公开(公告)号：AP2007004270A0

公开(公告)日：2007-12-31

申请号：AP2007004270

申请日：2006-05-31

Applicant: BASF AG

Inventor： DECKERS ANDREAS ,  SCHNEIDER THOMAS ,  MENIG HELMUTH

IPC: C01C3/10

公开(公告)号：AR057345A1

公开(公告)日：2007-11-28

申请号：ARP060102309

申请日：2006-06-02

Applicant: BASF AG

Inventor： DECKERS ANDREAS ,  SCHNEIDER THOMAS ,  MENIG HELMUTH

IPC: C01C3/10 ,  C01C3/00 ,  C01C3/08

Abstract: Un proceso para preparar una solucion de sales de cianuro, que comprende las etapas de: a) preparar un gas crudo que comprende ácido cianhídrico por deshidratacion de formamida hasta una conversion de la formamida de mayor o igual 97%; b) de ser apropiado, cepillar con ácido el gas crudo obtenido en la etapa a); c) posteriormente hacer reaccionar el gas crudo obtenido en la etapa a) o, de ser apropiado, en la etapa b) con una solucion acuosa de un hidroxido, M(OH)x, donde M está seleccionado de oxidacion de M y es 1 o 2.

公开(公告)号：PE00582007A1

公开(公告)日：2007-02-04

申请号：PE0006142006

申请日：2006-06-05

Applicant: BASF AG

Inventor： DECKERS ANDREAS ,  SCHNEIDER THOMAS ,  MENIG HELMUTH

IPC: C01C3/08 ,  C01C3/10

CPC classification number: C01C3/08 ,  C01C3/10

Abstract: QUE COMPRENDE: a) PREPARAR UN GAS CRUDO QUE COMPRENDE ACIDO CIANHIDRICO POR DESHIDRATACION DE FORMAMIDA HASTA UNA CONVERSION DE LA FORMAMIDA MAYOR O IGUAL A 97%, EN UN REACTOR EN PRESENCIA DE AIRE U OXIGENO Y A UNA TEMPERATURA ENTRE 300°C Y 650°C; b) DE SER APROPIADO, LAVAR CON ACIDO SULFURICO EL GAS CRUDO OBTENIDO EN (a); Y, c) HACER REACCIONAR EL GAS CRUDO OBTENIDO EN (a), O DE SER APROPIADO DE (b), CON UNA SOLUCION ACUOSA DE UN HIDROXIDO M(OH)x, DONDE M ES SELECCIONADO DEL GRUPO QUE CONSISTE EN METALES ALCALINOS Y METALES ALCALINOTERREOS, TAL COMO Li, Na Y K, Y x DEPENDE DEL ESTADO DE OXIDACION DE M Y ES 1 o 2. LA SOLUCION ACUOSA EN (c) COMPRENDE DE 5% A 50% EN PESO DE HIDROXIDO, Y (c) SE LLEVA A CABO A UNA TEMPERATURA DE 5°C A 100°C

公开(公告)号：AU2003293755A1

公开(公告)日：2004-06-23

申请号：AU2003293755

申请日：2003-12-03

Applicant: BASF AG

Inventor： BASSLER PETER ,  SIEGEL WOLFGANG ,  ACHHAMMER GUNTHER ,  NEGELE ANTON ,  MENIG HELMUTH ,  RUPPEL WILHELM ,  ZEHNER PETER ,  LUYKEN HERMANN ,  VOGT VOLKER

