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公开(公告)号:DE19702734A1
公开(公告)日:1998-07-30
申请号:DE19702734
申请日:1997-01-27
Applicant: BASF AG
Inventor: BAUR RICHARD DR , POTTHOFF-KARL BIRGIT DR , BERTLEFF WERNER DR
Abstract: The invention relates to a detergent and cleaning agent formulation, containing, besides other usual components, a bleaching system based on hydrogen peroxide, peroxo compounds and/or peracids, as well as a mixture of (A) largely biodegradable aliphatic or alicyclic amine with 1-12 C-atoms, which can, in addition, carry hydroxyl groups, and (B) complexing agents having a complexing effect on heavy metals, whereby the weight ratio of A:B ranges from 20:1, in particular from 1:5 to 5:1. The above mixture of amines (A) and complexing agents (B) has a stabilizing effect on the bleaching system.
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公开(公告)号:DE19625908A1
公开(公告)日:1998-01-08
申请号:DE19625908
申请日:1996-06-27
Applicant: BASF AG
Inventor: WEHLAGE THOMAS DR , BOECKH DIETER DR , BERTLEFF WERNER DR , OFTRING ALFRED DR
Abstract: Use of amines (I) is claimed as bleaching enhancers for textile detergents. (I) have pKa > (A-1) (preferably pKa > (A+0.5)). A = pH of the textile washing composition which contains 1 wt.% wash liquor. especially at least 0.5 above the pH. Also claimed are bleaching agents and textile detergents containing (A) 0.5-40 wt.% peroxide and/or percarboxylic acid bleach; (B) 0-20 wt.% bleach activator; and (C) 0.1-1 (especially 0.25-0.45) wt.% of a sec. amine of formula R NH-R (II), (III) or (IV). R = 6-14C hydrocarbyl or 6-14C hydroxyhydrocarbyl; and R = 1-5C hydrocarbyl, preferably Me; p, q = 0-4; X = 1-8C alkylene (optionally interrupted by O, S, O-C(O)-, NR or -NR-C(O)-) or 2-8C alkenylene; R = 1-8C alkyl; Y = as for X or bond, O, S, -O-C(O)-, or -NR-C(O)-; or when p+q
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公开(公告)号:DE19611992A1
公开(公告)日:1997-10-02
申请号:DE19611992
申请日:1996-03-26
Applicant: BASF AG
Inventor: WEHLAGE THOMAS DR , BOECKH DIETER DR , BERTLEFF WERNER DR , OFTRING ALFRED DR
Abstract: Use of amines (I) is claimed as bleaching enhancers for textile detergents. (I) have pKa > (A-1) (preferably pKa > (A+0.5)). A = pH of the textile washing composition which contains 1 wt.% wash liquor. especially at least 0.5 above the pH. Also claimed are bleaching agents and textile detergents containing (A) 0.5-40 wt.% peroxide and/or percarboxylic acid bleach; (B) 0-20 wt.% bleach activator; and (C) 0.1-1 (especially 0.25-0.45) wt.% of a sec. amine of formula R NH-R (II), (III) or (IV). R = 6-14C hydrocarbyl or 6-14C hydroxyhydrocarbyl; and R = 1-5C hydrocarbyl, preferably Me; p, q = 0-4; X = 1-8C alkylene (optionally interrupted by O, S, O-C(O)-, NR or -NR-C(O)-) or 2-8C alkenylene; R = 1-8C alkyl; Y = as for X or bond, O, S, -O-C(O)-, or -NR-C(O)-; or when p+q
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公开(公告)号:DE19541012A1
公开(公告)日:1997-05-07
申请号:DE19541012
申请日:1995-11-03
Applicant: BASF AG
Inventor: WEHLAGE THOMAS DR , BOECKH DIETER DR , KAPPES ELISABETH DR , OFTRING ALFRED DR , POTTHOFF-KARL BIRGIT DR , BERTLEFF WERNER DR
Abstract: Proposed is the use of mono and bis oxime esters (I), in which L is an oxime group of formula (II) or (III), R and R being hydrogen or an organic group and Z being an alkyl group, L is a second oxime group L or an organic group linked by an O-atom or N-atom, A is a chemical bond or a bridging group and m is 0 or 1, as activators for inorganic per-compounds, in particular cold-bleach activators or optical brighteners in washing, cleaning and bleaching agents and in disinfectants.
