Removal of sulhpur compounds from hydrocarbons

    公开(公告)号:GB845855A

    公开(公告)日:1960-08-24

    申请号:GB1459259

    申请日:1959-04-29

    Applicant: BASF AG

    Abstract: Crude liquid hydrocarbons are treated with alpha sodium sodium acetate (Na CH2, COO Na) to remove sulphur containing impurities. 0.1 5% wt. may be used. The alpha sodium sodium acetate may be activated by the addition of a similar amount of a mono-, di-or poly-hydric alkyl, aryl, aralkyl or cyclic alcohol e.g. methanol, isobutanol, dodecanol, glycol, glycerol, benzyl alcohol, cyclohexanol or hexylene glycol. The purified hydrocarbon may be separated from the sludge formed by distillation, filtration or centrifuging. Hydrocarbons specified are gasolines, diesel oils, jet fuels, distillate fuel oils coal tar distillate fractions and lubricating oils.

    Oil-soluble condensation products and a process for their production

    公开(公告)号:GB1102218A

    公开(公告)日:1968-02-07

    申请号:GB5451066

    申请日:1966-12-06

    Applicant: BASF AG

    Abstract: Oil soluble condensation products are prepared by interacting (a) 1 mole of a dialkyl benzene with (b) 1.5 mole to 6 mole of HCHO or an equivalent amount of a nitrogen-free formaldehyde generator at 70-180 DEG C., using an acid catalyst, neutralizing the product or washing out the acid and treating the product with (c) 10-40 times its weight of ethylene oxide or propylene oxide. The alkyl groups in (a) may contain up to 20 carbon atoms. (a) and (b) may be reacted in the presence of 1 mole of H2SO4 as catalyst. The second reaction may be under a pressure of 2-20 atmospheres in the presence of a caustic alkali as initiator and an inert solvent. Both reactions may be effected under an inert atmosphere and (a), (b) and/or (c) may be replaced by mixtures of reactants. In an example formalin and di-isopropylbenzene are interacted and the product dissolved in diisopropylbenzene. KOH is added as initiator followed successively by propylene oxide and ethylene oxide. The product is extracted from the solvent and dissolved in a mixture of di- and mono-methyl naphthalene.

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