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公开(公告)号:DE3819744A1
公开(公告)日:1989-12-14
申请号:DE3819744
申请日:1988-06-10
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , BRANDT HERMANN DR , MUEHLBACH KLAUS DR , BOEHLKE KLAUS DR
Abstract: Thermoplastic moulding compounds containing A) polyphenylene ether, B) polyamide, C) 1 to 20 parts by weight of a di-block copolymer of a conjugated diene and an aromatic vinyl compound having a number average molecular weight between 400 and 20,000, and D) 0 to 80 parts by weight of a rubber, a process for its production, and shaped articles produced therefrom.
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公开(公告)号:DE3803458A1
公开(公告)日:1989-08-17
申请号:DE3803458
申请日:1988-02-05
Applicant: BASF AG
Inventor: MUEHLBACH KLAUS DR , BRANDT HERMANN DR , RUPPMICH KARL
IPC: C08L69/00
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公开(公告)号:DE3522470A1
公开(公告)日:1987-01-02
申请号:DE3522470
申请日:1985-06-22
Applicant: BASF AG
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公开(公告)号:DE3515516A1
公开(公告)日:1986-11-06
申请号:DE3515516
申请日:1985-04-30
Applicant: BASF AG
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公开(公告)号:DE3855553D1
公开(公告)日:1996-10-24
申请号:DE3855553
申请日:1988-12-10
Applicant: BASF AG
Abstract: The moulding compositions contain, based on A, B, C, D and E,… A) from 40 to 95% by weight of a thermoplastic, halogen-free, aromatic polycarbonate based on the diphenols of the formula (1) … … in which A is a single bond, C1-C3-alkylene, C2-C3-alkylidene, C3-C6- cycloalkylidene, -S- or -SO2-,… B) from 5 to 30% by weight of at least one halogen-free graft polymer built up from, based on B),… b1) from 40 to 80% by weight of an elastomer (rubber) and… b2) from 20 to 60% by weight of a graft shell on this elastomer, built up from, based on b2),… b2a1) from 50 to 95% by weight of styrene, alpha -methylstyrene, ring- substituted styrene, methyl methacrylate or mixtures thereof and… b2a2) from 50 to 5% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-substituted maleimide or mixtures thereof, C) from 5 to 50% by weight of at least one halogen-free, thermoplastic copolymer comprising, based on C,… from 50 to 95% by weight of styrene, alpha -methylstyrene, ring-substituted styrene, methyl methacrylate or mixtures thereof, and… from 50 to 5% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-substituted maleimide or mixtures thereof,… D) from 1 to 25% by weight of at least one halogen-free phosphorus compound of the formula … … in which R , R and R , independently of one another, are halogen-free C1-C8-alkyl or halogen-free C6-C20-aryl, and n is 0 or 1, and… E) from 0.05 to 5% by weight of a tetrafluoroethylene polymer,… and are characterised in that the elastomer b1) is prepared by polymerising a monomer mixture comprising… b1a1) from 70 to 99.9% by weight, based on b1), of at least one alkyl acrylate with 1 to 8 carbon atoms in the alkyl radical,… b1a2) from 0 to 30% by weight, based on b1), of at least one further copolymerisable, monoethylenically unsaturated monomer, and… b1a3) from 0.1 to 5% by weight, based on b1), of a copolymerisable, polyfunctional, crosslinking monomer. … The moulding compositions are used to produce mouldings.
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公开(公告)号:DE59007712D1
公开(公告)日:1994-12-22
申请号:DE59007712
申请日:1990-06-02
Applicant: BASF AG
Inventor: LEBER LUDGER DR , BRANDT HERMANN DR , OSTERMAYER BERTRAM DR , FISCHER HERMANN DR , GAUSEPOHL HERMANN DR
IPC: C08G65/44
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公开(公告)号:DE58905531D1
公开(公告)日:1993-10-14
申请号:DE58905531
申请日:1989-11-10
Applicant: BASF AG
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公开(公告)号:DE58905492D1
公开(公告)日:1993-10-14
申请号:DE58905492
申请日:1989-01-20
Applicant: BASF AG
Inventor: MUEHLBACH KLAUS DR , SCHARF BERNHARD DR , BRANDT HERMANN DR
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公开(公告)号:DE3923232A1
公开(公告)日:1991-01-24
申请号:DE3923232
申请日:1989-07-14
Applicant: BASF AG
Inventor: HEDTMANN-REIN CAROLA DR , BAUMGARTNER EHRENFRIED DR , OSTERMAYER BERTRAM DR , BRANDT HERMANN DR
IPC: C08G65/44
Abstract: Process is for prodn. of high-mol. wt. polyphenylene ethers. (I) from monohydric phenols with alkyl or aryl substits. in the 2 ortho positions or also in one meta position but not in the para position (II), by oxidative coupling with oxygen at 20-60 deg.C in the presence of a complex catalyst consisting of a Cu salt and an organic amine (III), in a 6-10C aromatic hydrocarbon solvent, and working up the polycondensate soln. obtd.; the novelty is that (III) is an amine of formula (I)-(V) (where R1-R6 = (1-(r-methylpiperidinyl) or Ph-CH2CH2CH2-; R2 = 1-2C alkyl; R3, R4, R5, R6 = H or 1-4C alkyl). Pref. (III) is piperazine or N,N'-dimethylpiperazine. USE/ADVANTAGE - (I) are used for prodn. of moulded components. The process enables the prodn. of high-mol. wt. (I) in a relatively short reaction time (w.r.t. prior-art processes), with smaller amts. of coloured by-prods., etc..
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公开(公告)号:DE3834085A1
公开(公告)日:1990-04-12
申请号:DE3834085
申请日:1988-10-07
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , LAUSBERG DIETRICH DR , BRANDT HERMANN DR
Abstract: Thermoplastic moulding compositions based on A) polyesters and B) polyphenylene ethers, characterised by a content of C) from 0.1 to 40% by weight, based on the sum of A, B and C, of a copolymer comprising c1) from 40 to 99.9 mol % of a vinylaromatic monomer, c2) from 0.1 to 60 mol % of a compound of the formula (I) wherein R is -OH, alkoxy, aryloxy, aralkoxy or alkylaryloxy having up to 25 carbon atoms or, together with R is -NR -, R is -H or, if R is -H, is alkyl, aryl, aralkyl or alkaryl having up to 25 carbon atoms or chlorine, R is -H or, if R is -H, is alkyl, aryl, aralkyl or alkaryl having up to 25 carbon atoms or chlorine, R is alkoxy, aryloxy, aralkoxy or alkylaryloxy having up to 25 carbon atoms or, together with R , is -NR -, and R is hydrogen or an alkyl, cycloalkyl, aralkyl or aryl group having up to 12 carbon atoms which itself may be substituted by C1-C4-alkyl or -alkoxy groups, and c3) from 0 to 20 mol % of further copolymerisable monomers, and the preparation and use thereof.k
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