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    1.
    发明专利
    未知

    公开(公告)号：ES2054111T3

    公开(公告)日：1994-08-01

    申请号：ES90101449

    申请日：1990-01-25

    Applicant: BASF AG

    Inventor： BERTLEFF WERNER DR ,  KOEFFER DIETER DR

    IPC: B01J31/20 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02

    Abstract: Preparation of 2,2-dialkylpropionaldehydes I … … in which R and R stand for C1- to C4-alkyl groups, by hydroformylation of 1,1-dialkylethylenes II … … with cobalt carbonyl complexes by… (a) carrying out the reaction in the presence of water-containing solvents in which water is soluble or at least partially soluble, the water content of the reaction mixture being between 0.1 and 20% by weight, or… (b) carrying out the reaction in the presence of a lactone which can carry one or more C1- to C4-alkyl groups as substituents, or of an aliphatic or cycloaliphatic sulphone.

    2.
    发明专利
    未知

    公开(公告)号：DE59001085D1

    公开(公告)日：1993-05-06

    申请号：DE59001085

    申请日：1990-01-25

    Applicant: BASF AG

    Inventor： BERTLEFF WERNER DR ,  KOEFFER DIETER DR

    IPC: B01J31/20 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02

    Abstract: Preparation of 2,2-dialkylpropionaldehydes I … … in which R and R stand for C1- to C4-alkyl groups, by hydroformylation of 1,1-dialkylethylenes II … … with cobalt carbonyl complexes by… (a) carrying out the reaction in the presence of water-containing solvents in which water is soluble or at least partially soluble, the water content of the reaction mixture being between 0.1 and 20% by weight, or… (b) carrying out the reaction in the presence of a lactone which can carry one or more C1- to C4-alkyl groups as substituents, or of an aliphatic or cycloaliphatic sulphone.

    6.
    发明专利
    未知

    公开(公告)号：DE3869265D1

    公开(公告)日：1992-04-23

    申请号：DE3869265

    申请日：1988-08-04

    Applicant: BASF AG

    Inventor： HOELDERICH WOLFGANG DR ,  KOEFFER DIETER DR ,  BERTLEFF WERNER DR

    IPC: C07C41/28 ,  C07C43/15

    Abstract: Dialkoxyethenes of formula R1O-CR2:CR3-OR4 (I) are produced by cleavage of alcohols R4OH or R5OH from trialkoxyethanes of formula R1O-CHR2-CR3(OR5)-OR4 (II) in the presence of zeolites and/or phosphates and/or phosphoric or boric acid on a support material as catalysts. In the formulae, R1, R4, R5 are opt. branched alkyl or cycloalkyl; R2, R3 are alkyl or cycloalkyl as above, or H, aryl or alkenylaryl (opt. with aromatic gp. substd. with alkyl, alkoxy, Hal, etc.). 1,2-Dimethoxyethene (III) is made by cleavage of MeOH from 1,1,2-trimethoxyethane (IV) using the above, or acidic untreated metal oxides as catalysts, catalysts are pentasil-type zeolites esp. B, Fe or Al silicate zeolites or Y-type Al silicate zeolites, pref. doped with alkali, transition or rare earth metals or hydrothermally-produced phosphates of B, Al, Zr, Fe, Sr, esp. Al, Si/Al, Si/Fe/Al or B/Al phosphate or phosphoric or boric acid on a SiO2, Al2O3 or TiO2 support, or untreated acidic oxides of Ti, Zr, Si, V, W, Nb or Cr; reaction is carried out in the gas phase.

    7.
    发明专利
    未知

    公开(公告)号：DE3900207A1

    公开(公告)日：1990-07-12

    申请号：DE3900207

    申请日：1989-01-05

    Applicant: BASF AG

    Inventor： BOECKH DIETER DR ,  SEELMANN-EGGEBERT HANS-PETER D ,  HARTMANN HEINRICH DR ,  KOEFFER DIETER DR ,  TRIESELT WOLFGANG DR ,  KUD ALEXANDER DR ,  BAUR RICHARD DR

    IPC: C08F8/00 ,  C08F222/04 ,  C11D3/37

    Abstract: Pulverulent and liquid detergents contain (1) one or more anionic surfactants, one or more nonionic surfactants or mixtures thereof and (2) copolymers in amounts of from 0.1 to 15% by weight preparable by copolymerization of (a) from 10 to 55 mol % of a 1,2-di-C1-C4-alkoxyethylene, (b) from 10 to 60 mol % of a monoethylenically unsaturated dicarboxylic anhydride of from 4 to 8 carbon atoms, (c) from 0 to 60 mol % of a monoethylenically unsaturated C3-C8-monocarboxylic acid and (d) from 0 to 20 mol % of another monoethylenically unsaturated monomer and subsequent hydrolysis of the anhydride groups of the copolymerized monomer (b) or reaction of these groups with an alcohol or an amine. Preferred copolymers contain 1,2 dimethoxyethylene as the (a) monomer, maleic acid as the (b) monomer, and acrylic acid as the (c) monomer.

    9.
    发明专利
    未知

    公开(公告)号：DE58908552D1

    公开(公告)日：1994-12-01

    申请号：DE58908552

    申请日：1989-06-02

    Applicant: BASF AG

    Inventor： BERTLEFF WERNER DR ,  KOEFFER DIETER DR ,  KLAEUI WOLFGANG PROF DR ,  SONG CHOONG-EUI LEE

    IPC: B01J31/22 ,  B01J31/16 ,  B01J31/18 ,  C07B61/00 ,  C07C1/00 ,  C07C2/48 ,  C07C5/03 ,  C07C5/08 ,  C07C13/18 ,  C07C45/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/00 ,  C07C67/347 ,  C07C69/76 ,  C07F15/00 ,  C07F15/06

    Abstract: Transition metal complexes of the general formula I [A]x- [Q]+xI where Q is one equivalent of a cation, x is from 0 to 2 and A is a transition metal complex of the general formula A where n is from 1 to 3, M is positively charged cobalt, rhodium, iridium or ruthenium, the ligands B are phosphonic, arsonic, phosphinic and/or arsinic acid ligands which are esterified with identical or different alcohols, one or more of these alcohol components carrying a functional group, L is the radicals R5 are identical or different radicals from the group consisting of C1-C4-alkyl and phenyl, p is an integer from 0 to 6, q is an integer from 0 to 5, and R1 is fluorine, chlorine, bromine, iodine, cyanide, isocyanide, cyanate, isocyanate, thiocyanate, isothiocyanate, C1-C4-alkyl, C1-C4-trialkyl phosphite or triaryl phosphite, are used as catalysts, or prepared in situ, in processes for the cyclotrimerization of acetylene compounds, for the catalytic hydrogenation of unsaturated compounds and for the hydroformylation of alkenes.

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