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    TABLEWARE FORMED OUT OF HIGHLY FUNCTIONAL THERMOPLASTIC RESIN
    1.
    发明专利
    TABLEWARE FORMED OUT OF HIGHLY FUNCTIONAL THERMOPLASTIC RESIN 失效

    公开(公告)号：JPH1057215A

    公开(公告)日：1998-03-03

    申请号：JP13019297

    申请日：1997-05-21

    Applicant: BASF AG

    Inventor： AHLERS JUERGEN ,  BAUMGARTNER EHRENFRIED DR ,  WOLF PETER DR ,  HEEL HELMUT DR

    IPC: A47G19/00 ,  A47G21/00 ,  C08G75/23 ,  C08L71/00

    Abstract: PROBLEM TO BE SOLVED: To keep neutrality in taste and allow both of cleaning and washing processes to be repeated by making tableware using a composition formed out of highly func tional thermoplastic resin and irradiating a high energy radiation thereto. SOLUTION: Highly functional thermoplastic resin to be used, or polyarylene ether has a repetition unit I, and is expressed as shown in the formula, where (t) and (q) have a value between 0 and 3, and T, Q and Z are independent of one another. The amount of highly functional thermoplastic resin A contained in a composition is advantageously between 1 and 100wt.%, preferably between 10 and 90wt.% and particularly between 30 and 70wt.%. Also, the residue of the composition contains a thermosetting polymer B existing by volume advantageously between 0 and 99wt.%, preferably between 5 and 80wt.% and particularly between 10 and 60wt.%, and at the same time, other additives and a processing assistant C existing by a volume advantageously between 0 and 70wt.%, preferably between 5 and 60wt.% and particularly between 10 and 40wt.%. A laser to be used in this case is a CO2 laser (wavelength: 10.6μm) having a frequency multiplier (wavelength: 532, 355 and 256nm), preferably an excimer laser.

    5.
    发明专利
    未知

    公开(公告)号：DE3889303D1

    公开(公告)日：1994-06-01

    申请号：DE3889303

    申请日：1988-11-30

    Applicant: BASF AG

    Inventor： OSTERMAYER BERTRAM DR ,  BAUMGARTNER EHRENFRIED DR ,  BUESCHL RAINER DR ,  BRANDT HERMANN DR ,  BOEHLKE KLAUS DR ,  SEILER ERHARD DR ,  MCKEE GRAHAM EDMUND DR

    IPC: C08L25/04 ,  C08L51/04 ,  C08L71/12 ,  C08L77/00

    Abstract: Reinforced thermoplastic molding materials containing, as essential components, (A) from 40 to 94 parts by weight of a polymer component of (a1) from 10 to 90% by weight of polyphenylene ether and (a2) from 10 to 90% by weight, based in each case on A, of a styrene polymer toughened with an acrylate rubber or with an unhydrogenated or hydrogenated polymer of a conjugated diene, (B) from 1 to 20 parts by weight of a copolymer of (b1) from 70 to 99.9% by weight of a monomer from the group consisting of styrene, alpha -methylstyrene and styrene alkylated in the nucleus or a mixture of these monomers, (b2) from 0.1 to 30% by weight of one or more compounds from the group consisting of tert-butyl acrylate and tert-butyl methacrylate, or one or more compounds from the group of compounds of the general formula I I where R1 is hydrogen or methyl and R2, R3 and R4 are each an alkyl or alkoxy group of not more than 4 carbon atoms, or of the general formula II II where n is an integer from 1 to 4 and R5, R6 and R7 are each one of the radicals stated for R2 or are each -O(CH2-CH2-O)mR8, where R8 is C1-C4-alkyl and m is 1, 2, 3 or 4, and (b3) from 0 to 10% by weight, based on the copolymer, of a further ethylenically unsaturated monomer which is copolymerizable with b1 and b2, and (C) from 5 to 50 parts by weight of a reinforcing agent, the number of parts by weight being based on 100 parts by weight of the sum of A, B and C, are prepared and used for the production of moldings.

