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公开(公告)号：DE2909928A1
公开(公告)日：1980-09-25
申请号：DE2909928
申请日：1979-03-14
Applicant: BASF AG
Inventor： MAROSI LASZLO DIPL CHEM DR , STABENOW JOACHIM DIPL PHYS DR , SCHWARZMANN MATTHIAS DIPL CHEM
IPC: B01J29/04 , B01J29/072 , C07C1/20 , C07C11/02
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公开(公告)号：DE2830830A1
公开(公告)日：1980-01-31
申请号：DE2830830
申请日：1978-07-13
Applicant: BASF AG
Inventor： MAROSI LASZLO DIPL CHEM DR , STABENOW JOACHIM DIPL PHYS DR , SCHWARZMANN MATTHIAS DIPL CHEM
Abstract: New crystalline As silicate (I) has zeolite structure. (I) is produced by heating SiO2 and As2O3 in an aq. hexamethyl-enediamine (II) soln. at 100-200 degrees C under autogenous pressure and crystallisation. (I) is useful as catalyst in hydrocarbon conversions, esp. in the conversion of MeOH (or Me2O) to (2-4C) olefins.
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公开(公告)号：DE2830787A1
公开(公告)日：1980-01-31
申请号：DE2830787
申请日：1978-07-13
Applicant: BASF AG
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公开(公告)号：DE2510740A1
公开(公告)日：1976-09-30
申请号：DE2510740
申请日：1975-03-12
Applicant: BASF AG
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公开(公告)号：DE2325228A1
公开(公告)日：1974-12-05
申请号：DE2325228
申请日：1973-05-18
Applicant: BASF AG
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Patent Agency Ranking
公开(公告)号：DE3209223A1
公开(公告)日：1983-09-15
申请号：DE3209223
申请日：1982-03-13
Applicant: BASF AG
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公开(公告)号：DE3143869A1
公开(公告)日：1983-05-11
申请号：DE3143869
申请日：1981-11-05
Applicant: BASF AG
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公开(公告)号：DE3132014A1
公开(公告)日：1983-03-03
申请号：DE3132014
申请日：1981-08-13
Applicant: BASF AG
Inventor： MROSS WOLF DIETER DIPL CHEM DR , BIEDENKAPP DIETER DIPL CHEM DR , SCHWARZMANN MATTHIAS DIPL CHEM , SCHWETER WALTER DIPL CHEM DR
IPC: B01J23/84 , B01J23/86 , B01J23/88 , B01J23/881 , B01J23/887 , B01J27/18 , B01J27/188 , B01J27/199 , C07C5/333 , C07C15/46 , B01J23/85
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公开(公告)号：DE2904919A1
公开(公告)日：1980-08-21
申请号：DE2904919
申请日：1979-02-09
Applicant: BASF AG
Inventor： MROSS WOLF DIETER DIPL CHEM DR , TITZENTHALER ECKART DIPL CHEM , KOOPMANN JUERGEN DIPL CHEM DR , VOGT VOLKER DIPL CHEM DR , SCHWARZMANN MATTHIAS DIPL CHEM
IPC: B01J23/66 , B01J23/96 , B01J38/48 , C07B61/00 , C07D301/10
Abstract: Supported catalysts containing silver and alkali metals, for the preparation of ethylene oxide from ethylene and oxygen in the gas phase, are prepared or regenerated by modifying, respectively, a new or spent supported catalyst which already contains metallic silver and may or may not contain the light alkali metals lithium and/or sodium and, where a spent catalyst is concerned, also contains the heavy alkali metals potassium, rubidium and/or cesium, with a solution containing the heavy alkali metals, the modifier solution used containing (a) a surfactant and/or a reducing agent, in the case of the preparation of a new catalyst or (b) a surfactant, in the case of the regeneration of a spent catalyst.
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公开(公告)号：DE2831631A1
公开(公告)日：1980-02-07
申请号：DE2831631
申请日：1978-07-19
Applicant: BASF AG
Inventor： MAROSI LASZLO DIPL CHEM DR , STABENOW JOACHIM DIPL PHYS DR , SCHWARZMANN MATTHIAS DIPL CHEM
Abstract: V Silicate with zeolite structure is prepd. by crystallisation from a mixt. of water glass and an aq. soln. of amine at 100-200 degrees C under soln. pressure and in the presence of V oxide and/or V oxide cpd., pref. V chloride. The zeolite is prepd. using a mixt. of water glass (8wt.% Na2O, 25-30wt.% SiO2, small amt. of Al2O3) and V chloride in an aq. soln. contg. 5-50wt.% (10-25wt.%) hexamethylenediamine. The mixt. is heated for 1-5 days respectively, 2-4 days at 140-160 degrees C under soln. pressure. The resultant zeolite has a structure of ZSM-5 type and contains only a small amt. of Al. Its V oxide content is 0.5-3wt.%. Crystalline V silicate has a ZSM-5 type zeolite structure and is suitable as catalyst, after activation, in cracking and hydrocracking processes, and in the conversion of methanol to unsatd. hydrocarbon.
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