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    21.
    发明专利
    未知

    公开(公告)号：DE4132172A1

    公开(公告)日：1993-04-01

    申请号：DE4132172

    申请日：1991-09-27

    Applicant: BASF AG

    Inventor： NIESSNER NORBERT DR ,  NEUMANN RAINER DR ,  RUPPMICH KARL ,  SEITZ FRIEDRICH DR ,  ZELTNER DORIS DR

    IPC: C08K5/521 ,  C08K3/00 ,  C08L43/00 ,  C08L43/02 ,  C08L51/04 ,  C08L69/00

    Abstract: A moulding composition containing, based on the total amount of A to E, …… A: at least 40% by weight of at least one halogen-free polycarbonate A, … B: 5-40% by weight of at least one halogen-free graft polymer B built up from, based on B, …… B1: 40-80% by weight of an elastomer B1 having a glass transition temperature of below 0 DEG C and comprising, based on B1, …… B11: at least 50% by weight of a diene or an acrylate containing at least 4 carbon atoms in the alcohol moiety (B11), … B12: 1-40% by weight of a halogen-free phosphorus compound B12 of the following formula (I) … … in which …… R is H or CH3, … R and R are each, independently of one another, halogen-free C1-C8-alkyl or halogen-free C6-C20-aryl which is optionally substituted by halogen-free substituents, … X , X and X are O, S or NR (where R is hydrogen or halogen-free C1-C8-alkyl), and … n is from 0 to 10, …… B13: optionally up to 5% by weight of a further, crosslinking monomer, …… B2: 20-60% by weight of a graft shell B2 comprising, based on B2, …… B21: 40-98% by weight of styrene, alpha -alkylstyrene, ring-substituted styrene and/or C1-C8-alkyl (meth)acrylate, … B22: 2-60% by weight of (meth)acrylonitrile and/or maleic anhydride, …… … C: 5-40% by weight of a halogen-free, thermoplastic copolymer C comprising, based on C, …… C1: from 50 to 95% by weight of styrene, alpha -alkyl styrene, ring-substituted styrene and/or C1-C8-(meth)acrylates (C1), … C2: from 5 to 50% by weight of (meth)acrylonitrile and/or maleic anhydride (C2), …… D: from 1 to 50% by weight of a halogen-free phosphorus compound D of the formula (II) … … in which R , R and R are each, independently of one another, as defined above for R and R , … E: up to 5% by weight of a tetrafluoroethylene polymer having a mean particle size of from 50 to 2,000 nm. …

    22.
    发明专利
    未知

    公开(公告)号：DE3939046A1

    公开(公告)日：1991-05-29

    申请号：DE3939046

    申请日：1989-11-25

    Applicant: BASF AG

    Inventor： NEUMANN RAINER DR ,  BAUMGARTNER EHRENFRIED DR ,  BENKER KLAUS ,  RUPPMICH KARL

    IPC: C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L69/00

    Abstract: The thermoplastic moulding compositions comprise from 20 to 80% by weight of a polycarbonate A; from 10 to 60% by weight of a thermoplastic copolymer B comprising, in each case based on B, from 70 to 90% by weight of styrene, alpha -methylstyrene or a ring-alkylated styrene, and from 10 to 30% by weight of (meth)acrylonitrile; from 5 to 30% by weight of a graft copolymer C comprising, in each case based on C, from 20 to 60% by weight of a polybutadiene rubber c1 from 80 to 40% by weight of a shell c2 grafted thereto and comprising, in each case based on c2, either from 70 to 90% by weight of styrene c21 and from 10 to 30% by weight of (meth)acrylonitrile c22, or of a shell c2 comprising from 15 to 40% by weight of styrene c23, from 85 to 60% by weight of methyl methacrylate c24 and up to 3% by weight of glycidyl methacrylate c25; from 5 to 30% by weight of a graft copolymer D comprising, in each case based on D, from 20 to 60% by weight of a crosslinked acrylate rubber d1, from 80 to 40% by weight of a shell d2 grafted thereto and comprising, in each case based on d2, from 70 to 90% by weight of styrene d21 and from 10 to 30% by weight of (meth)acrylonitrile d22, with the proviso that the graft copolymer C has a mean particle diameter of from 0.2 to 0.5 mu m and the graft copolymer D has a mean particle diameter of from 0.4 to 0.7 mu m, in each case determined as the d50 value of the cumulative weight distribution.

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