an acid constant Ka of from 10-2 to 10-14, an alkali metal or alkaline earth metal hydroxide or an aminocarboxylic acid.
-
公开(公告)号:DE4026406A1
公开(公告)日:1992-02-27
申请号:DE4026406
申请日:1990-08-21
Applicant: BASF AG
Inventor: LORZ PETER MICHAEL DR , BERTLEFF WERNER DR , ROEPER MICHAEL DR , KOEFFER DIETER DR
Abstract: Rhodiumhydroformylation catalysts with bis-phosphite ligands of the formula I in which -X- is a divalent bisarylene radical or R , W is a divalent arylene, bisarylene or alkylene radical and R and R are identical or different and are a substituted or unsubstituted alkylene or ortho-arylene radical.
-
-
-
-
-
-
-