    6.
    发明专利
    未知

    公开(公告)号：DE3939046A1

    公开(公告)日：1991-05-29

    申请号：DE3939046

    申请日：1989-11-25

    Applicant: BASF AG

    Inventor： NEUMANN RAINER DR ,  BAUMGARTNER EHRENFRIED DR ,  BENKER KLAUS ,  RUPPMICH KARL

    IPC: C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L69/00

    Abstract: The thermoplastic moulding compositions comprise from 20 to 80% by weight of a polycarbonate A; from 10 to 60% by weight of a thermoplastic copolymer B comprising, in each case based on B, from 70 to 90% by weight of styrene, alpha -methylstyrene or a ring-alkylated styrene, and from 10 to 30% by weight of (meth)acrylonitrile; from 5 to 30% by weight of a graft copolymer C comprising, in each case based on C, from 20 to 60% by weight of a polybutadiene rubber c1 from 80 to 40% by weight of a shell c2 grafted thereto and comprising, in each case based on c2, either from 70 to 90% by weight of styrene c21 and from 10 to 30% by weight of (meth)acrylonitrile c22, or of a shell c2 comprising from 15 to 40% by weight of styrene c23, from 85 to 60% by weight of methyl methacrylate c24 and up to 3% by weight of glycidyl methacrylate c25; from 5 to 30% by weight of a graft copolymer D comprising, in each case based on D, from 20 to 60% by weight of a crosslinked acrylate rubber d1, from 80 to 40% by weight of a shell d2 grafted thereto and comprising, in each case based on d2, from 70 to 90% by weight of styrene d21 and from 10 to 30% by weight of (meth)acrylonitrile d22, with the proviso that the graft copolymer C has a mean particle diameter of from 0.2 to 0.5 mu m and the graft copolymer D has a mean particle diameter of from 0.4 to 0.7 mu m, in each case determined as the d50 value of the cumulative weight distribution.

    9.
    发明专利
    未知

    公开(公告)号：ES2052795T3

    公开(公告)日：1994-07-16

    申请号：ES89105095

    申请日：1989-03-22

    Applicant: BASF AG

    Inventor： BAUMGARTNER EHRENFRIED DR ,  ECHTE ADOLF PROF DR ,  MERTES JURGEN DR

    IPC: C08F212/10 ,  C08F20/52 ,  C08F212/00 ,  C08F212/08 ,  C08F220/42 ,  C08F220/44 ,  C08F220/54 ,  C08F220/56

    Abstract: The moulding composition contains a copolymer of a) styrene, b) optionally acrylonitrile and c) an N-substituted amide of methacrylic acid, the monomers being present in amounts of from 1 to 95% by weight of a), up to 40% by weight of b) and from 98 to 5% by weight of c), and the monomer c) used being the methacrylamide of the formula … … in which R is a primary, secondary or tertiary alkyl radical, cycloalkyl radical, aryl radical or aralkyl radical having 1 to 12 carbon atoms, with the proviso that, if the alkyl radical is methyl or isopropyl, the copolymers have a styrene content of less than 75% by weight.

    10.
    发明专利
    未知

    公开(公告)号：DE4110459A1

    公开(公告)日：1992-10-01

    申请号：DE4110459

    申请日：1991-03-30

    Applicant: BASF AG

    Inventor： BAUMGARTNER EHRENFRIED DR ,  HOFMANN JUERGEN ,  JUNG RUDOLF H DR ,  MOORS RAINER DR ,  SCHAECH HANS JOERG

    IPC: C08L25/12 ,  C08L55/02

    Abstract: The invention relates to rubber-modified, high-impact moulding compositions containing, based on the sum of A, B1 and B2, A: from 70 to 98% by weight of a polymer matrix A, formed by free radical-initiated polymerisation of a mixture of from 60 to 90% by weight of styrene and from 10 to 40% by weight of acrylonitrile, and B1: from 1 to 29% by weight of a particulate, first graft polymer B1 distributed in the matrix and comprising a graft base of polybutadien and graft branches of a copolymer of styrene and acrylonitrile, having a mean particle size of from about 100 to 500 nm, B2: from 1 to 29% by weight of a particulate, second graft copolymer B2 distributed in the matrix and comprising a graft base of polybutadien and graft branches of a copolymer of styrene and acrylonitrile having a mean particle size of from 600 to 10000 nm, as obtained by preparing the two graft copolymers in solution and/or bulk and incorporating them into the polymer matrix in a conventional manner. e

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