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公开(公告)号:DE19725519A1
公开(公告)日:1998-12-24
申请号:DE19725519
申请日:1997-06-17
Applicant: BASF AG
Inventor: SUTORIS HEINZ FRIEDRICH DR , MITULLA KONRAD DR , DUPUIS JACQUES DR , KALIBA CLAUS DR
IPC: C07B63/04 , C07C7/20 , C07C15/46 , C09K15/20 , C09K15/30 , C09K15/32 , C07C15/44 , C07C211/45 , C07C205/06 , C07D211/92
Abstract: The invention relates to a mixture of substances containing one or several compounds with vinyl groups as constituent (A) and a stabilizer (B) as another constituent containing one or several easily volatile nitroxyl compounds as constituent (b1), one or several non-easily volatile nitroxyl compounds as constituent (b2), optionally one or several aromatic nitro compounds as constituent (b3) and optionally one or several iron compounds as constituent (b4). The invention also relates to stabilizers (B) containing constituents (b1) and (b2), (b1) and (b2) and (b3), (b1) and (b2) and (b4), in addition to (b1), (b2), (b3) and (b4). The invention further relates to a method for inhibiting premature polymerization of compounds with vinyl groups during the cleaning thereof or distillation by adding a stabilizer (B), or by adding the constituents of stabilizer (B) as individual substances or in at least two groups of constituents.
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公开(公告)号:DE3776919D1
公开(公告)日:1992-04-09
申请号:DE3776919
申请日:1987-01-16
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , HUB HANS-HENNING DR , MITULLA KONRAD DR , KNOLL MANFRED
IPC: C08L67/00 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/02 , C08L69/00
Abstract: Thermoplastic moulding materials (I), and moulded bodies obtd. therefrom, are claimed. (I) comprise polycarbonates (II) and polyesters (III), with 1-30 wt.% of a graft copolymer (IV) contg. 60-99 wt.% (meth)acrylate or diene elastomer (opt. with other comonomers), grafted with 1-40 wt.% epoxy gp.-contg. monomer. Pref. (I) contain an impact toughness-modifying rubber. Pref. amts. are 8-90 wt.% (II), 8-90 wt.% (III), and 2-30 wt.% (IV).
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公开(公告)号:DE3776234D1
公开(公告)日:1992-03-05
申请号:DE3776234
申请日:1987-08-20
Applicant: BASF AG
Inventor: MITULLA KONRAD DR , SEILER ERHARD DR , SCHMITT BURGHARD PROF DR , SIEBEL HANS PETER DR , JUNG RUDOLF H DR , SCHARF BERNHARD DR
IPC: C08F279/02 , C08F285/00 , C08L25/12 , C08L51/00 , C08L51/04 , C08L55/02
Abstract: Thermoplastic moulding materials comprises (A) 1-70 wt.% (w.r.t. A+B) of a graft copolymer comprising an elastomer a1 and a shell a2 grafted onto the elastomer, the elastomer a1 consisting of butadiene alone or a copolymer of butadiene with up to 30 wt.% on a1 of styrene or acrylonitrile and having an ave. particle size of 100-750 micrometres (d50-value of the integral wt. distribution), and making up 90-50 wt.% of (A), and the shell a2 being made up of at least one 8-12C vinyl aromatic monomer (a22) and at least one monoethylenically unsatd. monomer (a23), and making up 10-50 wt.% of (A); and (B) 99-30 wt.% (w.r.t. A+B) of a copolymer hard matrix comprising (b1) at least one 8-12C vinylaromatic monomer and (b2) at least one mono-ethylenically unsatd. monomer. The grafted shell a2 is made in two stages in which (1) in a first stage, 5-50 wt.% w.r.t. a2) exclusively of the vinyl aromatic monomer is graft polymerised and (2) in a second stage 50-95 wt.% (w.r.t. a2) of a mixt. of a22 and the monomer a23 in a wt. ratio of 90:10 to 66:34 is graft polymerised in the presence of the elastomer a1.
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公开(公告)号:DE3766924D1
公开(公告)日:1991-02-07
申请号:DE3766924
申请日:1987-09-18
Applicant: BASF AG
Inventor: BRANDT HERMANN DR , MITULLA KONRAD DR , DREHER HERMANN DR , LEBER LUDGER DR , HAMBRECHT JUERGEN DR
IPC: C08G65/46
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公开(公告)号:DE3671238D1
公开(公告)日:1990-06-21
申请号:DE3671238
申请日:1986-06-19
Applicant: BASF AG
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公开(公告)号:DE3670093D1
公开(公告)日:1990-05-10
申请号:DE3670093
申请日:1986-09-30
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , MITULLA KONRAD DR , BOEHLKE KLAUS DR
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公开(公告)号:DE3477797D1
公开(公告)日:1989-05-24
申请号:DE3477797
申请日:1984-08-20
Applicant: BASF AG
Inventor: MITULLA KONRAD DR , SWOBODA JOHANN DR , ECHTE ADOLF DR , SCHMITT BURGHARD DR
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公开(公告)号:DE3632528A1
公开(公告)日:1988-03-31
申请号:DE3632528
申请日:1986-09-24
Applicant: BASF AG
Inventor: BRANDT HERMANN DR , MITULLA KONRAD DR , DREHER HERMANN DR , LEBER LUDGER DR , HAMBRECHT JUERGEN DR
IPC: C08G65/46
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公开(公告)号:DE3629150A1
公开(公告)日:1988-03-10
申请号:DE3629150
申请日:1986-08-27
Applicant: BASF AG
Inventor: MITULLA KONRAD DR , SEILER ERHARD DR , SCHMITT BURGHARD DR , SIEBEL HANS PETER DR , JUNG RUDOLF H DR , SCHARF BERNHARD DR
IPC: C08F279/02 , C08F285/00 , C08L25/12 , C08L51/00 , C08L51/04 , C08L55/02 , C08L25/00
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公开(公告)号:DE3535273A1
公开(公告)日:1987-04-09
申请号:DE3535273
申请日:1985-10-03
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , HAMBRECHT JUERGEN DR , MITULLA KONRAD DR
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