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公开(公告)号:ES2054111T3
公开(公告)日:1994-08-01
申请号:ES90101449
申请日:1990-01-25
Applicant: BASF AG
Inventor: BERTLEFF WERNER DR , KOEFFER DIETER DR
Abstract: Preparation of 2,2-dialkylpropionaldehydes I … … in which R and R stand for C1- to C4-alkyl groups, by hydroformylation of 1,1-dialkylethylenes II … … with cobalt carbonyl complexes by… (a) carrying out the reaction in the presence of water-containing solvents in which water is soluble or at least partially soluble, the water content of the reaction mixture being between 0.1 and 20% by weight, or… (b) carrying out the reaction in the presence of a lactone which can carry one or more C1- to C4-alkyl groups as substituents, or of an aliphatic or cycloaliphatic sulphone.
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公开(公告)号:DE59001085D1
公开(公告)日:1993-05-06
申请号:DE59001085
申请日:1990-01-25
Applicant: BASF AG
Inventor: BERTLEFF WERNER DR , KOEFFER DIETER DR
Abstract: Preparation of 2,2-dialkylpropionaldehydes I … … in which R and R stand for C1- to C4-alkyl groups, by hydroformylation of 1,1-dialkylethylenes II … … with cobalt carbonyl complexes by… (a) carrying out the reaction in the presence of water-containing solvents in which water is soluble or at least partially soluble, the water content of the reaction mixture being between 0.1 and 20% by weight, or… (b) carrying out the reaction in the presence of a lactone which can carry one or more C1- to C4-alkyl groups as substituents, or of an aliphatic or cycloaliphatic sulphone.
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公开(公告)号:DE3862624D1
公开(公告)日:1991-06-06
申请号:DE3862624
申请日:1988-07-23
Applicant: BASF AG
Inventor: MAERKL ROBERT DR , BERTLEFF WERNER DR , WILFINGER HANS-JOERG DR , SCHUCH GUNTER DR , HARDER WOLFGANG DR , KUEHN GEBHARD , PANITZ PAUL
IPC: C07C67/38 , B01J31/20 , C07B61/00 , C07C69/533
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公开(公告)号:DE3730186A1
公开(公告)日:1989-03-23
申请号:DE3730186
申请日:1987-09-09
Applicant: BASF AG
Inventor: KUMMER RUDOLF DR , SCHNEIDER HEINZ-WALTER DR , BERTLEFF WERNER DR , FISCHER ROLF DR , VAGT UWE DR
IPC: C07D315/00
Abstract: 5-Methylbutyrolactone is prepared from pentenoic acid esters by reacting these either directly with water and acidic catalysts or first hydrolysing the ester using acidic ion exchangers as catalysts and cyclising the pentenoic acids in a second step.
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公开(公告)号:DE3628357A1
公开(公告)日:1988-02-25
申请号:DE3628357
申请日:1986-08-21
Applicant: BASF AG
Inventor: BERTLEFF WERNER DR , KUMMER RUDOLF DR , MAERKL ROBERT DR
IPC: C07C67/38 , C07C67/00 , C07C67/48 , C07C67/54 , C07C67/60 , C07C69/02 , C07C69/34 , C07C69/44 , C07C69/533 , C07D211/70 , C07D213/06
Abstract: Aqueous solutions which are obtained in the carbalkoxylation of olefinically unsaturated compounds and contain heterocyclic aromatic nitrogen bases, their transformation products and lower fatty acids and/or their salts are treated by a process in which (a) the aqueous solution is heated to 150 DEG -300 DEG C. under from 10 to 300 bar and (b) heterocyclic aromatic nitrogen bases which are formed again from the transformation products are then separated off.
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公开(公告)号:DE3627776A1
公开(公告)日:1988-02-18
申请号:DE3627776
申请日:1986-08-16
Applicant: BASF AG
Inventor: MAERKL ROBERT DR , BERTLEFF WERNER DR , KUMMER RUDOLF DR
IPC: C07B61/00 , B01J31/00 , B01J31/20 , B01J31/24 , C07C41/00 , C07C41/48 , C07C43/315 , C07C67/00 , C07D317/22 , C07D319/06 , C07D321/06 , C07C41/30
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