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公开(公告)号:FR1317721A
公开(公告)日:1963-02-08
申请号:FR891170
申请日:1962-03-15
Applicant: BASF AG
Inventor: HERRLE KARL , ZUERN LUDWIG , SCHMIDT OSWALD , MERTENS HEINRICH , HEIMANN SIGISMUND
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22.
公开(公告)号:GB891217A
公开(公告)日:1962-03-14
申请号:GB3238260
申请日:1960-09-21
Applicant: BASF AG
Inventor: MERTENS HEINRICH , STADLER JOSEF
IPC: D06M13/364
Abstract: Wool and wool-containing textiles are shrink-proofed and felt-proofed by treating them with dichlorcyanuric acid and/or trichlorcyanuric acid in an alkaline aqueous solution or suspension. The treatment bath preferably contains 5.5%-14% by weight of dichlorcyanuric acid or 4.5%-11% by weight of trichlorcyanuric acid or mixtures thereof in an amount corresponding to 2%-5% of active chlorine with reference to the weight of the treated material, and the pH of the bath is preferably adjusted to above 7 by the addition of buffer substances, e.g. borax and alkali-metal phosphates. The bath may also contain other oxidising agents, e.g. salts of monopersulphuric, dipersulphuric, peracetic and perbenzoic acids, inorganic salts, e.g. sodium chloride, sodium bromide, sodium sulphate, calcium chloride, magnesium sulphate and zinc sulphate and/or organic salts, e.g. the alkali and alkaline-earth metal salts of acetic acid and ethylenediamino tetracetic acid, and wetting agents. The treatment may be carried out at room or elevated temperature, e.g. 20 DEG C.-40 DEG C., for about an hour and the material may then be rinsed with cold water and treated with a reductive or oxidative dechlorination bath, e.g. an alkaline metal bisulphite or dithionite, a salt of a hydroxyalkane sulphinic acid or a reaction product of such an acid with ammonia or hydrogen peroxide.
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公开(公告)号:FR1274708A
公开(公告)日:1961-10-27
申请号:FR840136
申请日:1960-10-03
Applicant: BASF AG
Inventor: MERTENS HEINRICH , STADLER JOSEF
IPC: D06M13/364
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公开(公告)号:FR1271349A
公开(公告)日:1961-09-08
申请号:FR839509
申请日:1960-09-26
Applicant: BASF AG
Inventor: MERTENS HEINRICH , STADLER JOSEF
IPC: D06M13/364
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公开(公告)号:FR1248251A
公开(公告)日:1960-12-09
申请号:FR817551
申请日:1960-02-04
Applicant: BASF AG
Inventor: ADAM KARL , MERTENS HEINRICH , SCHMIDT OSWALD
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公开(公告)号:FR1244154A
公开(公告)日:1960-10-21
申请号:FR814593
申请日:1959-12-31
Applicant: BASF AG
Inventor: MERTENS HEINRICH , SCHMIDT OSWALD , ADAM KARL
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公开(公告)号:BE590794A
公开(公告)日:1960-09-01
申请号:BE590794
申请日:1960-05-13
Applicant: BASF AG
Inventor: STILZ WALTER , POMMER HORST , GEHM ROBERT , SCHMIDT OSWALD , MERTENS HEINRICH , HEHL MANFRED , GRUNWALD WOLFGANG
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公开(公告)号:BE586775A
公开(公告)日:1960-05-16
申请号:BE586775
申请日:1960-01-20
Applicant: BASF AG
Inventor: GEHM ROBERT , SCHMIDT OSWALD , MERTENS HEINRICH , GRUNWALD WOLFGANG , HEHL MANFRED
IPC: C07D251/68 , D06M
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公开(公告)号:DK344686A
公开(公告)日:1987-01-23
申请号:DK344686
申请日:1986-07-21
Applicant: BASF AG
Inventor: FIKENTSCHER ROLF , HEIMANN SIGISMUND , MERTENS HEINRICH , SCHNEIDER SIEGFRIED , VESCIA MICHELE
Abstract: Dyeings with reactive dyes on cellulose fiber materials are after-treated with an aqueous solution of a condensate which is obtainable by reacting (a) bisbenzylpiperzine with (b) ethylene chloride, an epihalohydrin, propylene chloride, 1,3-dichloro-2-hydroxypropane, bisepoxybutane or 1,4-dichlorobutane or a mixture of these, in a molar ratio of from 1:0.5 to 1:1.1, or by reacting (c) piperazine, bis-1,4-aminopropylpiperazine, 1-aminoethylpiperazine, 2-hydroxyethylpiperazine or 1-methylpiperazine, or a mixture of these, with a compound according to (b) in a molar ratio of from 1:0.5 to 1:1.1 and benzylating the condensate, the benzylation being carried out using 0.15-1.0 mole of benzyl chloride per equivalent of nitrogen in component (c). The cellulose fiber materials after-treated in this manner possess very good wetfastness.
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公开(公告)号:ZA853503B
公开(公告)日:1986-01-29
申请号:ZA853503
申请日:1985-05-09
Applicant: BASF AG
Inventor: FIKENTSCHER ROLF , MERTENS HEINRICH , REINCKE KLAUS , VESCIA MICHELE
IPC: D06M13/46 , C08G59/50 , C08G73/02 , D06M13/02 , D06M13/322 , D06M13/47 , D06M13/477 , D06M15/61 , D06M101/00 , D06M101/02 , D06M101/10 , D06M101/16 , D06M101/30 , D06M101/34 , D06P1/52 , D06P5/06 , D06P5/08 , D06P , D06M
Abstract: Textile materials of natural polyamides or nylons, dyed with a dye containing acid groups, are after-treated with a dilute aqueous solution of a cationic condensate which is obtained by reaction of (a) piperazine or a derivative of piperazine with (b) a bifunctional crosslinking agent, such as an epihalohydrin, in a molar ratio of from 1:0.5 to 1:1.1, and quaternization of the condensate with benzyl chloride, from 0.15 to 1.0 mole of benzyl chloride being employed per equivalent of nitrogen in the component (a) during the quaternization. This after-treatment improves the wetfastness of the dye.
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