IPC: B01J12/00 ,  B01J15/00 ,  B01J19/02 ,  B01J19/24 ,  B01J23/86 ,  C01C3/02

公开(公告)号：ES2167027T3

公开(公告)日：2002-05-01

申请号：ES97953760

申请日：1997-12-09

Applicant: BASF AG

Inventor： FETZER THOMAS ,  DEMUTH DIRK ,  RUTTER HEINZ ,  MENIG HELMUTH ,  RESCH PETER ,  RUPPEL WILHELM

IPC: B01J23/72 ,  C07C45/38 ,  C07C45/39 ,  C07C47/127

Abstract: PCT No. PCT/EP97/06856 Sec. 371 Date Jun. 16, 1999 Sec. 102(e) Date Jun. 16, 1999 PCT Filed Dec. 23, 1997 PCT Pub. No. WO98/28251 PCT Pub. Date Jul. 2, 1998In a process for preparing carbonyl compounds of the formula where R1 is a hydrogen atom or an alkyl radical having from 1 to 3 carbon atoms, R2 is a hydrogen atom or a radical of the formula where R3 is a hydrogen atom or together with R4 is an oxygen atom, R4 is the radical OR6 or together with R3 is an oxygen atom, R5 is a hydrogen atom, an alkyl radical having from 1 to 8 carbon atoms or a cyclohexyl or cyclopentyl radical and R6 is an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CHO or -CH2-CH2-O-CH2-CHO, by gas-phase oxidation of methanol or alcohols of the formula where R1 and R5 are as defined above and R7 is a hydrogen atom or a radical OR8 and R8 is a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical for the formula -CH2-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, using an oxygen-containing gas in the presence of copper- and/or silver-containing catalysts and an amount of a phosphorus compound which is volatile under the reaction conditions which is such that the amount of phosphorus (calculated as P) is up to 20 ppm, based on the weight of alcohol used, the phosphorus is introduced within the catalyst bed.

公开(公告)号：ES2164379T3

公开(公告)日：2002-02-16

申请号：ES97953759

申请日：1997-12-09

Applicant: BASF AG

Inventor： FETZER THOMAS ,  DEMUTH DIRK ,  RUTTER HEINZ ,  MENIG HELMUTH ,  RESCH PETER ,  RUPPEL WILHELM

IPC: C07B61/00 ,  C07C45/38 ,  C07C45/39 ,  C07C47/127

Abstract: PCT No. PCT/EP97/06855 Sec. 371 Date Jun. 16, 1999 Sec. 102(e) Date Jun. 16, 1999 PCT Filed Dec. 9, 1997 PCT Pub. No. WO98/28250 PCT Pub. Date Jul. 2, 1998The present invention relates to a process for the preparation of carbonyl compounds of the formula in which R1 denotes a hydrogen atom or an alkyl radical containing from 1 to 3 carbon atoms, R2 denotes a hydrogen atom or a radical of the formula in which R3 denotes a hydrogen atom or, together with R4, an oxygen atom, R4 denotes the radical OR6 or, together with R3, an oxygen atom, R5 denotes a hydrogen atom or an alkyl radical containing from 1 to 8 carbon atoms or a cyclohexyl or cyclopentyl radical, and R6 denotes an alkyl radical containing from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CHO or -CH2-CH2-O-CH2-CHO, by gas-phase oxidation of methanol or alcohols of the formula in which R1 and R5 have the meanings specified above and R7 denotes a hydrogen atom or a radical OR8, and R8 denotes a hydrogen atom, an alkyl radical containing from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, using an oxygen-containing gas in the presence of a (copper and/or silver)-containing catalyst and a phosphorus compound which is volatile under the conditions of the reaction and is present in an amount such that the weight of phosphorus (calculated as P), based on the weight of alcohol used, is not more than 20 ppm, wherein the amount of phosphorus used is divided into at least two portions, of which a) the first portion is added together with the mixture of gaseous starting materials before this reaches the catalyst bed and b) at least one further portion is added within the catalyst bed.

公开(公告)号：CA2274489A1

公开(公告)日：1998-07-02

申请号：CA2274489

申请日：1997-12-09

Applicant: BASF AG

Inventor： FETZER THOMAS ,  RUPPEL WILHELM ,  WACHE HARRO ,  DEMUTH DIRK ,  MENIG HELMUTH ,  RUETTER HEINZ ,  RESCH PETER

IPC: C07B61/00 ,  C07C45/38 ,  C07C45/39 ,  C07C47/127

Abstract: The invention relates to a method for producing carbonyl compounds of formula (I), in which R1 is a hydrogen atom or alkyl radical with between 1 and 3 C atoms; R2 is a hydrogen atom or a radical of formula (II), in which R3 is a hydrogen atom or, together with R4, an oxygen atom; R4 is the radical OR6 or, together with R3, an oxygen atom; R5 is a hydrogen atom, an alkyl radical with between 1 and 8 C atoms or a cyclohexyl or cyclopentyl radical; and R6 is an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CHO or -CH2-CH2-O-CH2-CHO. According to said method, the carbonyl compounds are produced by gas phase oxidation of methanol or alcohols of formula (III), in which R1 and R5 have the meaning assigned above and R7 is a hydrogen atom or an OR8 radical, and R8 is a hydrogen atom, an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, with a gas containing oxygen, in the presence of catalysts containing copper and/or silver, and a phosphorus compound which is volatile under reaction conditions in such a quantity that the amount of phosphorus (calculated as P), in relation to the part by weight of alcohol used, is up to 20 ppm. Said method is characterized in that the quantity of phosphorus is added in at least two parts: a) the first part is added with the gaseous starting mixture before the catalyst bed, and b) at least one other part is added in the catalyst bed.